Development of the vac Source Profile using Collinearity Test in the Yeosu Petrochemical Complex

여수석유화학산단의 공선성 시험을 이용한 VOC 오염원 분류표 개발

  • Jeon Jun-Min (Department of Environmental Engineering, Suncheon First College) ;
  • Hur Dang (Department of Environmental Engineering, Suncheon First College) ;
  • Hwang In Jo (Industrial Liaison Research Institute, Kyung Hee University) ;
  • Kim Dong-Sul (College of Environment & Applied Chemistry and Center for Environmental Studies, Kyung Hee University)
  • 전준민 (순천제일대학 환경과) ;
  • 허당 (순천제일대학 환경과) ;
  • 황인조 (경희대학교 산학협력기술연구원) ;
  • 김동술 (경희대학교 환경응용화학대학 대기오염연구실 및 환경연구센터)
  • Published : 2005.06.01

Abstract

The total of 35 target VOCs (volatile organic compounds), which were included in the TO-14, was selected to develop a VOCs' source profile matrix of the Yeosu Petrochemical Complex and to test its collinearity by singular value decomposition(SVD) technique. The VOCs collected in canisters were sampled from 12 different sources such as 8 direct emission sources (refinery, painting, wastewater treatment plant, incinerator, petrochemical processing, oil storage, fertilizer plant, and iron mill) and 4 general area sources (gasoline vapor emission, graphic art activity, vehicle emission, and asphalt paving activity) in this study area, and then those samples were analyzed by GC/MS. Initially the resulting raw data for each profile were scaled and normalized through several data treatment steps, and then specific VOCs showing major weight fractions were intensively reviewed and compared by introducing many other related studies. Next, all of the source profiles were tested in terms of degree of collinearity by SVD technique. The study finally could provide a proper VOCs' source profile in the study area, which can give opportunities to apply various receptor models properly including chemical mass balance (CMB).

