• Title/Summary/Keyword: petrochemical study

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A Study on the Characteristics of $PM_{10}$ and Air-borne Metallic Elements Produced in the Industrial City (산업도시 대기 중$PM_{10}$의 농도 및 금속원소 성분의 특성 연구)

  • 나덕재;이병규
    • Journal of Korean Society for Atmospheric Environment
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    • v.16 no.1
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    • pp.23-35
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    • 2000
  • PM10, which is below 10 ${\mu}{\textrm}{m}$ in a diameter, has a high deposition in the lung or the bronchus by breathing and is generally composed of a lot of organic matters, viruses, algae, mold, and metallic elements that are very toxic to people. This study identified the characteristics of concentration of PM10 and air-borne jmetallic elements produced in the industrial city, Ulsan, and analyzed the correlatuion between sources and generation patterns of PM10 and metallic elements. We classified the five areas(green, residential, heavy traffic, mechanic, and petrochemcal and non-ferrous metal) which might have different characteristics of sources of PM10 and metallic elements. The average concentrations of PM10 in the five areas were as follows(petrochemical and non-ferrous metal(99.9$\mu\textrm{g}$/㎥)>mechanic(77.5 $\mu\textrm{g}$/㎥)>heavy traffic(47.1 $\mu\textrm{g}$/㎥)>residential(39.3 $\mu\textrm{g}$/㎥)>green(32.8 $\mu\textrm{g}$/㎥)). Those of petrochemical and non-ferrous metal areas were higher than other areas. In this study, the average concentration trend of metallic elements contained in PM10 are shown as follows: Fe>Zn>Pb>Cu>Mn>Cr>As>Cd>Sn>Hg, respectively. The metallic elements identified in PM10 showed the highest concentration in the petrochemical and non-ferrous areas. Metal combinations showed that a high correlation among concentrations of heavy metals were as follows: As, Cd and Fe in the residential area; Zn, Mn, Cu and Pb in the mechanical area; and Zn, Cu, As, Pb in the petrochemical and non-ferrous industrial area.

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Development of the vac Source Profile using Collinearity Test in the Yeosu Petrochemical Complex (여수석유화학산단의 공선성 시험을 이용한 VOC 오염원 분류표 개발)

  • Jeon Jun-Min;Hur Dang;Hwang In Jo;Kim Dong-Sul
    • Journal of Korean Society for Atmospheric Environment
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    • v.21 no.3
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    • pp.315-327
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    • 2005
  • The total of 35 target VOCs (volatile organic compounds), which were included in the TO-14, was selected to develop a VOCs' source profile matrix of the Yeosu Petrochemical Complex and to test its collinearity by singular value decomposition(SVD) technique. The VOCs collected in canisters were sampled from 12 different sources such as 8 direct emission sources (refinery, painting, wastewater treatment plant, incinerator, petrochemical processing, oil storage, fertilizer plant, and iron mill) and 4 general area sources (gasoline vapor emission, graphic art activity, vehicle emission, and asphalt paving activity) in this study area, and then those samples were analyzed by GC/MS. Initially the resulting raw data for each profile were scaled and normalized through several data treatment steps, and then specific VOCs showing major weight fractions were intensively reviewed and compared by introducing many other related studies. Next, all of the source profiles were tested in terms of degree of collinearity by SVD technique. The study finally could provide a proper VOCs' source profile in the study area, which can give opportunities to apply various receptor models properly including chemical mass balance (CMB).

A Study on Installation of Removal Device for Volatile Organic Compounds from Petrochemical Plant (석유화학 공장에서 VOCs 제거시설 설치사례 연구)

  • 김석택
    • Journal of environmental and Sanitary engineering
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    • v.15 no.2
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    • pp.95-101
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    • 2000
  • High growth of economy and industrial development was produced every air pollutants, that is, SOx, NOx, dust, VOCs and malodorous gas was produced. Recently, volatile organic compounds(VOCs) was bring about very serious environmental problems. Ulsan petrochemical complex was densely a large scale of petrochemical plant. This study was carried out to select treatment equipment of VOCs produced from petrochemical plant, and has compared with Carbon filter, Regenerative thermal oxidation(RCO) and Flare stack for technical merit and demerit but also initial investment and operating cost.

