• Title/Summary/Keyword: physical and chemical effects

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Dynamic characteristics of CFRP-Strengthened wooden beams: Experimental and numerical study

  • Nur Sunar;Habib Uysal
    • Structural Engineering and Mechanics
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    • v.89 no.3
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    • pp.323-334
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    • 2024
  • Physical and chemical factors can cause traditional timber constructions to lose structural integrity. Knowing the dynamic properties of the building components is vital to avoid damage to the buildings from dynamic effects, a subset of physical effects. In this work, spruce and scotch pine wooden beams that had been strengthened in three distinct ways with carbon fiber strengthened polymer (CFRP) were investigated for changes in their dynamic properties. For this, CFRP was used to strengthening unstrengthened wooden beams in the form of bottom confinement, U-shaped confinement, and full confinement after the dynamic parameters of the beams were determined. By using experimental modal analysis with both free-free and fixed-fixed boundary conditions, the beams'initial natural frequencies were identified.

Effects of total pressure and gravity level on the physical vapor transport of $Hg_2Cl_2-Cl_2$ system

  • Choi, Jeong-Gi;Kwon, Moo-Hyun;Kim, Geug-Tae
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.19 no.3
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    • pp.116-124
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    • 2009
  • Our computational studies for the physical vapor transport crystal growth of $Hg_2Cl_2-Cl_2$ system evidence suggests that the PVT growth process exhibits the diffusion-dominated behaviors for aspect ratios more than and equal to 10, which would provide purely diffusive transport conditions adequate to microgravity environments less than $10^{-3}g_0$. Also, the regimes of high temperature difference based on the fixed source temperature of $380^{\circ}C$, where ${\Delta}T$ is relatively large enough for the crystal growth of mercurous chloride, the transport rates do not keep increasing with ${\Delta}T$ but tend to some constant value of $2.12\;mole\;cm^{-2}s^{-1}$. For the aspect ratios of 5, 10, and 20, the transport rate is directly proportional to the total pressure of the system under consideration. For Ar = 5, the rate is increased by a factor of 2.3 with increasing the total pressure from 403 Torr to 935 Torr, i.e., by a factor of 2.3. For both Ar = 10 and 20, the rate is increased by a factor of 1.25 with increasing the total pressure from 403 Torr to 935 Torr.

Synthesis and Substituent Effects in Substituted Styryl 4-Methoxy-1-Naphthyl Ketones (다양한 치환기가 붙은 Styryl 4-Methoxy-1-Naphthyl Ketone의 합성과 치환기 효과에 관한 연구)

  • Thirunarayanan, G.;Ananthakrishna Nadar, P.
    • Journal of the Korean Chemical Society
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    • v.50 no.3
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    • pp.183-189
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    • 2006
  • A series of substituted styryl 4-methoxy-1-naphthyl ketones [(2E)-1-(4-methoxy-1-naphthyl)-3-phenyl-2-propen-1-ones] were synthesized using facile method of microwave assisted condensation reaction. The yield of chalcones is more than 90%. They are characterized by their physical constants, micro analysis, infrared (KBr, 4000-400 cm?1) and NMR both 1H and 13C spectral data. From infrared spectra, the s-cis and s-trans stretching vibrations of carbonyl group, from NMR spectra the ethylenic proton and carbon chemical shifts (ppm) are assigned. These spectral data are correlated with various Hammett substituent constants. From the results of statistical analysis the effect of substituents on CO, ? and ? proton and carbons are explained.

