• Proceedings of the Korean Vacuum Society Conference
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• 2004.02a
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• pp.68-68
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• 2004

• Proceedings of the Korean Society for Agricultural Machinery Conference
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• v.10 no.1
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• pp.249-252
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• 2005

• Elastomers and Composites
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• v.44 no.4
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• pp.423-428
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• 2009

The non-Newtonian flow curves of polyurethane melts were obtained by using a Physica cone-plate rheometer at various temperatures. The rheological parameters were obtained by applying non-Newtonian flow equation to the flow curves for polyurethane samples. When the polyurethane samples are under increasing-decreasing shear rate modes, the hysteresis loop and thixotropic behavior were shown. Polyurethane melts behave as strong gels when they are subjected to shear flow, but when the applied stress surpasses the yield stress, they exhibit non-linear viscoelasticity. Upon decreasing shear rate, its shear stress remains smaller than the values measured in the increasing shear rate mode, because of broken of its structure.

• Journal of the Korean Chemical Society
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• v.50 no.3
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• pp.196-202
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• 2006

The self diffusion distributions of viscoelastic molten polyurethanes were determined from the relationship between the relaxation spectra and the distribution of self diffusion. The relaxation spectra of ester, PCL and PCL dyed type molten polyurethanes were obtained by applying the experimental stress relaxation curves to the theoretical equation of the Ree-Eyring and Maxwell non-Newtonian model(REM model) from computer calculation. The experiments were carried out at various temperatures using the physica rheometer with the temperature controller. The self diffusion and hole distance of amorphous region of polyurethane samples were investigated by experiments of stress relaxation. The diffusion coefficients and hole volumes were calculated from rheological parameters and crystallite size in order to study the diffusion of flow segments in amorphous region. It was observed that the relaxation spectra and self diffusions of these polymer samples are directly related to the distribution of molecular weights, viscosities, hole volumes and activation energies of flow segments.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2005.05a
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• pp.350-355
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• 2005

This paper presents a new approach for hysteresis modeling of a magnetorheological (MR) fluid. The field-dependent hysteresis of MR fluid is investigated using the Preisach model. The commercial MR Product (MRF-132LD, Lord Corporation) is employed. Its field-dependent shear stress is then obtained using a rheometer (MCR 300, Physica). In order to show the applicability of the Preisach model to the MR fluid, two significant Properties; the minor loop property and the wiping-out property are experimentally examined. Subsequently, the Preisach model for the MR fluid is identified using experimental first order descending (FOD) curves in discrete manner. The effectiveness of the identified hysteresis model is verified in the time domain by comparing the predicted field-dependent shear stress with the measured one. In addition, the hysteresis model proposed in this work is compared to Bingham model.

• The Korean Journal of Rheology
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• v.9 no.1
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• pp.40-46
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• 1997

폴리이소부틸렌(PIB)/폴리부텐(PB) 고분자 용액에 분산된 입자의 영향을 살펴보기위 해 제조된 kaolinite/PIB/PB 용액에 대한 Weissenberg 효과와 유변학적 물성을 조사하였다. Kaolinite 분산 PIB/PB 고분자 용액도 2차 유체로 간주될수 있음이 발견되었으며 느린 변형 속도에서 2차유체로 간주되는 입자 분산 고분자 용액에 대한 막대상승 실험에서 얻는 고분 자 용액의 탄성 발현에 의한 상승높이에 비례하는 막대오름상수 $\beta$값으로부터 유변학적 특 서치들을 구할수 있었다. 이러한 막대오름상수 $\beta$값은 PIB/PB 및 kaolinite/PIB/PB계에서 용매 점도, 입자 농도와 PIB의 농도가 높을수록 증가하는 반면 온도에는 반비례함을 보이는 데 고분자 용융체에서와는 달리 입자 분산고분자 용액의 경우 입자의 농도가 증가함에 따라 탄성도 증가하는 특징적 거동을 관찰하였다. 한편 Physica MC-120과 RMS 800 Rheometer 를 사용하여 PIB 고분자 용액의 유변학적 물성들을 측정하였으며 2차 유체 구성방정식에 근거하여 얻어지는 유변학적 특성치들과 비교하였다.