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A Study on the Relationship between Transshipment and Import-Export Volume of Petrochemical Liquid Cargoes (석유화학 액체화물의 환적과 수출입 물동량 관계연구)

  • Shin, Chang-Hoon;Yang, Han-Na
    • Journal of Korea Port Economic Association
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    • v.36 no.4
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    • pp.1-16
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    • 2020
  • Since Korea has excellent port infrastructure and competitive petrochemical complexes, there is plenty of potential for creating an oil hub in Northeast Asia. In particular, Ship-to-Ship (STS), which creates high added values, contributes greatly to the national economy. In this study, the liquid cargo volumes of chemical industrial products, refined petroleum products, and crude oil were analyzed at the national and regional (Busan, Ulsan, and Yeosu/Gwangyang) levels. Additionally, a Granger causality analysis was performed between imports, exports, and transshipments, in pairs. ADF, PP, and KPSS were analyzed for the unit root test. In addition, the VAR model and expanded VAR model suggested by Toda and Yamamoto were used for further analyses. Findings revealed a difference in Granger causality depending on the region or cargo type. These findings suggest that policies and incentive schemes for ports need to be differentiated according to the region and cargo types. In addition, the different patterns in the relationship between transshipments and import-export petrochemical cargoes should be considered.

A Study on the Analysis and Protection of Lightning Accident in Petrochemical Plant Wastewater Storage Tank (석유화학공장 폐수 저장 탱크의 낙뢰사고 분석과 보호방안에 관한 연구)

  • Song, Bang-Un;Oh, Gil-Jung;Woo, In-Sung
    • Fire Science and Engineering
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    • v.33 no.2
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    • pp.107-113
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    • 2019
  • Recently, due to global warming, the trend shows an increase in number of lightning strikes which increase risk regarding industry infrastructures. Especially in case where the lightning strikes infrastructures including refinery, petorchemical plant facilities or storage tanks, it can cause power failures, electrical machine malfunction and damage which can lead to fire explosion and multiple calamities. Therefore, detailed case studies must be conducted through a systematic research regarding lightning strike accidents in order to understand its mechanism and devise preventive measures. This paper aims to study cases of explosion regarding waste water storage tanks in refineries and petrochemical plants in order to analyze its root cause and provide preventive measures for avoiding lightning related incidents.

Analyzing the Impact of Inventory Management Performance on the Energy Efficiency in Korean Petrochemical Companies (재고관리성과가 에너지효율성에 미치는 영향에 대한 실증분석 : 국내 석유화학 기업을 대상으로)

  • Kim, Gilwhan;Lee, Jiwoong
    • Korean Management Science Review
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    • v.34 no.3
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    • pp.1-14
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    • 2017
  • This study empirically analyzes the impact of inventory management performance on the energy efficiency in Korean petrochemical companies. The concept of the distance function is used to define the energy efficiency and the estimation of the distance function is performed using the stochastic frontier analysis. The inventory turnover is selected as the variable indicating the inventory management performance of the company. The main results of this study are as follows. First, the inventory turnover has a positive impact on energy efficiency. Second, during the period over 2011~2015, while the gap in energy efficiency among the companies expanded, the average energy efficiency decreased. Third, the average energy efficiency in upstream process companies was greater than downstream process companies and the gap in energy efficiency among downstream process companies was greater than upstream process companies. Fourth, the average marginal effect of inventory turnover on energy efficiency increased gradually from 2011 to 2015. Finally, the average marginal effect of inventory turnover in downstream process companies was greater than upstream process companies, and the gap in the marginal effect of inventory turnover among downstream process companies was greater than upstream process companies. These results together imply the importance of inventory management in terms of energy efficiency.

The feasibility and properties of dividing virtual machine resources using the virtual machine cluster as the unit in cloud computing

  • Peng, Zhiping;Xu, Bo;Gates, Antonio Marcel;Cui, Delong;Lin, Weiwei
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.9 no.7
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    • pp.2649-2666
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    • 2015
  • In the dynamic cloud computing environment, to ensure, under the terms of service-level agreements, the maximum efficiency of resource utilization, it is necessary to investigate the online dynamic management of virtual machine resources and their operational application systems/components. In this study, the feasibility and properties of the division of virtual machine resources on the cloud platform, using the virtual machine cluster as the management unit, are investigated. First, the definitions of virtual machine clusters are compared, and our own definitions are presented. Then, the feasibility of division using the virtual machine cluster as the management unit is described, and the isomorphism and reconfigurability of the clusters are proven. Lastly, from the perspectives of clustering and cluster segmentation, the dynamics of virtual machines are described and experimentally compared. This study aims to provide novel methods and approaches to the optimization management of virtual machine resources and the optimization configuration of the parameters of virtual machine resources and their application systems/components in large-scale cloud computing environments.

