• Membrane and Water Treatment
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• v.12 no.2
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• pp.59-64
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• 2021

The rejection of sodium chloride (NaCl) and calcium chloride (CaCl2) single salt solutions were carried out for commercial nanofiltration NFDK membrane. Results showed that the NFDK membrane had a negative surface charge and had a higher observed rejection of 93.65% for calcium (Ca2+) ion and 78.27% for sodium (Na+) ions. Prediction of rejection for aqueous solutions of both salts was made using Donnan Steric Pore Model based on Extended Nernst-Planck Equation in addition to concentration polarization film theory. A MATLAB program was developed to execute the model calculations. Absolute Average Relative Error (% AARE) was found below 5% for real rejection of the NFDK membrane. This research could be used successfully to assess the membrane characterization parameter using a proposed procedure which can reduce the number of experiments.

• Bulletin of the Korean Mathematical Society
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• v.56 no.5
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• pp.1219-1233
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• 2019

Let $E{\rightarrow}M$ be an arbitrary vector bundle of rank k over a Riemannian manifold M equipped with a fiber metric and a compatible connection $D^E$. R. Albuquerque constructed a general class of (two-weights) spherically symmetric metrics on E. In this paper, we give a characterization of locally symmetric spherically symmetric metrics on E in the case when $D^E$ is flat. We study also the Einstein property on E proving, among other results, that if $k{\geq}2$ and the base manifold is Einstein with positive constant scalar curvature, then there is a 1-parameter family of Einstein spherically symmetric metrics on E, which are not Ricci-flat.

• Bulletin of the Korean Chemical Society
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• v.14 no.2
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• pp.215-220
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• 1993

Experiment on isomorphous substitution of Al by Fe in sodalite framework was carried out using dry way method at 800-900$^{\circ}$C in nitrogen atmosphere. The substitution of Fe was possible up to 25 mole% with some deviation of symmetry in sodalite cage. The cubic unit cell parameter increased with increasing Fe content. It showed ionic semiconducting property, especially the highest conductivity and the lowest activation energy in 10 mole% Fe-substituted sodalite which could behave as a superionic conductor at above 400$^{\circ}$C. When more Fe was introduced into sodalite the electronic conductivity was improved at high temperature. But the relative electronic contribution was found to be lower compared with ionic contribution at high temperature. In infrared spectra some major absorption bands of sodalite shifted to lower wave numbers due to heavier Fe atoms substitution in Al lattice sites.

• Journal of the Semiconductor & Display Technology
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• v.21 no.2
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• pp.45-50
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• 2022

The etching with high selectivity of silicon dioxide over silicon nitride is essential in semiconductor fabrication, and gas phase etch (GPE) can increase the competitiveness of the selective dielectric etch. In this work, GPE of plasma enhanced chemical vapor deposited SiO₂ was performed, and the effects of process parameters, such as temperature, partial pressure ratio, and gas supply cycle, are investigated in terms of etch rate and within wafer uniformity. Employing multiple regression analysis, the importance of each parameter elements is analyzed.

• Journal of the Korean Society for Heat Treatment
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• v.35 no.5
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• pp.239-245
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• 2022

The purpose of this study is to evaluate the degree of microstructural change of materials using ultrasonic nonlinear parameters. For microstructure change, isothermal heat-treated ferritic 2.25Cr steel and low-cycle fatigue-damage copper alloy were prepared. The variation in ultrasonic nonlinearity was analyzed and evaluated through changes in hardness, ductile-brittle transition temperature, electron microscopy, and X-ray diffraction tests. Ultrasonic nonlinearity of 2.25Cr steel increased rapidly during the first 1,000 hours of deterioration and then gradually increased thereafter. The variation in non-linear parameters was shown to be coarsening of carbides and an increase in the volume fraction of stable M6C carbides during heat treatment. Due to the low-cycle fatigue deformation of oxygen-free copper, the dislocation that causes lattice deformation developed in the material, distorting the propagating ultrasonic waves, and causing an increase in the ultrasonic nonlinear parameters.

• Steel and Composite Structures
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• v.53 no.1
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• pp.91-101
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• 2024

A cost-effective fabrication method suitable for research purposes is proposed in this study. The elastic modulus of the fabricated functionally graded materials is evaluated and compared using two experimental methods: the three-point bending test and the tensile test, with a focus on the fiber volume fraction of the FGM layers. New methods for computing the elastic modulus are introduced, which are based on Castigliano's theorem and the secant modulus concept, incorporating the non-linear behavior of the material. Additionally, the mode I fracture toughness of the FGM layers is measured accurately using the three-point bending test and finite element analysis, and the influence of varying fiber volume fractions on this parameter is investigated through statistical analysis. Results indicate that while an increase in fiber volume fraction correlates with a rise in elastic modulus, it does not necessarily lead to an enhancement in mode I fracture toughness, highlighting the complex interactions between material composition and mechanical properties.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.6 no.4
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• pp.245-255
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• 2008

