• 제목/요약/키워드: phase changing material

검색결과 76건 처리시간 0.028초

TTIP를 이용한 저온소성용 TiO2 페이스트 최적화 (Optimized for Low-temperature Sintering of TiO2 Paste with TTIP)

  • 정유라;;구할본
    • 한국전기전자재료학회논문지
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    • 제26권8호
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    • pp.608-613
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    • 2013
  • In this paper, the low-temperature sintering of $TiO_2$ is approached to solve the problem of high temperature sintering which decreases the interconnection between particles or between substrate and particle. $TiO_2$ paste is prepared with Titanium (IV) isopropoxide as the precursor material and calcinate at different conditions (low temperature). In the results, since the changing of temperature and time of sintering, crystalline phase do not change and the intensities of anatase, rutile phase are higher. At $110^{\circ}C$, 7 h sintering condition, crystalline size of anatase and rutile phase are the smallest which are 13.07 and 17.47 nm, respectively. In addition, the highest zeta potential is about 32.77 mV and the repulsive force increases thus leading to the best of the dispersion characteristics between $TiO_2$ particles. Futhermore, DSSCs at that condition exhibits the highest efficiency with the values of $V_{oc}$, $J_{sc}$, FF and ${\eta}$ are 0.69 V, $8.60mA\;cm^{-2}$, 67.93% and 4.06%, respectively.

RIETAN 및 MEED법에 의한 다상시료의 결정구조 및 정량상 분석 (Crystal Structure and Quantitative Phase Analysis of Multiphase Sample using RIETAN and MEED)

  • 김광복;천희곤;조동율;신종근;구경완
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
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    • pp.303-307
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    • 2000
  • The crystal structure of ZnS fabricated by gas-liquid phase reaction was obtained by XRD and refined by RIETAN near R$_{wp}$ factor 10%. The increasement of HCP phase depended on extra H$_2$S gas and the lattice parameter and crystalline size changed by the relative ratio of multiphase. Using ZnS of the different multiphase ratio and crystalline size, sintered ZnS:Cu, Al green phosphor and the CL property resulted optimum luminescence in the range of 91~94% and 150~190$\AA$, respectably, FCC/HCP ratio and crystalline size. As changing of structure ratio, the reason of different luminescence property is now studying. As well as, after XRD pattern of TiO$_2$powder fitted by RIETAN and the structure factor using MEED method simulated about each atom of (002) plane. Additionally, we proposed RIETAN and MEED were the methods of the study of luminescence mechanism for many phosphor materials.s.

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저온 PCM 혼입을 위한 경량기포콘크리트의 배합설계 및 기계적 특성 (Mix Design and Mechanical Properties of Aerated Concrete for Incorporation of Low Temperature PCM)

  • 밧짜야 바산쿠;임명관;임희섭;최동욱
    • 한국구조물진단유지관리공학회 논문집
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    • 제21권4호
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    • pp.110-115
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    • 2017
  • 이 연구는 상변화 물질(저온 PCM)을 포함한 경량 콘크리트의 기계적 성능을 검토하기 위해 수행되었다. Micro capsulised PCM은 wax type core와 melamine based wall으로 구성되어있다. 또한, 단일 종류의 PCM의 경우, Vermiculite에 파라핀 왁스를 삽입하고 그 표면을 멜라민 수지로 코팅 하였다. 계면 중합은 1-dodecanol(핵심 물질)과 물(용매) 사이의 표면에서 중합반응이 일어나 벽 물질을 형성한다는 원리에 기반한다. 경량 콘크리트는 10 MPa의 압축 강도, 1.5 MPa의 인장 강도 및 1.0 kg/L의 절건 밀도를 가지며 10 %, 20 % 또는 30 %의 PCM을 포함하고 있다. 이를 위해 예비 배합으로 경량 기포 콘크리트($1.0kg/m^3$)를 제조 한 후 1-dodecanol 및 멜라민의 PCM 마이크로 캡슐과 혼합하여 그 물성을 조사하였다.