Effects of Nutrient Source on Soil Physical, Chemical, and Microbial Properties in an Organic Pear Orchard (유기질 비료 급원이 배 과원의 토양 물리화학성 및 미생물성에 미치는 영향)

  • Choi, Hyun-Sug;Li, Xiong;Kim, Wol-Soo;Lee, Youn
    • Korean Journal of Environmental Agriculture
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    • v.30 no.1
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    • pp.16-23
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    • 2011
  • BACKGROUND: This study was conducted to investigate the effects of different organic treatments and a chemical fertilizer on the soil chemical, physical, and microbial properties in an organic pear orchard. METHODS AND RESULTS: Control was referred as a NPK chemical fertilizer (15N-9P-10K) and organic treatments included compost containing with oil cake, compost containing with humic acid, and compost containing with chitin substance. All treatments applied at rates equivalent to 200 g N per tree per year under the tree canopy in March 30 of 2008 and 2009. Soil bulk density, solid phase, liquid phase, and penetration resistance were not significantly different among the treatments. Organic treatment plots had greater organic matter, total nitrogen, potassium, and magnesium concentrations compared to control, and the nutrient concentrations were not consistently affected by the organic treatments. Microbial biomass nitrogen and carbon, dehydrogenase, acid-phosphatase, and chitinase activities overall increased from March to August. Organic treatments, especially compost containing with oil cake or chitin aicd, increased the microbial variables compared to control. CONCLUSION(s): All the organic treatments consistently stimulated soil biological activity. The consistent treatment effect, however, did not occur on the soil mineral nutrition as the trees actively taken up the nutrients during a growing season, which would have diminished treatment effects. Long-term study required for evaluating soil physical properties in a pear orchard.

Mercurous bromide $(Hg_2Br_2)$ crystal growth by physical vapor transport and characterization

  • Kim, S.K.;S.Y. Son;K.S. Song;Park, J.G.;Kim, G.T.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.12 no.6
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    • pp.272-282
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    • 2002
  • Mercurous bromide ($Hg_{2}0Br_{2}$) crystals hold promise for many acousto-optic and opto-electronic applications. This material is prepared in closed ampoules by the physical vapor transport (PVT) growth method. Due to the temperature gradient between the source and the growing crystal region, the buoyancy-driven convection may occur. The effects of thermal convection on the crystal growth rate was investigated in this study in a horizontal configuration for conditions ranging from typical laboratory conditions to conditions achievable only in a low gravity environment. The results showed that the growth rate increases linearly with Grashof number, and for 0.2 $\leq$ Ar (transport length-to-height, L/H)$\leq$1.0 sharply for Ar=5 and $\Delta$T=30 K. We have also shown that the magnitude of convection decreases with the Ar. For gravity levels of less than $10^{-2}$g the non-uniformity of interfacial distribution is negligible.

A Study on the Hydrolyzed Ginseng Saponin-Quaternary and its Application in Cosmetics (가수분해된 인삼사포닌 4급 암모늄엽과 화장품으로의 응용에 관한 연구)

  • 김영대;김창규;이정남;하병조
    • Journal of Ginseng Research
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    • v.13 no.2
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    • pp.189-197
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    • 1989
  • A new quaternary ammonium compound, hydrolyzed ginseng-saponin quaternary (HGSQ), from Korean ginseng saponin and 2,3-epoxypropyltrimethylammonium chloride has been developed as a conditioning agent in cosmetics. This structure has a hydrophobic group from the aglycone of ginseng saponin which is biologically active and considered to be the most important component of the Korean ginseng. Its properties : surface tension, critical micelle concentration (CMC), eye irritation, sorption onto hair, force reduction(%) and moisture retention effect were studied. Its cationic character allows the molecule to be more substantive than ginseng saponin. HGSQ had good physical properties and was safe. enough as a cosmetic raw material. Also half-head tests of HGSQ-containing shampoo were carried out to compare the conditioning effects in shampoos. HGSQ was an excellent conditioning agent in shampoo..

