• Carbon letters
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• v.12 no.2
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• pp.70-80
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• 2011

Two pitches with different average molecular structures were electrospun and compared in terms of the properties of their fibers after oxidative stabilization, carbonization, and activation. The precursor with a higher molecular weight and greater content of aliphatic groups (Pitch A) resulted in better solubility and spinnability compared to that with a lower molecular weight and lower aliphatic group content (Pitch B). The electrical conductivity of the carbon fiber web from Pitch A of 67 S/cm was higher than that from Pitch B of 52 S/cm. The carbon fiber web based on Pitch A was activated more readily with lower activation energy, resulting in a higher specific surface area compared to the carbon fiber based on Pitch B (Pitch A, 2053 $m^2/g$; Pitch B, 1374 $m^2/g$).

• Composites Research
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• v.28 no.6
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• pp.361-365
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• 2015

The influence of MWCNTs on fracture toughness properties of MWCNTs/Nickel-Pitch Fibers/epoxy composites (MWCNTs/Ni-PFs/epoxy) was investigated according to MWCNTs content. Nickel-Pitch-based carbon fibers (Ni-PFs) were prepared by electroless nickel-plating. The surface properties of Ni-PFs were determined by scanning electron microscopy (SEM) and X-ray photoelectron spectrometry (XPS). The fracture toughness of MWCNTs/Ni-PFs/epoxy was assessed by critical stress intensity factor ($K_{IC}$) and critical strain energy release rate ($G_{IC}$). From the results, it was found that the fracture toughness properties of MWCNTs/Ni-PFs/epoxy were enhanced with increasing MWCNTs content, whereas the value decreased above 5 wt.%. MWCNTs content. This was probably considered that the MWCNTs entangled with each other in epoxy due to an excess of MWCNTs.

• Speech Sciences
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• v.8 no.2
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• pp.133-148
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• 2001

Focus and information structure are closely related with the distribution of pitch accents. A focused word conveys new information and bears a pitch accent. A content word can usually get a pitch accent, but it can be deaccented if it is mentioned earlier in the discourse. In this paper, we test how English native speakers and Korean learners of English realize pitch accents according to focus and information structure of a sentence. The production experiment shows that English native speakers give a pitch accent to narrow-focused items, deaccenting all the other items of the sentence. For VP broad focus, native speakers give a pitch accent either to both the verb and its complement or to the complement only. On the other hand, it is found that Koreans give pitch accents to most content words regardless of focus and information structure. Moreover, the perception experiment confirms that Koreans' intonation patterns, which are not appropriate in terms of focus and information structure, may jeopardize listeners' comprehension. This paper shows that Korean speakers have little knowledge about focus and information structure for intonational realization, and that such notions should be applied to teaching of English intonation.

• Korean Journal of Materials Research
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• v.25 no.6
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• pp.279-287
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• 2015

In order to prepare anode materials for high power lithium ion secondary batteries, carbon composites were fabricated with a mixture of petroleum pitch and coke (PC) and a mixture of petroleum pitch, coke, and natural graphite (PC-NG). Although natural graphite has a good reversible capacity, it has disadvaantages of a sharp decrease in capacity during high rate charging and potential plateaus. This may cause difficulties in perceiving the capacity variations as a function of electrical potential. The coke anodes have advantages without potential plateaus and a high rate capability, but they have a low reversible capacity. With PC anode composites, the petroleum pitch/cokes mixture at 1:4 with heat treatment at $1000^{\circ}C$ (PC14-1000C) showed relatively high electrochemical properties. With PC-NG anode composites, the proper graphite contents were determined at 10~30 wt.%. The composites with a given content of natural graphite and remaining content of various petroleum pitch/cokes mixtures at 1:4~4:1 mass ratios were heated at $800{\sim}1200^{\circ}C$. By increasing the content of petroleum pitch, reversible capacity increased, but a high rate capability decreased. For a given composition of carbonaceous composite, the discharge rate capability improved but the reversible capacity decreased with an increase in heat treatment temperature. The carbonaceous composites fabricated with a mixture of 30 wt.% natural graphite and 70 wt.% petroleum pitch/cokes mixture at 1:4 mass ratio and heat treated at $1000^{\circ}C$ showed relatively high electrochemical properties, of which the reversible capacity, initial efficiency, discharge rate capability (retention of discharge capacity in 10 C/0.2 C), and charge capacity at 5 C were 330 mAh/g, 79 %, 80 %, and 60 mAh/g, respectively.

• 한국기계연구소 소보
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• s.15
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• pp.37-46
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• 1985

Properties of Precursor pitch derived from petroleum residue were studied physical and chemical analysis method for investigation of production of pitch fiber. For preparing of those precursor pitches it was carried out a temperature and time variation experiment i reactor. It was demonstrated the precursor pitch prepared in this study to have a similar properties to Ashland precursor pitch capable of bulk mesophase formation from the results of the basic analysis, that is, molecular weight distribution, coking yield, carbon content, chemical composition, etc.

