• Title/Summary/Keyword: parameter characterization

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Electrochemical treatment of cefalexin with Sb-doped SnO2 anode: Anode characterization and parameter effects

  • Ayse, Kurt;Hande, Helvacıoglu;Taner, Yonar
    • Advances in nano research
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    • v.13 no.6
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    • pp.513-525
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    • 2022
  • In this study, it was aimed to evaluate direct oxidation of aqueous solution containing cefalexin antibiotic with new generation Sn/Sb/Ni: 500/8/1 anode. The fact that there is no such a study on treatment of cefalexin with these new anode made this study unique. According to the operating parameters evaluation COD graphs showed clearer results compared to TOC and CLX and thus, it was it was chosen as major parameter. Furthermore, pseudo-first degree kd values were calculated from CLX results to show more accurate and specific results. Experimental results showed that after 60 min of electrochemical oxidation, complete removal of COD and TOC was accomplished with 750 mg L-1 KCl, at pH 7, 50 mA cm-2 current density and 1 cm anode-cathode distance. Also, the stability of the Sn/Sb/Ni anode was evaluated by taking SEM and AFM images and XRD analysis before and after of electrochemical oxidation processes. According to the results, it was not occurred too much change on the anode surface even after 300 h of electrolysis. Thus, it was thought that the anode material was not corroded to a large extent. Furthermore, the removal efficiencies were very high for almost all the time and conditions. According to the results of the study, electrochemical oxidation with new generation Sn/Sb/Ni anodes for the removal of cefalexin antibiotic was found very successful and applicable due to require less reaction time complete mineralization and doesn't require pH adjustment step compared to other studies in literature. In future studies, different antibiotic types should be studied with this anode and maybe with real wastewaters to test applicability of the process in treatment of pharmaceutical wastewaters containing antibiotics, in a better way.

Characterization Of Rainrate Fields Using A Multi-Dimensional Precipitation Model

  • Yoo, Chul-sang;Kwon, Snag-woo
    • Water Engineering Research
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    • v.1 no.2
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    • pp.147-158
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    • 2000
  • In this study, we characterized the seasonal variation of rainrate fields in the Han river basin using the WGR multi-dimensional precipitation model (Waymire, Gupta, and Rodriguez-Iturbe, 1984) by estimating and comparing the parameters derived for each month and for the plain area, the mountain area and overall basin, respectively. The first-and second-order statistics derived from observed point gauge data were used to estimate the model parameters based on the Davidon-Fletcher-Powell algorithm of optimization. As a result of the study, we can find that the higher rainfall amount during summer is mainly due to the arrival rate of rain bands, mean number of cells per cluster potential center, and raincell intensity. However, other parameters controlling the mean number of rain cells per cluster, the cellular birth rate, and the mean cell age are found invariant to the rainfall amounts. In the application to the downstream plain area and upstream mountain area of the Han river basin, we found that the number of storms in the mountain area was estimated a little higher than that in the plain area, but the cell intensity in the mountain area a little lower than that in the plain area. Thus, in the mountain area more frequent but less intense storms can be expected due to the orographic effect, but the total amount of rainfall in a given period seems to remain the same.

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Characterization of Microstructures of Variously Heat Treated Hypoeutectoid and Eutectoid Steel by Magnetic Coercivity Measurement (보자력 측정에 의한 아공석강 및 공석강의 열처리에 따른 미세조직 평가)

  • Byeon Jai Won;Kim C. S.;Kwun S. I.
    • Korean Journal of Materials Research
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    • v.14 no.8
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    • pp.565-572
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    • 2004
  • The microstructures of variously heat treated hypoeutectoid($0.45\%$ carbon) and eutectoid($0.85\%$ carbon) steel were characterized by magnetic coercivity measurement. The effect of spheroidization of cementites on the coercivity was investigated for $0.45\%$ carbon steel. In case of $0.85\%$ carbon steel, microstructural parameters such as prior austenite grain size, phase and pearlite interlamellar spacing were measured along with coercivity to investigate the relationships between them. Prior austenite grain size had little effect on the measured coercivity. Coercivity was observed to be high in order of martensite, pearlite and ferrite phases. The linear decrease of coercivity with increasing pearlite interlamellar spacing was found. The effect of each microstructural factor on the coercivity and the potential of coercivity as a nondestructive evaluation parameter for assessing microstructures of steel products are discussed.

