• 제목/요약/키워드: permeability barrier

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고차단성 자동차 부품용 고무소재 (Elastomeric High Barrier Materials for Vehicle)

  • 김진국
    • Elastomers and Composites
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    • 제46권1호
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    • pp.2-9
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    • 2011
  • 가스와 증기에 대한 투과성(Permeability to gases and Vapors)은 고무 제품을 타이어 튜브나 다이아후램(diaphragm)과 같은 제품으로 사용하고자 할 때 아주 중요한 특성이다. 모든 고무는 가스와 증기에 대하여 투과성이 있다. 그러나 그 투과 속도는 고무 재질에 따라 아주 다르다. 일반적으로 실리콘 고무의 투과성이 제일 크고, 그 다음으로 NR, EPDM, SBR, CR, NBR, FPM, ECO, IIR 순이다. 이러한 투과성은 같은 원료고무를 사용해도 사용 배합약품의 종류에 따라 크게 다를 수도 있다. 고무와 기체와의 메커니즘은 발포고무에 매우 중요하게 되어 이에 대한 연구$^{1-7}$는 많이 이루어졌으나 고무의 차단성에 대한 연구는 그리 많지 않다. 고무소재의 투과성 또는 차단성 기능을 주기위하여 나노복합탄성체$^8$의 기술 동향 및 코팅에 의한 기능성 향상$^{9-13}$을 하거나 열가소성탄성체 본문에서 적용하는 기술이 있는데 자동차에 사용되는 액체 및 기체 차단용 고무부품에 대하여 몇가지 소개하여 본다.

한국 소방대원 방수피복의 소재특성에 관한 비교 연구 (A Study on the Textile for Protective Clothing of Fire Fighters)

  • 정정숙;이연순
    • 대한가정학회지
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    • 제40권5호
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    • pp.15-24
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    • 2002
  • The following research conclusions were made, relative to the experiments of the textiles of fire fighters Protective Clothing. 1. When the body protection efficiency such as the thickness, the strength and heat resistance are considered, Nomex(N) is tuned out the best outer shelf, Gore-tex(KG) the best moisture barrier, and Wool-felt(WC) the best thermal barrier. 2. In the hygienic and sanitary efficiency also, N is turned out the best outer shelf, KG the best moisture barrier, and WC the best thermal barrier in its degree of water resistance, water vapour permeability, and air permeability. 3. In the washing and maintenance efficiency, too. N is turned out the best outer shell, KG the best moisture barrier, and WC the best thermal barrier, being considered the material's rate of contraction, the changing rate of frame resistance, water resistance, and water vapour permeability. 4. When considered the frame resistance against the reflection tape and reflection efficiency, O is the best material for it marks the highest score in the frame resistance and reflective effect.

알츠하이머 치매와 미세뇌혈관병리: 혈액뇌장벽 투과도 영상 (Alzheimer Dementia and Microvascular Pathology: Blood-Brain Barrier Permeability Imaging)

  • 문원진
    • 대한영상의학회지
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    • 제81권3호
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    • pp.488-500
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    • 2020
  • 최근의 연구들은 알츠하이머병의 병리가 단순히 아밀로이드와 타우단백질의 축적만이 아닌, 혈액뇌장벽(blood brain barrier; 이하 BBB) 이상과 같은 미세혈관병리와 밀접한 관련이 있음을 밝히고 있다. BBB 투과도 변화는 아밀로이드 및 타우 단백질 축적뿐 아니라 신경염증과 신경 퇴행성변화를 일으킴으로써 결국 임상 치매를 야기한다. 최근에는 알츠하이머 및 관련 질환의 BBB 이상을 보기 위한 MR 영상의 이용이 증가하고 있다. 이 종설에서는 알츠하이머병에서 BBB와 관련된 병리를 소개하고, BBB 투과도 변화에 대한 MR 영상 연구들을 소개할 것이다. 또한 BBB 투과도 측정을 위한 MR 방법론 개요와 문제점들을 제시할 것이다.

