• 제목/요약/키워드: physical and chemical effects

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도시 폐기물로부터 알코올 생산 (II) - 물리적, 화학적 전처리된 폐지의 효소가수분해 조건 검토 - (The Production of Alcohol from Municipal Waste(II) - The Effects of Physical or Chemical Treatment on the Enzymatic Hydrolysis of Waste Paper -)

  • 임부국;양재경;이종윤
    • Journal of the Korean Wood Science and Technology
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    • 제25권1호
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    • pp.65-70
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    • 1997
  • The effects on the enzymatic hydrolysis of waste paper treated with physical or chemical treatment were investigated. To gain the higher saccharification rate, physical or chemical treatment are necessary in enzymatic conversion process of waste paper. The major deterrents to the effective utilization of waste paper for enzymatic conversion process are phenolic compounds, cellulose crystallinity and coating materials. In the enzymatic hydrolysis of waste paper, the deterrents through enzymatic conversion process can be eliminated by the physical or chemical treatment. This study was performed to obtain the optimal condition for enzymatic conversion process of non-treated waste paper and to review effects on enzymatic conversion process of waste paper treated with physical or chemical methods. In the aspect of saccharification rate, waste paper treated with 1.5% sodium hypochlorite was the most effective and in physical treatment methods, multi-stage treatment(autohydrolysis+refining treatment) was more effective than the other physical treatment.

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Occupational Exposure to Physical and Chemical Risk Factors: A Systematic Review of Reproductive Pathophysiological Effects in Women and Men

  • Soleiman Ramezanifar;Sona Beyrami;Younes Mehrifar;Ehsan Ramezanifar;Zahra Soltanpour;Mahshid Namdari;Noradin Gharari
    • Safety and Health at Work
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    • 제14권1호
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    • pp.17-30
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    • 2023
  • The human reproductive system can be affected by occupational exposure to many physical and chemical risk factors. This study was carried out to review the studies conducted on the issue of the pathophysiological effects of occupational physical and chemical risk factors on the reproductive system of females and males. In this systematic review, the databases such as "Google Scholar," "Pub-Med," "Scopus," and "Web of Science" were used. Following the Preferred Reporting Items for Systematic reviews and Meta-Analyses (PRISMA 2020), the studies included in our study were published between 2000 and 2021. In order to extract the required data, all sections of the articles were reviewed. Out of 57 articles we reviewed, 34 articles were related to field studies and 23 articles to clinical studies. Among them, 43 studies dealt with the pathophysiological effects of chemical agents, six studies dealt with the pathophysiological effects of physical factors, and 8 studies dealt with the pathophysiological effects of physicochemical factors on the human reproductive system. Physical (noise, heat, and radiofrequency radiation) and chemical (such as carbamate and organophosphate pesticides, benzene, toluene, xylene, formaldehyde, NO2, CS2, manganese, lead, nickel, and n-hexane) risk factors had pathophysiological effects on the human reproductive system. The presence of these risk factors in the workplace caused damage to the human reproductive system. The rate of these negative pathophysiological effects can be reduced by performing appropriate managerial, technical, and engineering measures in work environments.

장기저장시 가공 원료잎담배의 이화학성 변화 (The Change of Physical and Chemical Properties of Processed Leaf Tobacco During Long-term Storage)

  • 김상범;안동명;이종철;이경구;조수헌
    • 한국연초학회지
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    • 제23권1호
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    • pp.31-39
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    • 2001
  • This study was carried out to investigate the changes of physical and chemical properties and the usability of long-term stored leaf tobacco. The physical chemical properties of the flue-cured and burley leaves produced in 1993, processed in 1994 were analysed from Nov. 1996 to Nov. 1999. The pH and moisture content in leaf decreased slowly until 4 years’storage after processing, while those of leaf changed little thereafter. However, total sugar content continuously decreased until 5 years after processing. The filling capacity increased and shatter resistance index decreased in long-term stored leaf. The sensory test, cilia stasis and the chemical components of cigarette smoke had no significant differences between short and long-term stored leaves. When the processed leaves were stored till 5 years after processing, there were no deteriorative effects on quality and usability of leaf tobacco. Therefore, it is considered that the processed leaf may be stored for 5 years or more under the inevitable situation.