Electrical Characterization of BGA interconnection for RF packaging (Radio Frequency 회로 모듈 BGA 패키지)

  • Kim, Dong-Young;Woo, Sang-Hyun;Choi, Soon-Shin;Jee, Yong
    • Proceedings of the IEEK Conference
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    • 2000.06b
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    • pp.96-99
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    • 2000
  • We presents a BGA(Ball Grid Array) package for RF circuit modules and extracted its electrical parameters. We constructed a BGA package of ITS(Intelligent Transportation System) RF module and examined electrical parameters with a HP5475A TDR(Time Domain Reflectometry) equipment and compared its electrical parasitic parameters with PCB RF circuits. With a BGA substrate of 3 $\times$ 3 input and output terminals, we have found that self capacitance of BGA solder ball is 68.6fF, self inductance 146pH, mutual capacitance 10.9fF and mutual inductance 16.9pH. S parameter measurement with a HP4396B Network Analyzer showed the resonance frequency of 1.55㎓ and the loss of 0.26dB. Thus, we may improve electrical performance when we use BGA package structures in the design of RF circuit modules.

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Microstructure and Characterization Depending on Process Parameter of SnO2 Thin Films Fabricated by PECVD Method (PECVD법에 의해 제조된 SnO2 박막의 공정변수에 따른 미세구조 및 특성)

  • Lee, Jeong-Hoon;Jang, Gun-Eik;Son, Sang-Hee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.7
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    • pp.680-686
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    • 2006
  • Tin oxide$(SnO_2)$ thin films were prepared on glass substrate by Plasma Enhanced Chemical Vapor Deposition (PECVD) method. $SnO_2$ thin films were prepared using gas mixture of dibutyltin diacetate as a precursor and oxygen as an oxidant at 275, 325, 375, $425^{\circ}C$, respectively as a function of deposition temperature. The XRD peaks corresponded to those of polycrystalline $SnO_2$, which is in the tetragonal system with a rutil-type structure. As the deposition temperature increased, the texture plane of $SnO_2$ changed from (200) plane to denser (211) and (110) planes. Lower deposition temperature and shorter deposition time led to decreasing surface roughness and electrical resistivity of the formed thin films at $325\sim425^{\circ}C$. The properties of $SnO_2$ films were critically affected by deposition temperature and time.

Characterization of Direct Laser Melting Technology for the Fabrication of Fuel Cell Bipolar Plate (연료전지용 금속 분리판 제작을 위한 DLM공정 특성 연구)

  • Mun, S.M.;Jang, J.H.;Kim, T.H.;Lee, H.J.;Moon, Y.H.
    • Transactions of Materials Processing
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    • v.20 no.2
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    • pp.118-123
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    • 2011
  • Manufacturing of the bipolar plate of a direct methanol fuel cell (DMFC) by direct laser melting technology (DLM) was attempted. The DLM technology is highly influenced by process parameters such as laser power, scan rate and layering height. Therefore, an analysis of the DLM technology was performed under various conditions. The bipolar plates were fabricated using the DLM process with 316L stainless steel (STS 316L) plates and powder. Powder melting trials at various energy density were performed in order to select a feasible melting range for a given laser power. The melting line height increases and eventually saturates when the energy density increases, but decreases when the laser power increases at a given energy density. For the estimation of the potential performance of the bipolar plate, the surface roughness and contact resistance of the DLM layer were also analyzed. The changes of line height and thickness are useful information to report when manufacturing bipolar plate of fuel cell through the DLM process.