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Effects of Substrate Temperature and Sputter Gas on the Physical Characteristics, Chemical Composition and Preferred Orientation of ZnO Thin Films (기판온도 및 스퍼터가스에 따른 ZnO 박막의 우선배향성, 화학조성, 물리적특성 변화)

  • 김병진;조남희
    • Journal of the Korean Ceramic Society
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    • v.34 no.12
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    • pp.1227-1234
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    • 1997
  • ZnO thin films were prepared by rf-magnetron sputter at various conditions. Crystallinity, microstructure, chemical composition, and optical composition, and optical properties of the films were investigated as functions of substrate temperature (R. T.-50$0^{\circ}C$) an sputter gas (O2/Ar=0-50%). ZnO thin films grown at 50$0^{\circ}C$ with sputter gas of pure argon as well as at R. T. with sputter gas of a mixture of argon & oxygen(O2/Ar=2%) exhibit a strong tendency of (002) preferred orientation, compared with a considerable random orientation at the other conditions. The thin films with (002) preferred orientation has a chemical stoichiometry of Zn/O-1.01, a band gap of 3.3eV, and a packing density of 98% respectively.

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Applications of carbon-based materials in solid phase micro-extraction: a review

  • Guo, Jian;Park, Soo-Jin;Meng, Long-Yue;Jin, Xinghua
    • Carbon letters
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    • v.24
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    • pp.10-17
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    • 2017
  • With continuous development in the field of sample preparation technology, solid phase micro-extraction (SPME) has been widely used in analytical chemistry for high extraction efficiency and convenient operation. Different materials lead to different extraction results. Among existing materials, carbon-based materials are still attracting attention from scientists due to their excellent physical and chemical properties as well as their modifiable surfaces, which could enhance the adsorption effects of SPME fiber. This review introduces the preparation methods and applications of different kinds of carbon-based material coatings on fibers. In addition, directions for future research on carbon material composites are discussed.

Effects of Silver Treatment and the Physical and Chemical Properties of Spherical Activated Carbon

  • Oh, Won-Chun;Kim, Jong-Gyu;Kim, Hyuk;Chen, Ming-Liang;Zhang, Kan;Meng, Ze-Da;Zhang, Feng-Jun
    • Korean Journal of Materials Research
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    • v.19 no.11
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    • pp.569-575
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    • 2009
  • In this study, the effects of silver treatment and activation on the physical and chemical properties of spherical activated carbon (SAC) were studied. The textural properties of SAC were characterized by BET surface area, XRD, SEM, iodine adsorption, strength intensity, pressure drop and antibacterial effects. BET surface areas of SACs decreased with an increase of the amount of PR before and after activation, and the BET surface areas of SACs were found to be about 2-3 times the size of those before activation. The XRD patterns showed their existing state as stable Ag crystals and carbon structure. The Ag particles are seaweedlike and uniform, being approximately 5-10 μm in size deposited on the surface of activated carbon. All of the samples had much more iodine adsorption capability after activation than before activation. The strength values of SACs increased with an increase of the amount of PR, and there was a smaller drop in the strength values of SACs with silver treatment than with non-silver treatment after activation. The Ag-SAC composites showed strong antibacterial activity against Escherichia coli (E. Coli).

Implications of Air Pollution Effects on Athletic Performance

  • Pierson, W.E.;Covert, D.S.;Koenig, J.Q.;Namekata, T.;Kim, Y.S.
    • Journal of Environmental Health Sciences
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    • v.11 no.2
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    • pp.1-16
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    • 1985
  • There are a large number or chemical compounds that are present in a polluted atmosphere and that alone or in combination are important to consider for their potential effect on the respiratory system and impact on athletic performance. A general categorization or description of the level of pollution in terms of the concentration of one or more compounds or by type such as oxidizing compounds is inadequate and misleading. A useful initial categorization of pollutant compounds according to their mechanism of production, primary or secondary, is often made. For health effects, consideraiions of the physical state, gaseous or particulate, and the solublity and reactivity of the pollutant is also important. Pollutant compounds or substances that are emitted directly from a source and that undergo little or no chemical change in the atmosphere from source to receptor are termed primary pollutants.

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