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사출성형 열가소성 폴리우레탄의 물리적 성질에 미치는 금형 온도 영향 (Effects of Mold Temperatures on Physical Properites of Injection Molded Thermoplastic Polyurethanes)

  • 이대수;김성근;구엔빈칸;이명걸;방수진
    • Elastomers and Composites
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    • 제39권4호
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    • pp.286-293
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    • 2004
  • 경도를 달리하는 에스테르계 및 에테르계 열가소성 폴리우레탄(thermoplastic polyurethane: TPU)의 사출에서 금형 온도가 물리적 성질에 미치는 영향을 조사하였다. TPU의 연질부 유리전이온도는 금형 온도 변화에 따라 거의 변화하지 않았으며, 연질부와 경질부의 상분리는 금형온도의 영향을 별로 받지 않는 것으로 판단되었다. 그러나 에스테르계와 에테르계 TPU는 종류에 관계없이 공통적으로 경도가 높은 TPU들은 금형온도를 높이는 경우 결정성, 고무상 평탄 온도영역, 인장강도가 감소하였으나, 경도가 낮은 TPU들은 오히려 결정성, 고무상 평탄 온도영역, 인장강도의 증가를 보였다. TPU의 사출 성형 금형 온도에 따른 물리적 성질의 차이를 결정성 경질부의 결정화와 물리적 가교효과 차이로 해석하였다.

버어리종 건조방법이 건엽의 품질에 미치는 영향 (Effects of Curing Methods on the Quality of Cured Leaves in Burley Tobacco (N. tabacum L.))

  • 배성국;조천준;임해건;김요태
    • 한국연초학회지
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    • 제20권1호
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    • pp.26-32
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    • 1998
  • This study was conducted to obtain the basic information on the burley tobacco (Nicotiana tabacum L.) curing methods. The effects of the three kinds of curing methods on the dry weight losses during curing, chemical contents and physical properties of cured leaves, and organoleptic and smoking qualities were observed. The dry weight losses during curing was the highest in the stalk curing, and the lowest in the conventional priming. The longer the curing periods was, the more the loss of dry weight. The percent of the excessive dried leaves was high and the price per kilogram was low in the conventional priming. The chemical contents and the physical properties of the cured leaves in the conventional priming were similar to those of yellowing or browning stage of curing. But, the chemical contents and the physical properties of the cured leaves in the stalk curing were comparable to those of the air curing. The smoking quality was the best in the stalk curing.

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Effect of Surfactant on the Physical Properties and Crosslink Density of Silica Filled ESBR Compounds and Carbon Black Filled Compounds

  • Hwang, Kiwon;Kim, Woong;Ahn, Byungkyu;Mun, Hyunsung;Yu, Eunho;Kim, Donghyuk;Ryu, Gyeongchan;Kim, Wonho
    • Elastomers and Composites
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    • 제53권2호
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    • pp.39-47
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    • 2018
  • Styrene-butadiene rubber (SBR) is widely used in tire treads due to its excellent abrasion resistance, braking performance, and reasonable cost. Depending on the polymerization method, SBR is classified into solution-polymerized SBR (SSBR) and emulsion-polymerized SBR (ESBR). ESBR is less expensive and environmentally friendlier than SSBR because it uses water as a solvent. A higher molecular weight is also easier to obtain in ESBR, which has advantages in mechanical properties and tire performance. In ESBR polymerization, a surfactant is added to create an emulsion system with a hydrophobic monomer in the water phase. However, some amount of surfactant remains in the ESBR during coagulation, making the polymer chains in micelles clump together. As a result, it is well-known that residual surfactant adversely affects the physical properties of silica-filled ESBR compounds. However, researches about the effect of residual surfactant on the physical properties of ESBR are lacking. Therefore, in this study we compared the effects of remaining surfactant in ESBR on the mechanical properties of silica-filled and carbon black-filled compounds. The crosslinking density and filler-rubber interaction are also analyzed by using the Flory-Rehner theory and Kraus equation. In addition, the effects of surfactant on the mechanical properties and crosslinking density are compared with the effects of TDAE oil (a conventional processing aid).

육체운동에 의해 유발되는 화학물질에 대한 반응성의 변화 (Alteration in Response to Chemicals Induced by Physical Exercise)

  • 김영철
    • Toxicological Research
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    • 제18권3호
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    • pp.215-226
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    • 2002
  • Acute or repeated physical exercise affects a large number of physiological parameters including hemodynamics, respiration, pH, temperature, gastrointestinal function and biotransformation, which determine the pharmacokinetics of drugs and chemicals. The rate and the amount of a chemical reaching the active site are altered by physical exercise, which results in significant changes in pharmacolosical/toxicological activity of the chemical. This aspect of physical exercise has vast implication in therapeutics and in safety evaluation, particularly for chemicals that have a low margin of safety. However there appears to be a wide inter- and intraindividual variation in the effects of physical exercise depend-ing on the duration, intensity and type of exercise, and also on the properties of each chemical. It is suggested that more studies need to be done to determine which factor(s) plays a major role in the disposition of chemicals in human/animals performing physical exercise. Certain chemicals induce severe toxicity due to metabolic conversion to reactive intermediate metabolites. it is suggested that repeated exercise may enhance the free radical scavenging system by increasing the activity of antioxidant enzymes. This area of research remain to be explored to elucidate the interaction of exercise and chemical on the antioxidant system.