Korea Hydro and Nuclear Power Company(KHNP) conducted site investigations for a low and intermediate-level nuclear waste repository in the Gyeong Ju site. The site characterization work constitutes a description of the site, its regional setting and the current state of the geosphere and biosphere. The main objectives of hydogeological investigation aimed to understand the hydrogeological setting and conditions of the site, and to provide the input parameters for safety evaluation. The hydogeological characterization of the site was performed from the results of surface based investigations, i.e geological mapping and analysis, drilling works and hydraulic testing, and geophysical survey and interpretation. The hydro-structural model based on the hydrogeological characterization consists of one-Hydraulic Soil Domain, three-Hydraulic Rock Domains and five-Hydraulic Conductor Domains. The hydrogeological framework and the hydraulic values provided for each hydraulic unit over a relevant scale were used as the baseline for the conceptualization and interpretation of flow modeling. The current hydrogeological characteristics based on the surface based investigation include some uncertainties resulted from the basic assumption of investigation methods and field data. Therefore, the reassessment of hydrostructure model and hydraulic properties based on the field data obtained during the construction is necessitated for a final hydrogeological characterization.

• Tunnel and Underground Space
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• v.34 no.5
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• pp.477-502
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• 2024

To effectively dispose of high-level radioactive waste, it is crucial to understand the geological characteristics of the deep rock at the disposal site where the disposal facility will be located. Deep drilling is essential in this process and can obtain multidisciplinary deep rock characteristics by conducting tests using recovered cores and various tests using boreholes. However, in Korea, there are currently no established guidelines or procedures for deep drilling aimed at sit investigation and characterization for high-level radioactive waste disposal. This report proposes a deep drilling procedure based on five years from 2020 of multipurpose deep drilling experience conducted for various rock types by the Korea Institute of Geoscience and Mineral Resources. The proposed procedure includes various processes such as health, safety, and environments, pre-drilling work, drilling work, circulating drilling water management, site characterization evaluation parameter acquisition tests and measurements, and sampling. These procedures will need to be continuously revised and amended in the future to meet the needs of drilling and HLW disposal industries and related fields, as well as to strengthen quality assurance under the Nuclear Safety Act.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.23 no.1
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• pp.31-36
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• 2013

Acetylated Cellulose Ether (ACE), cellulose-based amphiphilic polymer with hydrophilic and hydrophobic, was synthesized and investigated in terms of its solubility and wettability for organic solvents and water. Acetyl group was substituted to the cellulose ether in a hydrophilic polymer by esterification. As a result of FT-IR, the peak corresponding to the hydroxyl group decreased and carboxyl acid peak increased with increasing reaction time and temperature, which signified the increase in the degree of acetylation of the ACE. There were similar thermal decomposition behaviors before and after esterification reaction until $800^{\circ}C$ so that the reaction occurred without significant structural changes of cellulose backbones. The solubility parameter of the ACE had a range of 18.5~26.4, and its viscosity and turbidity were controlled according to the solubility parameter of organic solvents. The ACE showed the hydrophilicity because the contact angle of the ACE was higher than the cellulose ether. These results confirmed that the ACE had the hydrophobicity and hydrophilicity due to the ether which was glucosidic bonding between the glucose units and un-reacted hydroxyl functional groups in the ACE.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.31 no.10
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• pp.986-992
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• 2007

This paper presents the fabrication and characterization of carbon films pyrolyzed with various photoresists for bioMEMS applications. To verify the usefulness of pyrolyzed carbon films as an electrode material in an electrochemical biosensor developed by the authors, interactions between avidin and biotin on the pyrolyzed carbon film were studied via electrochemical impedance spectroscopy based on electrostatic interactions between avidin and negatively-charged ferricyanide. The pyrolyzed carbon films were characterized using a surface profiler, a precision semiconductor parameter analyzer, a nanoindentor, scanning electron microscopy, and atomic force microscopy. Amine conjugated biotin was immobilized on the electrode using EDC/NHS as crosslinkers after $O_2$ plasma treatment to enhance functional groups on the carbon electrode pyrolyzed at $1000^{\circ}C$ with AZ9260. The detection of avidin binding with different concentrations in a range of 0.75 nM to $7.5\;{\mu}M$ to the pyrolyzed carbon electrode modified with biotin was carried out by measuring the electrochemical impedance change. The results show that avidin binds to the biotin on the electrode not by non-specific interaction but by specific interaction, and that EIS successfully detects this binding event. Pyrolyzed carbon films are a promising material for miniaturization, integration, and low-cost fabrication in electrochemical biosensors.