• Journal of Broadcast Engineering
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• v.9 no.1
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• pp.2-7
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• 2004

In this paper, we proposed the content-based music information retrieval technique using some MPEG-7 low-level descriptors. Especially, pitch information and timbral features can be applied in music genre classification, music retrieval, or QBH(Query By Humming) because these can be modeling the stochasticpattern or timbral information of music signal. In this work, we restricted the music domain as O.S.T of movie or soap opera to apply broadcasting system. That is, the user can retrievalthe information of the unknown music using only an audio clip with a few seconds extracted from video content when background music sound greeted user's ear. We proposed the audio feature set organized by MPEG-7 descriptors and distance function by vector distance or ratio computation. Thus, we observed that the feature set organized by pitch information is superior to timbral spectral feature set and IFCR(Intra-Feature Component Ratio) is better than ED(Euclidean Distance) as a vector distance function. To evaluate music recognition, k-NN is used as a classifier

• Journal of the Korean Ceramic Society
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• v.33 no.12
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• pp.1387-1393
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• 1996

A study on mesophase pitch as a matrix precursor of carbon fiber reinforced carbon (C/C) composite has been recently presented. This study is concerned with the production of mesophase pitch as matrix precursors for C/C composite from coal tar pitch. A commercial coal tar pitch was heat-treated at 25$0^{\circ}C$ for 2 hours to remove low molecular weight fraction from the pitch then increasing the temperature of the pitch to between 350~45$0^{\circ}C$ to produce mesophase pitch. The pitch was continuously stirred during this time and nitrogen gas was continuously bubbled through the pitch. Spherical and bulk mesophases were formed in the pitch after heat-treatment,. Parent and mesophae pitches were characterized by elemental analysis coke yield solubi-lity in tetrahydrofuran and hexane and an optical microscopy to measure the mesiophase content. It was neces-sary to produce C/C composite that a mesophase pitch with about 30-40 vol% mesophase spherulites can be infiltrated into a fiber preform without a filter effect as a matrix precursor conditions. This condition was satisfied with mesophase pitch heat treated at 40$0^{\circ}C$ for 2 hours. The other heat treatment conditions showed the nuclei of mesophase or bulk mesophae which were not satisfied with the matix precursor condition.

• The Journal of the Acoustical Society of Korea
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• v.23 no.4E
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• pp.112-119
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• 2004

This paper presents a method for the automatic recognition of pitch accents with no prior knowledge about the phonetic content of the signal (no knowledge of word or phoneme boundaries or of phoneme labels). The recognition algorithm used in this paper is a time-delay recurrent neural network (TDRNN). A TDRNN is a neural network classier with two different representations of dynamic context: delayed input nodes allow the representation of an explicit trajectory F0(t), while recurrent nodes provide long-term context information that can be used to normalize the input F0 trajectory. Performance of the TDRNN is compared to the performance of a MLP (multi-layer perceptron) and an HMM (Hidden Markov Model) on the same task. The TDRNN shows the correct recognition of $91.9{\%}\;of\;pitch\;events\;and\;91.0{\%}$ of pitch non-events, for an average accuracy of $91.5{\%}$ over both pitch events and non-events. The MLP with contextual input exhibits $85.8{\%},\;85.5{\%},\;and\;85.6{\%}$ recognition accuracy respectively, while the HMM shows the correct recognition of $36.8{\%}\;of\;pitch\;events\;and\;87.3{\%}$ of pitch non-events, for an average accuracy of $62.2{\%}$ over both pitch events and non-events. These results suggest that the TDRNN architecture is useful for the automatic recognition of pitch accents.

• Carbon letters
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• v.25
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• pp.89-94
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• 2018

In this study, we tried to prepare an isotropic spinnable pitch which can be useful to prepare the general purpose carbon fiber through the co-carbonization of biomass tar with ethylene bottom oil under two different preparation methods (atmospheric distillation, pressurized distillation). The results showed that the ethylene bottom oil added co-carbonization was very effective to decrease of the oxygen contents for obtaining a stable spinnable pitch. The pressurized distillation was more effective to reduce the oxygen functional groups of pitches than atmospheric distillation. The obtained spinnable pitch by the pressurized distillation showed higher pitch yield of 42% and lower oxygen content of 9.12% than the spinnable pitch by the atmospheric distillation. The carbon fiber derived from the pressurized distillation spinnable pitch by carbonization at $800^{\circ}C$ for 5 min showed that the higher tensile strength of carbon fiber was increased up to 800 MPa.

• Journal of the Korean Wood Science and Technology
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• v.32 no.4
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• pp.46-51
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• 2004

The objective of this study was to evaluate the applicability of high temperature drying to pitch pine (Pinus rigida) lumber, especially intended for use as lamina of structural glued laminated timber (glulam), to enhance the efficient utilization and provide added-value to that species. The high temperature schedule and drying procedures utilized were shown to be reasonable for drying glulam lamina due to the occurrence of small moisture gradients, minimal residual drying stress, and low warpage. Through preliminary tests, it was confirmed that residual resin at lamina surfaces did not adversely affect the gluing process. However, quantitative analysis of resin is required for developing a method to constrain the occurrence of pitch trouble with respect to decreasing long-term adhesive and finish durability of glulam in use after manufacturing. The final moisture content of high temperature dried lamina was much lower than target moisture content and discoloration was more severe than anticipated. In a further study, it will be necessary to determine the optimal drying conditions, such as temperature, humidity, drying time, and top load restraint level, which could best control discoloration, warpage, and moisture content of the lamina, while minimizing fuel expense.