• Title/Summary/Keyword: permeability model

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The Effect of Substrate Pore Size on Gas Permeation Mechanism in Composite Membrane by Plasma Polymerization (플라즈마 중합된 고분자 복합막에서 기질의 기공크기가 기체투과 메카니즘에 미치는 영향)

  • Hyun, Sang-Won;Jung, Il-Hyun
    • Applied Chemistry for Engineering
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    • v.10 no.4
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    • pp.502-508
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    • 1999
  • We prepared non-porous membrane on the $Al_2O_3$ substrate with the different pore by the size by the plasma polymerization of $CHF_3$. We studied the permeability characteristics of membrane by Ar treatment and the effect of substrate pore size on gas permeation mechanism. The selectivity was increased with Ar plasma treatment time and rf-power near the substrate to the cathode while the permeability was decreased. It was observed that the solution-diffusion model would be applied to non-porous layers while it is applied Knudsen diffusion model to the substrate. From the experimental observation, it could be concluded that the pore size of $Al_2O_3$ membrane influenced on the permeability and the selectivity.

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The Protective Effect of Mineral Water Against UVB Irradiation (미네랄워터의 피부 장벽 보호 효과 연구)

  • Lee, Sung Hoon;Min, Dae Jin;Na, Yong Joo;Shim, Jongwon;Kwon, Lee Kyoung;Cho, Jun-Cheol;Lee, Hae Kwang
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.39 no.1
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    • pp.39-46
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    • 2013
  • Bicationic minerals such as calcium and magnesium are known to protect the skin barrier. The principal objective of this study was to evaluate the skin barrier protective effects of mineral water, which is composed of calcium, magnesium, manganese, and fluorine. UVB irradiation induces a destruction of tight junction (TJ) components. The TJ permeability barrier was also disrupted by UVB irradiation. We employed a skin equivalent model to assess the efficacy of mineral water in this regard. Mineral water maintained the structure of the skin equivalents following UVB irradiation. The results of the TJ permeability assay showed that mineral water helped to maintain the TJ permeability barrier after UVB irradiation in skin equivalent model. Mineral water supported the structure of TJ components and restored the occludin protein level in differentiated normal human keratinocytes after UVB irradiation. In conclusion, we found out the protective effect of mineral water against UVB irradiation.

Measurement of Air Tightness of Concrete Block and its Construction Joint from a Model Experiment (모형실험을 통한 콘크리트 블록 및 시공이음부의 기밀성 측정)

  • Kim, Hyung-Mok;Ryu, Dong-Woo;Synn, Joong-Ho;Song, Won-Kyong
    • Tunnel and Underground Space
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    • v.20 no.6
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    • pp.434-445
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    • 2010
  • Underground compressed air energy storage (CAES) system in a lined rock cavern is considered one of the promising large-scale energy storage technologies. In this study, permeabilities of concrete lining block and its construction joint, which are the major components of an air tightness system of the undeground CAES, were measured from a model experiment. From the experiment, it was found that intrinsic permeability of construction joint was larger than that of concrete block by the order scale of $10^1{\sim}10^4$, so that it would be very important to control the quality of construction joints in-situ in order to secure air tightness of storage system. And the permeability of construction joint could be decreased as low as that of the concrete block by pasting an acryl-type adhesive on bonding surfaces. Higher degrees of water saturation of the concrete block resulted in the lower permeability, which is more preferable in the viewpoint of air tightness of storage cavern.

Facilitated Transport of Oxygen in Copolymer Membranes of Styrene and 4-Vinylpyridine Containing Cobalt Schist Base Carrier : Effect of Membrane Thickness and Carrier Concentration

  • Hong, Jae-Min;Kang, Yong-Soo
    • Macromolecular Research
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    • v.8 no.1
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    • pp.1-5
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    • 2000
  • The valiclity of the simple mathematical model for facilitated transport in a solid state membrane developed previously has been examined againsts the carrier concentration and membrane thick-ness. Membranes are prepared with copolymer of styrene and 4-vinylpyridine as a matrix and Co(salen) as a carrier. 4-Vinylpyridine is incorporated to provide the coordination site for Co(salen) carrier. Oxygen permeability through the facilitated transport membrane is linearly increased with the square of its thick-ness, as predicted by the mathematical model. However, the oxygen permeability does not increase linearly with the carrier concentration. This seems to be due to the deactivation of the carrier by dimerization at high carrier concentrations as well as the reduced chain mobility by coordination of bulky Co(salen) carrier.

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Biobarrier를 이용한 유기오염물질의 생물학적분해모의를 위한 수치모델개발

  • 왕수균
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.04a
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    • pp.137-140
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    • 2003
  • This study presents a mathematical model for simulating the fate and transport of a reactive organic contaminant degraded through cometabolism in dual-porosity soils during the in situ bioaugmentations. To investigate the effect of dual-porosity on transport and biodegradation of organic hydrocarbons, a bimodal approach was incorporated into the model. Modified Monod kinetics and a microcolony concept [Molz et at., 1986〕 were employed to represent the effects of biodegrading microbes on the transport and biodegradation of an organic contaminant. The effect of permeability reduction due to biomass accumulation on the flow field were examined in the simulation of a hypothetical field-scale in situ bioaugmentation. Simulation results indicate that the presence of the immobile region can decrease the bioavailablity of biodegradable contaminants and that the placement of microbes and nutrients injection wells should be considered for an effective in situ bioaugmentation scheme.