PCM 기술의 콘크리트 적용 II : 계면중합법에 의한 1-도데카놀 마이크로 캡슐에 있어서 계면활성제로 사용된 SSMA의 표면활성도가 마이크로 캡슐의 특성에 미치는 영향 (Application of PCM Technology to Concrete II : Effects of SSMA(Sulfonated Styrene-Maleic Anhydride) on the Properties of the 1-Dodecanol Micro-Capsule)

  • 신세순;정재윤;임명관;최동욱;김영호
    • 한국건설순환자원학회논문집
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    • 제1권1호
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    • pp.17-25
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    • 2013
  • 축열재 이용 기술은 실내 냉난방을 위하여 사용된 에너지를 장시간 일정온도로 유지할 수 있도록 하여 에너지 사용 효율을 높이는 장점이 있다. 이 중 상변화 물질을 이용한 잠열 축열재는 물질의 잠열성질을 이용하는 것으로서 심물질로서 일정온도에서 녹는점을 갖는 물질을 캡슐화 하여 이를 건축자재에 적용하여 실내 및 외기의 온도에 따라서 심물질이 녹거나 어는 과정에서 축열과 방열로 인한 에너지 절감 및 차단 효과를 갖는다. 상변화 물질을 이용해 축열재를 만드는 방법은 마이크로 캡슐화의 방법이 있다. 이 방법은 크게 분류하면 화학적 방법, 물리 화학적 방법 및 물리적 기계적 방법의 3가지로 나눌 수 있다. 물리 화학적 방법으로 습식공정에 의한 마이크로 캡슐화 공정을 이용했으며 이 공정은 심물질을 용매에서 에멀젼화한 다음 고분자모노머를 심물질인 에멀젼의 벽면에 코팅하여 경화 시키는 공정이다. 이 경우에 심물질의 에멀젼이나 벽재 모노머의 코팅 성능을 좋게 하기 위하여 계면활성제가 사용된다. 또한 계면활성제의 특성에 따라서 마이크로 캡슐화의 성능이 좌우되고 특히 벽재물질의 코팅 두께 및 코팅의 균일성에 크게 좌우된다. 본 연구에서는 상변화를 이용한 축열재로서 심물질인 1-도데카놀을 멜라민수지로 계면중합법에 의하여 마이크로 캡슐화 하는데 있어서 계면활성제인 SSMA(sulfonated styrene-maleic anhydride)의 화학적 특성에 따른 마이크로 캡슐의 성능과 이에 따른 축열 성능을 비교하였다.

현대패션에 표현된 dynamism의 조형성 연구 (A Study on the Formation of Dynamism in the Modern Fashion)

  • 이은숙
    • 한국의상디자인학회지
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    • 제4권1호
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    • pp.143-153
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    • 2002
  • Fashion has been analyzed and explained in diverse ways. Fashion, like every phase of culture, is a reflection of the Zeitgeist. In order to understand the changing fashion we must understand the changing society. For fashion of a period are expressions of the interrelation of the various elements of the culture, including the social and political values, the economic and industrial progress, art, the development of technology, etc... Particularly fashion is closely connected with a style of art. In a style of art, futurism focused on the "dynamism" resulting from super-speed and high-technology. This study aimed to review literatures, fashion magazines, web-site in order to know how the dynamism of futurism is expressed in modern fashion. The results of this study were as follows; 1. Dynamism was expressed by means of lines, colors, patterns through the eyesights visually. Asymmetrical oblique lines, zig-zag lines or bold cutting expressed the mechanical and offensive dynamism. In contrast, such lines as curves and spirals expressed the soft and natural dynamism. Primary colors or complementary contrast expressed energetic and rhythmical dynamism. The geometrical patterns and automobile wheels patterns expressed dynamism resulting from mechanical aesthetics. 2. Dynamism was expressed through repeat of lines, colors, patterns, and textiles. Particularly Vinyl material, fluorescent material, metallic material, beads, and spangle expressed a strong dynamism. On the other hand, natural materials, paper and other similar ones are used to signify the orientation towards a futuristic high-technology society.y society.

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Effect of Phase Stability on the Microstructure Development of α-SiAlON Ceramics

  • Kim, Joosun;Lee, Hae-Weon;Chen, I-Wei
    • 한국분말재료학회지
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    • 제10권2호
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    • pp.118-122
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    • 2003
  • Alpha-SiAlON ceramics having various compositions and modifying cations were investigated with respect to their phase stability, transformation kinetics. and resulting microstructures. Each composition was heat treated at 150$0^{\circ}C$ for 1h and measured the $\alpha$-SiAlON transformation. The phase-boundary composition in the single-phase $\alpha$-SiAlON region showed sluggish transformation from $\alpha$-$Si_3N_4$ to $\alpha$-SiAlON compared to the phase-center composition in the diagram. Using the different rare earth modifying cations, dependence of transformation kinetics on the phase stability in a fixed composition was also explained. By changing size of the stable u-phase region with exchanging cations, systematic change in transformation was observed. Transformation rate of $\alpha$-SiAlON at low temperature has an important role on controlling the final microstructure. Less transformation gives more chances to develop elongated grain in the microstructure.