산 이동에 따른 심층혼합기둥체 차수벽의 성능변화 (Changes of Performance of Soil-Cement Barrier due to Migration of Acids)

  • 정문경;천찬란;이주형;김강석
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2003년도 봄 학술발표회 논문집
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    • pp.189-196
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    • 2003
  • Soil-cement column is often used as a contaminant barrier. This study presents the results of experimental study performed to investigate the changes of properties of soil-cement column under the attack of acids. Sulfuric nitric, and ascetic acid were used as contaminants. Specimen were made of clayey and sandy soils with addition of cement and water Permeability of soil-cement decreased with time during permeability test. When significant amount of acid percolated the specimen, permeability increased and compressive strength decreased due to the dissolution and leaching of cement and its chemical reaction compounds. Sulfuric and nitric acid were more effective than ascetic acid in deteriorating soil-cement column. Amount of acid required to lower the pH of soil cement below 12 was calculated from the results of permeability tests. This leads to a conclusion that, under the conditions employed in this study, the chemical stability of soil-cement column could be maintained against acid attack for longer than generally accepted lifetime of contaminant barriers.

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솔-젤법을 이용한 aminoalkoxysilane 산소차단필름의 제조 (The Preparation of Sol-Gel Derived Aminoalkoxysilane Films and its Application for Oxygen Barrier)

  • 김현준
    • 반도체디스플레이기술학회지
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    • 제5권3호
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    • pp.17-21
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    • 2006
  • The oxygen barrier films were formed on poly(ethylene terephthalate) (PET) substrate by a sol-gel process using aminoalkoxysilanes. The coating layers were characterized by FT-IR and SEM. The oxygen permeability coefficients of coating films were measured by variable volume method, and then the influences of solvent ratio in sol and film drying temperature on the oxygen barrier properties were investigated. The aminoalkoxysilane coating films exhibited much higher oxygen barrier properties than PET film. The oxygen permeability coefficient of the film coated with each of APTEOS and APTMOS was measured to be $2.96{\times}10^{-6}$ and $3.05{\times}10^{-5}\;GPU$, respectively, while that of PET film was $1.16{\times}10^{-4}\;GPU$.

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The Effect of Multi-lamellar Emulsion (MLE) on Skin Barrier Function: Can an Improve Permeability Barrier Provide a Solution for Itching due to Skin Barrier Malfunction\ulcorner

  • Youm, Jong-kyung;Kim, Yang-hee;Park, Byeong-deog;Jeong, Se-kyoo;Park, Eung-ho;Ahn, Sung-ku;Lee, Seung-hun
    • 대한화장품학회:학술대회논문집
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    • 대한화장품학회 2003년도 IFSCC Conference Proceeding Book I
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    • pp.765-779
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    • 2003
  • Physiological lipid mixtures comprised of cholesterol, ceramide and free fatty acid better maintain epidermal homeostasis and have been recently used for dermatoses induced by skin barrier damage, for example for atopic dermatitis and xerotic skin. Itching and dry atopic dermatitis of the skin may be related to altered skin barrier function. In a previous study, the use of multi-lamellar emulsion (MLE), which is a lipid mixtures containing cholesterol, pseudoceramide and free fatty acid, has been shown to accelerate the recovery of the epidermal permeability barrier. In this study, we assessed the efficacy of MLE compared with a currently used anti-itch moisturizer (AIM), the active ingredients of which are menthol and camphor, on barrier recovery after barrier disruption. To clarify the effect of MLE and AIM after acute barrier perturbation, we measured the relation between transepidermal water loss (TEWL) and the barrier recovery rate at 3, 6, 24, and 48 hours after tape stripping hairless mice and then observed changes in the stratum corneum (SC), including the intercellular lipid structure and secretion of lamellar bodies, by electron microscopy. MLE treated skin recover skin barrier function more rapidly, and AIM treated skin delayed barrier repair. Morphological changes in the epidermis, of MLE treated skin revealed well-conserved lipid multi-lamellar structures at 24 h after tape stripping, whereas AIM treated skin showed altered lamellar bilayers within the SC interstices at 48 h. In addition, MLE treated skin showed an increase in the number of LBs and in their secretions and a decrease in the number of SC layers versus AIM treated skin. These results suggest that MLE may accelerate the production of an epidermal permeability barrier in hairless mice by increasing the number and secretion of LB and improve the dryness and itch associated with an altered epidermal permeability barrier.

