• Title/Summary/Keyword: pH10

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The Effect of Temperature and pH on Bromate Formation by Ozonation (오존처리시 Bromate생성에 미치는 온도 및 pH의 영향)

  • Lee, Mu Gang;Kim, Yeong Cheol;Choe, Jong Won
    • Journal of Environmental Science International
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    • v.13 no.7
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    • pp.667-674
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    • 2004
  • The objective of this study was to investigate the effects of pH and temperature on the formation of bromate, which is ozonation by-products, during ozonation. In this experiment, the operating parameters including pH 3 ~ 10 and temperature 15 ~ $30^{\circ}C$ were studied. Through the study for the bromate formation, reaction rate constant, and ozonation effect index on pH and temperature, the results obtained are as follows. At the same initial pH condition, the increase of pH shown similar trends even if the reaction variables such as temperature and reaction time of ozonation were exchanged. As pH and temperature were increasing, the bromate concentration was increased but bromine(HOBr+OBr) was decreased with increasing pH from 3 to 10. The activation energy(J/mol) for bromate formation decreased with increasing pH. The rate constants of bromate formation for the reaction of ozone and bromide, and ozone dosage coefficient$(K_{0})$ increased with temperature and pH. Ozonation effect index(OI) decreased with increasing temperature and pH.

Effect of pH Variation on the Properties of the Hydroxyapatite Precipitates and Powder Prepared by the Wet Method (습식법으로 제조한 수산화아파타이트 침전입자와 분말의 특성에 미치는 pH변화의 영향)

  • 신용규;정형진;김병호
    • Journal of the Korean Ceramic Society
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    • v.26 no.2
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    • pp.157-166
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    • 1989
  • The effect of pH variation in starting solution on the characteristics of hydroxyapatite precipitates and powder prepared by the wet method was investigated. Hydroxyapatite precipitates was agglomerated, the average agglomerated particle size was decreased in the range from 2 to 6${\mu}{\textrm}{m}$ with increasing pH values in starting solution. The aspect ratio of rod-shaped hydroxyapatite particle was rapidly increased at pH 11 and 11.5. The maximum specific surface area, 91.1$m^2$/g, was at pH 10.5. Dried powder prepared at high pH values contained more minutes CO2 than that prepared at low pH values. The poor crystallinity was maintained up to $600^{\circ}C$ regardless of the pH values in starting solutions. However, the second phase or high crsytalline hydroxypatite phase appeared above 80$0^{\circ}C$. In pH 9.5 and pH 10, $\beta$-whitlockite transformed to $\alpha$-whitlockite at 120$0^{\circ}C$, while in pH 10.5-11.5, hydroxyapatite phase was maintained up to 120$0^{\circ}C$.

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Effects of Protein Concentration, Heat Treatment and pH on the Foaming Properties of Caseinate (농도, 열처리 및 pH가 Caseinate의 거품성에 미치는 영향)

  • Yang, Seung-Taek
    • Applied Biological Chemistry
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    • v.37 no.4
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    • pp.259-265
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    • 1994
  • To investigate the effects of protein concentration, heat treatment and pH on the foaming properties of sodium caseinate, surface tension, apparent viscosity, turbidity, foaming ability and foam stability at 1.0, 3.0, 5.0, 7.0 and 10.0% (W/V), at 55 and $65^{\circ}C$ and at pH 6.0, 7.0 and 8.0 were examined. The conditions of protein concentrations for the foaming abilities were $3.0{\sim}7.0%$ (W/V). Foam stabilities of heated sodium caseinates were worse than those of unheated sodium caseinates (control) at pH6.0 and 7.0 (p<0.05), while the heated one were better than the unheated at pH 8.0, 10.0% concentrations (p<0.05). Also foam stabilities of sodium caseinate at pH 6.0 were higher than those at pH 7.0 and 8.0. Foaming ability and foam stability were inconsistently effected by changing protein concentration, heat treatment and pH.

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Optimization of Response Characteristics of pH-ISFET Glucose Sensor (완충용액과 효소고정화막의 조성에 따른 pH-ISFET 포도당센서의 감응특성)

  • Lee, Heung Lark;Yang, Seung Tae;Jung, Doog Sook;Kim, Chang Soo;Sohn, Byung Ki
    • Analytical Science and Technology
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    • v.5 no.2
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    • pp.177-184
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    • 1992
  • A preparation method and response characteristics of a glucose sensor which consisted of pH-ISFET and glucose oxidase-immobilized membrane were investigated. The pH-ISFET glucose sensor was fabricated by immbilizing bovine serum albumin and glucose oxidase with glutaraldehyde on gate of the pH-ISFET. Effects of pH and concentration of working buffer and enzyme load on the pontentiometric response of the pH-ISFET glucose sensor were examined. Response characteristics for the determination of glucose in synthetic physiological saline solution(pH 7.4) were as follows. That is the concentration range of linear response, slope of linear response(sensitivity), and response time were $1.0{\times}10^{-4}{\sim}6.0{\times}10^{-3}M $, 4.1 mV/decade, and 12~15 min., respectively.