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.16 no.1 s.106
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• pp.3-11
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• 2006

This paper presents a new approach for hysteresis modeling of a magnetorheological (MR) fluid. The field-dependent hysteresis of MR fluid is investigated using the Preisach model. The commercial MR product (MRF-132LD, Lord Corporation) is employed. Its field-dependent shear stress is then obtained using a rheometer (MCR 300, Physica). In order to show the applicability of the Preisach model to the MR fluid, two significant properties; the minor loop property and the wiping-out. property are experimentally examined. Subsequently, the Preisach model for the MR fluid is identified using experimental first order descending (FOD) curves in discrete manner. The effectiveness of the identified hysteresis model is verified in the time domain by comparing the predicted field-dependent shear stress with the measured one. In addition, the hysteresis model proposed in this work is compared to Bingham model.

• Archives of Pharmacal Research
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• v.19 no.3
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• pp.183-190
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• 1996

There are a wide variety of semi-solid ointments used for healing the skin diseases, whose therapeutic and skin penetration abililties may greatly differ from one another depending on the compositions of ointment vehicles. A computer optimization technique was applied to obtain the optimum formula of o/w type ointment giving the in vitro maximum absorption rate through hairless rat skin membrane. Some of the formulations were selected to find out a relationship between skin penetration of ointment and its Theological characteristics. The experimental value of absorption rate obtained from the ointment by optimum formula agreed well with the theoretical value obtained from a polynomial regression analysis, Three kinds of ointments selected among 15 formulations were obtained with a concentric cylinder type rheometer (Model; Rheolab SM-HM Physica, Germany) at 20, 30, 40 and $50^{\circ}C$ for rheograms of rhelolgical properties of o/w type ointments. As the temperature was raised, all products showed a decrease in both shear stress and yield values. The higher skin penetration, the lower shear stress showed.

• Review of KIISC
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• v.29 no.2
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• pp.23-28
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• 2019

산업제어시스템은 물리적인 현장장치의 상태를 기반으로 시스템과 시스템 내부의 프로세스들을 제어, 유지하는 CPS(Cyber Physica System)으로 볼 수 있다. 하지만 IT 시스템의 유입과 더불어 IT 시스템이 보유하고 있는 보안위협 또한 상속되었고 그에 따라 IT 시스템에서 사용하는 보안 대응책을 산업제어시스템에도 적용해야 한다. 본 논문에서는 산업제어시스템과 유사한 CPS인 교통신호제어시스템의 표준규격서에 통신보안으로 규격화 되어있는 SSL VPN을 산업제어시스템에 적용할 때 만족하는 보안요구사항을 살펴보고, 더불어 산업제어시스템에서의 보안 적용 시 반드시 고려해야 하는 가용성과 관련한 성능측정 결과를 보이고 결과분석을 수행한다.

• Proceedings of the Materials Research Society of Korea Conference
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• 1994.11a
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• pp.125-126
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• 1994

The chemorheological changes and kinetics during curing reaction of an silica filled epoxy system (DGEBA with curing agent Polyxoypropylenediamine) were investigated. This study concentrates on the influence of silica on the reaction kinetics and rheological behavior of the eopxy system. The concentration of the filler was varied 0~200phr. Curing behavior of the silica filled epoxy system was measured at various heating rates with DSC. Conversion was also measured by integrating the obtained DSC curve and Kinetic parameters measured by using the nonlinear regression method. DSC experiments showed that the presence of silica was found to accelerate the progress of the curing reaction and of reduce the heat of reaction compared with that of unfilled epoxy systems . Rheological experiments were conducted on a Physica by using a disposable parallel plate fixture. Material properites were measured such as the elastic modulus(G′), the loss modulus(G"), the loss tangent(tan $\delta$), and the viscosity was at the initial stahe, and the more the silica filler was added, and the lower the gel temperature was in the epoxy system. In this study it is concluded that the curing of the silica filled epoxy system was found to be accelerated, as silica was added to the epoxy compound.