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표피항상성과 건조피부의 관리 (Epidermal Homeostasis and Dry Skin Management)

  • 박장서
    • 대한화장품학회지
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    • 제34권1호
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    • pp.1-8
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    • 2008
  • 피부장벽을 포함한 표피층은 인체의 조직 가운데에서도 가장 역동적인 기관이다. 다시 말해서 끊임없이 새로운 표피세포의 형성, 분화 및 탈각과정이 반복되면서 표피항상성(epidermal homeostasis)을 유지한다. 표피항상성은 피부기능 가운데 가장 주요한 기능인 permeability barrier homeostasis의 확립으로 연결된다. Permeability barrier homeostasis는 각질층에서 이루어지며 이를 형성하고 유지하기 위해 매우 정교하게 조절되어야 한다. 표피항상성을 조절하는 핵심 조절인자로서 nuclear hormone receptor(NHR)가 중심에 있음이 최근 다양한 연구를 통해 입증되었다. 이들은 각질세포 특이적인 단백질, 즉, involucrin, loricrin 및 trans-glutaminase 1(TG 1) 등의 발현을 유전자 수준에서 조절할 뿐 아니라 표피 지질성분의 생합성을 증가시키는 등 피부장벽을 구성하는 brick 및 mortar의 생성과 유지에 핵심적 역할을 하는 것으로 알려졌다. NHR 가운데 peroxisome proliferator activator receptor(PPAR)와 liver X receptor(LXR)의 activator/ligands가 리놀레인산 등 지방산, leukotriene, prostanoid 및 oxygenated sterol 등이 지질대사과정에서 형성된 지질 종류인 까닭에 liposensor로도 알려지고 있다. 따라서 liposensor들을 비롯한 PPAR과 LXR activator/ligands들은 피부장벽기능이 저해된 아토피성 피부를 포함하여 건조피부를 관리하는 epidermotherapy의 수단으로서 잠재적 가능성이 있다고 생각된다.

Prediction of Gas Permeability by Molecular Simulation

  • Yoo, Jae ik;Jiang, Yufei;Kim, Jin Kuk
    • Elastomers and Composites
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    • 제54권3호
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    • pp.175-181
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    • 2019
  • The research and development of high-performance polymer materials with excellent gas barrier properties has gained considerable attention from the viewpoint of expanding their applications in various fields, including tire automobile parts and the polymer film industry. Natural rubber (NR) has been widely used as a rubber material in real-life, but its application is limited owing to its poor gas barrier properties. In this paper, we study the gas barrier properties of NR, epoxidized natural rubber (ENR), and their blend compositions by using molecular simulation. The results show that ENR-50 has superior oxygen barrier properties than those of NR. Moreover, the oxygen barrier properties of a blend of NR/ENR-50 improve with increasing volume fraction of ENR-50. The trend of improved oxygen barrier properties of NR, ENR-50, and their blend is in good agreement with experimental observations.

Z형 강널말뚝의 오염물질 차단효과 (The permeability charateristic of Z-type sheet pile joints under water sealing conditions)

  • 홍승서;이용수;정하익
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2009년도 세계 도시지반공학 심포지엄
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    • pp.1283-1288
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    • 2009
  • In general steel sheet piles are used in the containment system, which are vertical barrier systems for waste disposal and landfill purposes, and roads in excavation for temporary structure. This paper presents case study of the use of an interlocking sheet pile for water and containment. Cut-off Z-type sheet pile joints are investigated to determine their permeability from the field test. Four different joint sealing materials are used in field test. The results showed joint permeability is significant time-dependent and joint-dependent. These are explored and conclusions on permeability characteristics of different sealants are noted. A case study gives a design example as well as suggestion on permeability and water tightness can be implemented in using the sheet pile barrier in civil and environment works. From the test results, the effective sealing programs of sheet pile interlocks are suggested.

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An assessment of the mechanical behavior of zeolite tuff used in permeable reactive barriers

  • Cevikbilen, Gokhan
    • Geomechanics and Engineering
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    • 제31권3호
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    • pp.305-318
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    • 2022
  • Permeable reactive barriers used for groundwater treatment require proper estimation of the reactive material behavior regarding the emplacement method. This study evaluates the dry emplacement of zeolite (clinoptilolite) to be used as a reactive material in the barrier by carrying out several geotechnical laboratory tests. Dry zeolite samples, exhibited higher wetting-induced compression strains at the higher vertical stresses, up to 12% at 400 kN/m2. The swelling potential was observed to be limited with a 3.5 swell index and less than 1% free swelling strain. Direct shear tests revealed that inundation reduces the shear strength of a dry zeolite column by a maximum of 10%. Falling head permeability tests indicate decreasing permeability values with increasing the vertical effective stress. Regarding self-loading and inundation, the porosity along the zeolite column was calculated using a proposed 1D numerical model to predict the permeability with depth considering the laboratory tests. The calculated discharge efficiency was significantly decreased with depth and less than 2% relative to the top for barrier depths deeper than 20 m. Finally, the importance of directional dependence in the permeability of the zeolite medium for calibrating 2D finite element flow analysis was highlighted by bench-scale tests performed under 2D flow conditions.