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A Novel Design Approach Composed of Two Sequential Processes Using the Specific BE and Hybrid FE-BE Method (특수경계요소와 유한요소.경계요소병용법을 이용한 2단계 최적설계법)

  • Im, Jee-Won
    • Proceedings of the KIEE Conference
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    • 2001.07e
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    • pp.20-23
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    • 2001
  • This paper presents a novel design approach composed of two sequential processes for 3D magnetic shielding problems, which results in the global optimum solution in a shorter time. The feature of the proposed approach is the adoption of the specific boundary element with permeability of infinity. Assuming the permeability of infinity enables us to regard the thickness of ferromagnetic shields as infinitesimal, and thus to simplify the investigated model adequately in numerical analysis. This reduces the number of unknown variables and saves us a large amount of CPU-time for grasping the broad characteristics of the model. Some numerical results that demonstrate the validity of the proposed approach are also presented.

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Predictive Thermodynamic Model for Gas Permeability of Gas Separation Membrane (기체 분리막의 투과 특성 예측 모델식 개발)

  • Kim, Jong Hwan;Hong, Sung Kyu;Park, Sang Jin
    • Korean Chemical Engineering Research
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    • v.45 no.6
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    • pp.619-626
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    • 2007
  • It is of special interest in our membrane separation technology due to its low energy consumption and cost, relatively simple equipment, low investment and operation cost, et al. Full scale utilization of such processes can be widely utilized to the various fields. Using the difference of permeability of gas molecules between the filter layers, it is able to separate effectually pure gases from the mixed gases. In this paper, the membranes of PDMS, ${\gamma}-radiated$ PDMS, PTFE, PTFE-X are chosen to develop the predictive model for the separation of pure gases such as oxygen, nitrogen, hydrogen, and other gases from mixed gases. By utilizing the thermodynamic gas properties($\sigma$, $\varepsilon/k$) and experimental data of gas transport characteristics for different polymer membranes, it is able to develop the predictive model equation under the influence of temperature, pressure and polymer characteristics. Predictive model developed in this research showed good agreement with experimental data of gas permeability characteristics for develop four different polymer membranes. The proposed model can also be extended to the general equation for predicting the separation of gases based on the properties of polymeric membranes.

A Study of Dynamic Characteristic Analysis for Hysteresis Motor Using Permeability and Load Angle by Inverse Preisach Model (역 프라이자흐 모델에 의한 투자율과 부하각을 이용한 히스테리시스 전동기의 동적 특성 해석 연구)

  • Kim, Hyeong-Seop;Han, Ji-Hoon;Choi, Dong-Jin;Hong, Sun-Ki
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.68 no.2
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    • pp.262-268
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    • 2019
  • Previous dynamic models of hysteresis motor use an extended induction machine equivalent circuit or somewhat different equivalent circuit with conventional one, which makes unsatisfiable results. In this paper, the hysteresis dynamic characteristics of the motor rotor are analyzed using the inverse Preisach model and the hysteresis motor equivalent circuit considering eddy current effect. The hysteresis loop for the rotor ring is analyzed under full-load voltage source static state. The calculated hysteresis loop is then approximated to an ellipse for simplicity of dynamic computation. The permeability and delay angle of the elliptic loop apply to the dynamic analysis model. As a result, it is possible to dynamically analyze the hysteresis motor according to the applied voltage and the rotor material. With this method, the motor speed, generated torque, load angle, rotor current as well as synchronous entry time, hunting effect can be calculated.

A Modification of Water Table Fluctuation Model Considering Delayed Drainage Effect of Unsaturated Zone (비포화대 지연배수 효과를 고려한 지하수위 변동모델의 개선 및 적용)

  • Kim, Seong-Han;Park, Eun-Gyu;Kim, Yong-Sung;Kim, Nam-Jin
    • Journal of Soil and Groundwater Environment
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    • v.16 no.3
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    • pp.17-27
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    • 2011
  • Recently, a physically based model of water-table fluctuation due to precipitation is developed based on aquifer water balance model. In the model, it was assumed that the water infiltration into ground surface is advection dominant and immediately reaches to water-table. The assumption may be suited for the sites where the water-table is shallow and/or the permeability of the unsaturated zone is high. However, there are more cases where the model is not directly applicable due to thick and low permeable unsaturated zone. For the low permeability unsaturated zone, the pattern of water flux passing through unsaturated zone is diffusive as well as advective. In this study, to improve the previously developed water-table fluctuation model, we combined the delayed drainage model, which has long been used in well hydraulics, to the water-table fluctuation model. To test the validity of the development, we apply the developed model to 5 different domestic sites. The model parameters are calibrated based on the groundwater hydrograph and the precipitation time series, and the correlation analyses among the parameters are pursued. The overall analyses on the delineated model parameters indicate that the delayed drainage parameters or delay index used in the developed model are able to reveal drainage information in the unsaturated zones.

A numerical investigation on nonlinear behavior of fluid flow with variation of physical properties of a porous medium (다공성 매질의 물리적 특성 변화에 따른 유체흐름의 비선형 거동에 대한 수치적 분석)

  • Jeong, Woochang
    • Journal of Korea Water Resources Association
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    • v.50 no.5
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    • pp.325-334
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    • 2017
  • In this study, the numerical investigation of the non-linear behavior of the fluid flow with physical properties, such as porosity and intrinsic permeability of a porous medium, and kinematic viscosity of a fluid, are carried out. The applied numerical model is ANSYS CFX which is the three-dimensional fluid dynamics model and this model is verified through the application of existing physical and numerical results. As a result of the verification, the results of the pressure gradient-velocity relationship and the friction coefficient-Reynolds number relationship produced from this study show relatively good agreement with those from existing physical and numerical experiments. As a result of the simulation by changing the porosity and intrinsic permeability of a porous medium and the kinematic viscosity of a fluid, the kinematic viscosity has the biggest effect on the non-linear behavior of the fluid flow in the porous medium.