The Relationship between Workers' Safety Behaviors and Safety Climate in Chemical Industry (화학산업 작업자의 안전행동과 안전분위기의 상관관계)

  • Baek, Jong-bae;Uhm, Minyong;Kim, Ji-sun
    • Journal of the Korean Society of Safety
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    • v.30 no.5
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    • pp.100-107
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    • 2015
  • Korea government has established and enforced countermeasures about the various policy of industrial accident prevention. Recent chemical accidents included hazardous materials. Exposure to these chemicals can cause serious environmental poisoning and various health problems. The key factor causing these major accidents may be associated with the mistake in workers' safety behaviors. Some researchers noted workers' safety behaviors may be related to workers' safety climate. In this research, a survey was conducted to explore workers' safety behaviors and safety climate in a large petrochemical company in Korea. The company processes major petrochemical materials and any spills can be hazardous and cause chemical disasters. In this study, we explored one petrochemical company to investigate three hypotheses. 593 workers were surveyed for this study. We checked association between workers' safety behavior and safety climate. The survey result shows the people who have safety climate do safe behavior.

A Study on Vibrational Characteristics of Piping Systems in Petrochemical Plants Considering the Fluid Velocity and Pressure (유체의 속도와 압력을 고려한 석유화학 플랜트 배관계의 진동특성에 대한 연구)

  • Kim, Kyoung-Hoon;Kim, Jeong-Hoon;Choi, Myung-Jin
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2006.05a
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    • pp.1053-1060
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    • 2006
  • This paper consider an initially deformed state caused by the pressurized fluid flowing through the pipe at a constant velocity. When the initial forte is neglected in curved pipes, the natural frequencies are reduced as flow velocity increases. However, when the initial tension took into account, the natural frequencies are not changed with the change of the flow velocity. As the internal pipe pressure is increased the natural frequencies are also slightly increased. In free vibrational simulation of piping systems in petrochemical plants, it is necessary to calculate the initial state force due to the velocity and the pressure of the fluid flow from the equilibrium first, then the force should be included in the equation of motion of the systems to get more accurate natural frequencies. In this study, calculate the mass matrix and stiffness matrix of piping system by MATLAB

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Characteristics of Occupational Exposure to Benzene during Turnaround in the Petrochemical Industries

  • Chung, Eun-Kyo;Shin, Jung-Ah;Lee, Byung-Kyu;Kwon, Ji-Woon;Lee, Na-Roo;Chung, Kwang-Jae;Lee, Jong-Han;Lee, In-Seop;Kang, Seong-Kyu;Jang, Jae-Kil
    • Safety and Health at Work
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    • v.1 no.1
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    • pp.51-60
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    • 2010
  • Objectives: The level of benzene exposure in the petrochemical industry during regular operation has been well established, but not in turnaround (TA), where high exposure may occur. In this study, the characteristics of occupational exposure to benzene during TA in the petrochemical companies were investigated in order to determine the best management strategies and improve the working environment. This was accomplished by evaluating the exposure level for the workers working in environments where benzene was being produced or used as an ingredient during the unit process. Methods: From 2003 to 2008, a total of 705 workers in three petrochemical companies in Korea were studied. Long- and short-term (< 1 hr) samples were taken during TAs. TA was classified into three stages: shut-down, maintenance and start-up. All works were classified into 12 occupation categories. Results: The long-term geometric mean (GM) benzene exposure level was 0.025 (5.82) ppm (0.005-42.120 ppm) and the short-term exposure concentration during TA was 0.020 (17.42) ppm (0.005-61.855 ppm). The proportions of TA samples exceeding the time-weighted average, occupational exposure level (TWA-OEL in Korea, 1 ppm) and the short-term exposure limit (STEL-OEL, 5 ppm) were 4.1% (20 samples of 488) and 6.0% (13 samples of 217), respectively. The results for the benzene exposure levels and the rates of exceeding the OEL were both statistically significant (p < 0.05). Among the 12 job categories of petrochemical workers, mechanical engineers, plumbers, welders, fieldman and scaffolding workers exhibited long-term samples that exceeded the OEL of benzene, and the rate of exceeding the OEL was statistically significant for the first two occupations (p < 0.05). Conclusion: These findings suggest that the periodic work environment must be assessed during non-routine works such as TA.