피부의 광반응 (Photoreactions of the Skin)

  • 배성수;박래준;김진상;권혁철
    • The Journal of Korean Physical Therapy
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    • 제4권1호
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    • pp.13-18
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    • 1992
  • Most of the electromagnetic agents used in physical therapy rely for their effects on tissue heating and photoreaction of the body. Infrared and untraviolet light on the other hand, owns its place in medicine because it produces direct photochemial reaction when it interacts with the body. This study was carried out to investigate and review for photoreaction of the akin. The results were an follows. 1. The effects of the infrared are heat production, increasing metabolism, increasing circulation, vasodilatation and pigmentation. 2. Directed photoreactions are divided into acute reaction and chronic reaction, and the acute reaction makes pigmentation from $290\~320nm$ of ultraviolet ray. 3. Ultraviolet ray formated pigmentations, which are melanoblasts excited from ultraviolet ray and received chemical stimulation, that make melanin granule. 4. If exposured with long duration, at ultraviolet ray, it makes skin thickening and epithelioma. 5. Indirected photoreaction is made by existenced hypersensitivity of photoreaction or lack of photodefence structure. 6. The phototoxic reactions are synthesized by chemical reaction of excitement from ultraviolet ray also this time analysis, synthesis and polymerization from energy of a circumferenced substance. 7. Sunscreen substances are P-amino benzoic acid and oxidate titan.

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A Chemical Kinetic Model Including 54 Reactions for Modeling Air Nonequilibrium Inductively Coupled Plasmas

  • Yu, Minghao;Wang, Wei;Yao, Jiafeng;Zheng, Borui
    • Journal of the Korean Physical Society
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    • 제73권10호
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    • pp.1519-1528
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    • 2018
  • The objective of the present study is the development of a comprehensive air chemical kinetic model that includes 11 species and 54 chemical reactions for the numerical investigation of air nonequilibrium inductively coupled plasmas. The two-dimensional, compressible Navier-Stokes equations coupled with the electromagnetic-field equations were employed to describe the fundamental characteristics of an inductive plasma. Dunn-Kangs 32 chemical-reaction model of air was reconstructed and used as a comparative model. The effects of the different chemical kinetic models on the flow field were analyzed and discussed at identical/different working pressures. The results theoretically indicate that no matter the working pressure is low or high, the use of the 54 chemical kinetic model presented in this study is a better choice for the numerical simulation of a nonequilibrium air ICP.

Effects of inert gas (Ne) on thermal convection of mercurous chloride system of $Hg_2Cl_2$ and Ne during physical vapor transport

  • Choi, Jeong-Gil;Lee, Kyong-Hwan;Kim, Geug-Tae
    • 한국결정성장학회지
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    • 제18권6호
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    • pp.225-231
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    • 2008
  • For an aspect ratio (transport length-to-width) of 5, Pr=1.13, Le=1.91, Pe=4.3, Cv=1.01, $P_B=20\;Torr$, the effects of addition of inert gas Ne on thermally buoyancy-driven convection ($Gr=2.44{\times}10^3$) are numerically investigated for further understanding and insight into essence of transport phenomena in two dimensional horizontal enclosures. For $10K{\leq}{\Delta}T{\leq}50\;K$, the crystal growth rate increases from 10 K up to 20 K, and then is slowly decreased until ${\Delat}T=50\;K$, which is likely to be due to the effects of thermo-physical properties stronger than the temperature gradient corresponding to driving force for thermal convection. The dimensional maximum velocity gratitude reflecting the intensity of thermal convection is directly and linearly proportional to the temperature difference between the source and crystal regions. The rate is first order-exponentially decreased for $2{\leq}Ar{\leq}5$. This is related to the finding that the effects of side walls tend to stabilize convection in the growth reactor. In addition, the rate is first order exponentially decayed for $10{\leq}P_B{\leq}200\;Torr$.