• 제목/요약/키워드: photoelectrochemistry

검색결과 24건 처리시간 0.022초

광촉매 반응에 의한 기상 MTBE 분해 (Photocatalytic degradation of MTBE in gas phase)

  • 박상은;주현규;정희록;전명석;오정무;강준원
    • 한국태양에너지학회 논문집
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    • 제21권2호
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    • pp.55-67
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    • 2001
  • This study contains the photocatalytic degradation of methyl-tert-butyl ether(MTBE), one of water-contaminating substances, into $CO_2$. Herein was investigated factors, kinetics, and reaction pathways related with MTBE degradation. This works is possible to be applied in the field of environmental remediation such as undergroundwater purification with optimized system configuration in the near future.

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광촉매 반응 시스템을 위한 광섬유 광특성 조사 (Study on the characteristics of optical fiber for photocatalytic system)

  • 정희록;주현규;박상은;전명석;오정무;문일
    • 한국태양에너지학회 논문집
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    • 제21권2호
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    • pp.45-54
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    • 2001
  • In this study, the characteristics of optical fibers for the application in photocatalytic system was investigated using the intentionally designed accessories for spectrometer and radiometer to resolve the problems associated with the conventional system such as cost and structural restrictions from artificial lamp usage, to broaden the application fields into underground, and to utilize solar light in the future. To do this two kinds of optical fibers, plastic optical fiber (POF) and quartz optical fiber (QOF) were compared in terms of characteristics related with light transmittance and absorption and reactivity in TCE degradation.

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Photoelectrochemical Deposition of CdZnSe Thin Films on the Se-Modified Au Electrode

  • Ham, Sun-Young;Jeon, So-Yeon;Lee, Ungki;Paeng, Ki-Jung;Myung, No-Seung
    • Bulletin of the Korean Chemical Society
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    • 제29권5호
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    • pp.939-942
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    • 2008
  • Photoelectrochemical deposition of CdZnSe thin films on the Se-modified Au electrode using electrochemical quartz crystal microgravimetry (EQCM) and voltammetry is described. Corrosion of pre-deposited Se electrodes by illumination at a fixed potential resulted in $Se^{2-}$ species, which was manifest from the EQCM frequency changes. $Se^{2-}$ species generated from the photocorrosion reacted with $Cd^{2+}$ and $Zn^{2+}$ ions in the electrolyte to form CdZnSe films on the Au electrode. The effect of electrolyte composition on the composition and band gap of CdZnSe films was studied in detail. Also, photoelectrochemistry, EDX, Raman spectroscopy were used for the characterization of CdZnSe thin films.

Photoelectrochemical Hydrogen Production on Textured Silicon Photocathode

  • Oh, Il-Whan
    • 전기화학회지
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    • 제14권4호
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    • pp.191-195
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    • 2011
  • Wet chemical etching methods were utilized to conduct Si surface texturing, which could enhance photoelectrochemical hydrogen generation rate. Two different etching methods tested, which were anisotropic metal-catalyzed electroless etching and isotropic etching. The Si nano-texture that was fabricated by the anisotropic etching showed ~25% increase in photocurrent for H2 generation. The photocurrent enhancement was attributed to the reduced reflection loss at the nano-textured Si surface, which provided a layer of intermediate density between water and the Si substrate.

New Field in Photoelectrochemistry: Photocatalytic, Super-hydrophilic and Super-hydrophobic Functions of $TiO_2$ Coatings

  • Fujishima Akira;Hashimoto Kazuhito
    • 전기화학회지
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    • 제3권2호
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    • pp.81-84
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    • 2000
  • This article deals with various photochemical processes occurring at $TiO_2$ surface and its applications in practical living conditions. In the first part, we present an overview of $TiO_2$ photocatalysis under weak W illumination with a special emphasis on bactericidal and detoxification properties of $TiO_2$ films. The second part deals with the photoinduced super hydrophilic TiCt surftce which has a wide commercial applications. In the last part, we present our recent work on boehmite-based super hydrophobic surfaces containing small amount of $TiO_2$ to obtain self-cleaning effect.

Dye-Sensitized Metal Oxide Nanostructures and Their Photoelectrochemical Properties

  • Park, Nam-Gyu
    • 전기화학회지
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    • 제13권1호
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    • pp.10-18
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    • 2010
  • Nanostructured metal oxides have been widely used in the research fields of photoelectrochemistry, photochemistry and opto-electronics. Dye-sensitized solar cell is a typical example because it is based on nanostructured $TiO_2$. Since the discovery of dye-sensitized solar cell in 1991, it has been considered as a promising photovoltaic solar cell because of low-cost, colorful and semitransparent characteristics. Unlike p-n junction type solar cell, dye-sensitized solar cell is photoelectrochemical type and is usually composed of the dye-adsorbed nanocrystalline metal oxide, the iodide/tri-iodide redox electrolyte and the Pt and/or carbon counter electrode. Among the studied issues to improve efficiency of dye-sensitized solar cell, nanoengineering technologies of metal oxide particle and film have been reviewed in terms of improving optical property, electron transport and electron life time.