태양광패널 온도제어를 위한 PCM시스템 최적화에 관한 실험적 연구 (Experimental study for optimizing the thermal regulating system with phase change material on the photovoltaic panel)

  • 이효진;전종한
    • 한국태양에너지학회:학술대회논문집
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    • 한국태양에너지학회 2009년도 추계학술발표대회 논문집
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    • pp.273-278
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    • 2009
  • The experimental study is performed to investigate the optimum design of the system dissipating properly heat from the in-situ solar panel installed on site. For this purpose, six 12-Watts panels, which are set at the different conditions of the solar panels contained phase change material, changing the array of the aluminum fin and honeycomb at the back of the panel, are tested. PCM, which has $44^{\circ}C$ melting point, is chosen in this study. In order to enhance the thermal heat from the absorbed heat in PCM, finned aluminum plate is placed. Furthermore, Aluminum honeycomb is imbedded in the back container to find if it would improve the thermal conductivity of PCM. As a result, the solar panel, which is combined with honeycomb and outward fins with PCM instead of placing the fine inward, is showing the best performance in terms of controling panel temperature and efficiency.

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상변환물질을 활용한 태양광 패널 표면온도 제어효과 및 최적화 시스템 (Temperature Control for PV Panel Absorbing Heat by Phase Change Material and its Estimation)

  • 이효진;전종한
    • 한국태양에너지학회 논문집
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    • 제30권2호
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    • pp.10-15
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    • 2010
  • The experimental study was conducted to optimize the system dissipating properly heat from the in-situ solar panel installed on the roof. For this purpose, six 12-Watt panels, which were consisted of the different design conditions such as containing phase change material(PCM), changing the array of the aluminum fin and honeycomb at the back of the panel, were tested. PCM, which had $44^{\circ}C$ melting point, was chosen in this study. In order to enhance absorbing and expelling heatin PCM, profiled aluminum fin was placed either inward oroutward from the panel. Furthermore, Aluminum honeycomb is imbedded in the back container to find if it would improve the thermal conductivity of PCM. During the experiment, there were ranged to $26^{\circ}C\sim32^{\circ}C$ for outdoor temperature and $700W/m^2\sim1000W/m^2$ for irradiance. As a result, the solar panel, combined with honeycomb and outward fins with PCM instead of placing the fins inward, is showing the best performance in terms of controling panel temperature and its efficiency.

Liquid-phase epitaxy로 성장시킨 A $I_x$Ga${1-x}$As(x.<=.0.15)의 photoreflectance (Photoreflectance of A $I_x$Ga${1-x}$As(x.<=.0.15) grown by liquid-phase epitaxy)

  • 배인호;김인수;이철욱;최현태;김말문;김상기
    • E2M - 전기 전자와 첨단 소재
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    • 제7권4호
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    • pp.300-305
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    • 1994
  • We determined the alloy composition of the liquid-phase epitaxy(LPE) grown $Al_{x}$G $a_{1-x}$ As by the photoreflectance(PR), and observed the variation of PR signal by changing the condition of annealing and thickness of epilayer. As the measuring temperature was decreased, the broadening parameter was decreased, and the amplitude of PR signal was increased. When the temperature of annealing was increased, the surface carrier concentration was decreased and then the shape and amplitude of PR signal were affected by the surface electric field. The structure change was observed when the specimen was annealed for long time at a high temperature. We found that the surface electric field increased when the thickness of epilayer was decreased by etching, because the band bending was increased by the decreased of the width of depletion layer....

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카본블랙/섬유강화 복합재료의 전자파 차폐효과 (Electromagnetic Interference shielding effectiveness of carbon black / Glass fiber woven roving and Carbon fiber unidirectional fabric reinforced composite)

  • 김진석;한길영;안동규;이상훈;김민수
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2005년도 춘계학술대회 논문집
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    • pp.1322-1325
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    • 2005
  • The main objectives of this research work are to develop conductive glass fiber woven roving and carbon fiber unidirectional fabric composite materials and to determine their electromagnetic shielding effectiveness(EMSE). Epoxy is the matrix phase and glass, carbon fiber are the reinforcement phase of the composite material. Carbon black are incorporated as conductive fillers to provide the electromagnetic shielding properties of the composite material. The amount of carbon black in the composite material is varied by changing the carbon black composition, woven roving and unidirectional (fabric) structure. The EMSE of various fabric composites is measured in the frequency range from 300MHz to 800MHz. The variations of EMSE of woven roving and unidirectional composites with fabric structure, metal powder composite are described. Suitability of conductive fabric composites for electromagnetic shielding applications is also discussed.

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