Keywords

References

  1. 건설교통부(2001) 도로교통통계 연보
  2. 국립환경연구원 (1996) 유해가스 배출량 산정에 관한 연구 (III), 제 18권,93-102
  3. 김동술(1990) 황사의 양적추정을 위한 기초연구, 한국대기 보전학회지,6(1),11-12
  4. 백성옥, 깅영민, 황승만(1998) 고속도로 터낼내부 공기 중 휘발성유기화합물의 농도 측정, 한국대기보전학 회지,14(1),73-77
  5. 이영재 (2001) 광주지역 대기 중 휘발성유기화합물의 농도 및 오염원 특성에 관한 연구,박사학위논문
  6. 영산강환경청 (2000) 여수산단 VOCs 배출량 보고자료
  7. 전준민, 허 당, 김동술(2005) 여수석유화학산단내 VOCs에 대한 오염원 분류표의 개발 벚 CMB 모델에 의한 기여도 산정, 한국대기환경학회지,21(1),83-96
  8. 전준민, 허 당, 검동술(2003) 여수산단 대기 중 휘발성유기 화합물질 농도 경향, 한국대기환경학회지, 19(6), 663-677
  9. 전준민, 허 당, 김동술(2002) Canister와 GC/MSD를 이용한 대기 중 VOCs 분석시스템의 정도관리 (QC), 한국 대기환경학회지, 18(6),527 -538
  10. 환경부(1997) 대기오염물질 위해성펑가 빛 관리기술, 제2단 계 1차년보고서,284-288
  11. Belsley, D.A., E. Kuh, and R.E. Welsch (1980) Regression Diagnostics, John Wiley & Sons, Inc., New York
  12. Chung, J., R.A. Wadden, and P.A. Scheff (1996) Development of ozone-precursor relationships using VOC receptor modeling, Atmos. Environ., 30(18), 3167-3179 https://doi.org/10.1016/1352-2310(96)00015-5
  13. Conner, T.L., W.A. Lonneman, and R.L. Seila (1995) Transportation- related volatile hydrocarbon source profiles measured in Atlanta, AWMA, 45, 383-394
  14. Duffy, B.L. and P.F. Nelson (1996) Non-methane exhaust composition in the Sydney Harbour tunnel: A focus on benzene and I, 3-butadiene, Atmos. Environ., 30,557-566
  15. Dunovant, V.S., C.S. Clark, S.S. Que Hee, V.S. Hertzberg, and J.H. Trapp (1986) Volatile organics in the wastewater and air-spaces of three wastewater treatment plants, J. Water Pollut. Control Fed., 58, 886
  16. Gertler, A.W., E.M. Fujita, W.R. Pierson, and D.N. Wittorff (1996) Apportionment of NMHC tailpipe vs. nontailpipe emissions in the Fort McHenry and Tuscarora Mountain Tunnels, Atmos. Environ., 30(12), 2297-2305 https://doi.org/10.1016/1352-2310(95)00090-9
  17. Harkov, R., J. Jenks, and C. Ruggeri (1987) Volatile organic compounds in the ambient air near a large regional sewage plant in New Jersey, paper 87-95.1. presented at the 80th annual meeting of the JAPCA, New York
  18. Kim, D.S. and P.K. Hopke (1988) Source apportionment of the El Paso aerosol by particle class balance analysis, Aerosol Sci. and Technol., 9,221 -235 https://doi.org/10.1080/02786828808959210
  19. Martens, H., M. Hby, F. Westad, D. Folkenberg, and M. Martens (2001) Analysis of designed experiments by stabilized PLS regression and jack-knifing, Chemometrics and Intelligent Laboratory System, 58, 151-170 https://doi.org/10.1016/S0169-7439(01)00157-5
  20. Na, K.S. (2002) Characteristics of atmospheric volatile organic compounds in Seoul; measurements and chemical mass balance receptor modeling, Ph.D. Dissertation, Yonsei University, Seoul, Korea
  21. Pierson, W.R., A.W. Gertler, N.F. Robinson, J.C. Sagebiel, B. Zielinska, G.A. Bishop, D.H. Stedman, R.B. Zweidinger, and W.D. Ray (1996) Real-world automotive emissions-summary of studies in the Fort Mchency and Tuscarora Mountain tunnels, Atmos. Environ., 30, 2233-2256 https://doi.org/10.1016/1352-2310(95)00276-6
  22. Quarder, S., U. Claussnitzer, and M. Otto (2001) Using singular value decompositions to classify spatial patterns generated by a nonlinear dynamic model of the olfactory system, Chemometrics and Intelligent Laboratory System, 59,45-51 https://doi.org/10.1016/S0169-7439(01)00144-7
  23. Scheff, P.A., R.A. Wadden, D.M. Kenski, and J. Chung (1996) Receptor model evaluation of the Southeast Michigan ozone study ambient NMOC measurements, AWMA, 46(11), 1048- 1057
  24. Scheff. P.A. and R.A. Wadden (1993) Receptor modeling of volatile organic compounds. I. emission inventory and validation, Environ. Sci. & Technol., 27(4), 617-625 https://doi.org/10.1021/es00041a005
  25. Scheff, P.A., R.A. Wadden, B.A. Bates, and P.F. Aronian (1989) Source fingerprints for receptor modeling of volatile organics, JAPCA, 39(4)
  26. Thijsse, T.R., R.F. van Oss, and P. Lenschow (1999) Determination of source contributions to ambient volatile organic compound concentrations in Berlin, AWMA, 49(12), 1394-1404
  27. US EPA (1989) Ethylbenzene, CASRN 100-41-4, IRIS (1/189)
  28. US EPA (1997) Compendium Method TO- 14A-Determination of Volatile Organic Compounds (VOCs) in Ambient Air Using Specially Prepared Canisters With Subsequent Analysis By Gas Chromatography, Compendium of Methods for the Determination of Toxic Organic Compounds in Ambient Air, 2nd ed., EPA/625R-96/010b
  29. Vega, E., V. Mugica, R. Carmona, and E. Valencia (2000) Hydrocarbon source apportionment in Mexico City using the chemical mass balance receptor model, Atmos. Environ., 34,4121-4129 https://doi.org/10.1016/S1352-2310(99)00496-3
  30. Wadden, R.A. and P.A. Scheff (1994) Receptor modeling of VOCs; 11. development of VOC control functions for ambient ozone, Atmos. Environ., 28(15), 2507-2521 https://doi.org/10.1016/1352-2310(94)90401-4
  31. Watson, J.G., J.C. Chow, and E.M. Fujita (2001) Review of volatile organic compound source apportionment by chemical mass balance, Atmos. Environ., 35, 1567- 1584 https://doi.org/10.1016/S1352-2310(00)00461-1