Friction Welding Process Analysis of Piston Rod in Marine Diesel Engine and Mechanical Properties of Welded Joint (선박 디젤 엔진용 피스톤 로드의 마찰용접 공정해석 용접부 기계적 특성)

  • Jeong, H.S.;Son, C.W.;Oh, J.S.;Choi, S.K.;Cho, J.R.
    • Transactions of Materials Processing
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    • v.20 no.3
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    • pp.236-242
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    • 2011
  • The two objectives of this study were, first, to determine the optimal friction welding process parameters using finite element simulations and, second, to evaluate the mechanical properties of the friction welded zone for large piston rods in marine diesel engines. Since the diameters of the rod and its connecting part are very different, the manufacturing costs using friction welding are reduced compared to those using the forging process of a single piece. Modeling is a generally accepted method to significantly reduce the number of experimental trials needed when determining the optimal parameters. Therefore, because friction welding depends on many process parameters such as axial force, initial rotational speed and energy, amount of upset and working time, finite element simulations were performed. Then, friction welding experiments were carried out with the optimal process parameter conditions resulting from the simulations. The base material used in this investigation was AISI 4140 with a rod outer diameter of 280 mm and an inner diameter of 160 mm. In this study, various investigation methods, including microstructure characterization, hardness measurements and tensile and fatigue testing, were conducted in order to evaluate the mechanical properties of the friction welded zone.

Analysis of Domestic Water Consumption Characteristics for Water Usage Purpose (가정용수의 사용 목적별 소비경향 특성분석)

  • Choi, Sun-hee;Son, Mi-na;Kim, Sang-hyun
    • Journal of Korean Society of Water and Wastewater
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    • v.22 no.1
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    • pp.23-29
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    • 2008
  • Throughout the analysis of field data from water distribution system, valid parameters were determined that can be included in the water service and design plan. This study investigates water consumption patterns to understand the variation of water-demand structures utilizing the pattern analysis of domestic purpose water. Water use data were collected by a public water resources management firm in Korea, Kwater, for 140 houses monitored during three years. Flow meters were installed at the faucet for drinking water, the shower booth, the laundry machine, bathroom sink, toilet, and garden faucet. Data was filtered using multiple physically meaningful criteria to improve analysis credibility. Mann Kendall and Spearman's Rho tests were used to carry out the analysis. Distinct factors of water consumption patterns can be determined for both increasing and decreasing trends of water use. Throughout the data analysis, the characterization of terms was classified and analyzed by the condition of the location of water-demand. Analysis of this data provide a physical basis for the parameter configuration of a reasonable design for a domestic water demand prediction model.

Data Mining Approach for Diagnosing Heart Disease (심장 질환 진단을 위한 데이터 마이닝 기법)

  • Noh, Ki-Yong;Ryu, Keun-Ho;Lee, Heon-Gyu
    • Science of Emotion and Sensibility
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    • v.10 no.2
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    • pp.147-154
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    • 2007
  • Electrocardiogram(ECG) being the recording of the heart's electrical activity provides valuable clinical information about heart's status. Many researches have been pursued for heart disease diagnosis using ECG so far. However, electrocardio-graph uses foreign diagnosis algorithm in the con due to inaccuracy of domestic diagnosis results for a heart disease. This paper proposes ST-segment extraction technique diagnosing heart disease parameter from raw ECG data. As the ST-segment is used for prediction of Coronary Artery Disease, we can predict heart disease using classification approach in data mining technique. We can also predict patient's clinical characterization from patient clinical data.

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A study on the design of an Inverted-F Internal Antenna for the 2.4GHz local wireless communication system (2.4GHz 근거리 무선 통신용 역-F형 내부 안테나 설계에 관한 연구)

  • 주성남;박청룡;손달윤;김장식;김영남;김갑기
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2003.05a
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    • pp.100-103
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    • 2003
  • In this paper, the characteristics of an inverted-F antenna for the 2.4GHz local wireless communication system have been analysed in terms of the variation of design parameters. The antenna can be integrated on printed circuit board, and the characteristics in terms of the variation of the gap between feed line and shorting stub, gap between antenna's leg and ground plane, antenna leg's width, substrate's height and dielectric constant are analysed. By using these characterization plot of design parameter, the tuning techniques are proposed to design optimum antenna. The designed antenna has 6.4% frequency bandwidth for VSWR under 1.5 and 3dB gain.

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