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Extraction of Short Peptide Using Supported Liquid Membranes (Supported Liquid Membrane을 이용한 Short Peptide의 추출)

  • Lee, Jae-Heung;Park, Ki-Moon
    • Food Science of Animal Resources
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    • v.25 no.3
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    • pp.340-343
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    • 2005
  • The objective of this work was to study separation of short peptide (glycine-tyrosine) by using supported liquid membranes (SLMs) containing Aliquat as a cationic carrier, In the present investigation, the influence of pH of donor phase, concentrations of carrier and salt concentrations of acceptor phase on separation flux rate were investigated. Below pH 7.0 the flux rate was not affected by NaCl concentration or carrier concentration. However, the rate was increased significantly above pH 7.0. The rate with Hossain's SLM(H-SLM) containing $20\%$ Aliquat was about 3-fold higher with pH 9.0 at 0.25 M NaCl and 10-fold higher with pH 8.0 at 1.0 M NaCl than that with Duggan's SLM(D-SLM) containing $8\%$ Aliquat respectively. Furthermore, the rate with H-SLM was 10-fold higher at 1.0 M NaCl than the rate with 0.25 M NaCl, In conclusion, it would appear that the rate of separation was facilitated by using high salt concentrations together with high carrier concentrations above pH 7.0.

Resistance to a pH Fall with Water-Cement Ratio in Cementitous Material (물-시멘트비에 따른 시멘트계 재료의 pH 저하 저항성 평가)

  • Jung, Min-Sun;Ann, Ki-Yong;Song, Ha-Won
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.325-326
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    • 2009
  • The present study concerns the acid neutralization capacity (ANC) of cement paste, mortar and concrete depending on a free water-cement ratio. The ANC of paste at 30%, 40% and 50% of water-cement ratio was measured and simultaneously the effect of aggregate on the ANC was evaluated. It was found that an increase in the acid concentration resulted in a decrease in the pH of the suspension, in particular, at 10 in the pH, a sharp decrease was observed. The ANC showed some peak resistances to acid at particular pH values.

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An Observation on the Viability and pH of Lactobacillus casei isolated from Yakult. (유산균음과에서 분리한 Lactobacillus casei의 저장온도별 균수 및 pH의 경시적 변화 관찰)

  • 이용욱;이원창
    • Journal of Environmental Health Sciences
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    • v.3 no.1
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    • pp.1-3
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    • 1976
  • The authors studied the viability and pH of Lactobacillus casei which was isolated from the Yakult in terms of its storage temperature time(days). The following results have been obtained: (1) The viability test to Lactobacillus casei under storage in 4$\circ$C temperature condition in 35 days, has shown that the original population of $4.0\times 10^8$ organisms was decreased to $0.1\times 10^8$, under storage in 10$\circ$C temperature the organisms to $0.08\times 10^8$, in room temperature the organisms to $0.009\times 10^8$, and in 35$\circ$C temperature the organisms to $0.0009\times 10^8$. The correlation coefficient of storage period (days) and number of bacterial viability were significant as r=0.956(p<0.01) in 4$\circ$C, r=-0.999 (p<0.01) in 100C, r=0.975(p<0.01) in room temperature and r=-0.923(p<0.01) in 35$\circ$C. (2) The pH test to Lactobacillus casei unde.r storage in 4$\circ$C temperature condition for 35 days has shown that the original pH of 3.54 were acidified to 3.35, under storage in 10$\circ$C temperature the pH were acidified to 3.20, in room temperature the pH were acidified to 3.15, and in 35$\circ$C temperature the pH were acidified to 3.0. The correlation coefficient of variation of pH between storage period (days) and temperature were significant as r=-0.972(p<0.01) in 4$\circ$C, r=-0.922 (p<0.01) in 10$\circ$C, r=-0.963 (p<0.01) in room temperature and r=-0.953 in 35$\circ$C.

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A genome-wide association study (GWAS) for pH value in the meat of Berkshire pigs

  • Park, Jun;Lee, Sang-Min;Park, Ja-Yeon;Na, Chong-Sam
    • Journal of Animal Science and Technology
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    • v.63 no.1
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    • pp.25-35
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    • 2021
  • The purpose of this study is to estimate the single nucleotide polymorphism (SNP) effect for pH values affecting Berkshire meat quality. A total of 39,603 SNPs from 1,978 heads after quality control and 882 pH values were used estimate SNP effect by single step genomic best linear unbiased prediction (ssGBLUP) method. The average physical distance between adjacent SNP pairs was 61.7kbp and the number and proportion of SNPs whose minor allele frequency was below 10% were 9,573 and 24.2%, respectively. The average of observed heterozygosity and polymorphic information content was 0.32 ± 0.16 and 0.26 ± 0.11, respectively and the estimate for average linkage disequilibrium was 0.40. The heritability of pH45m and pH24h were 0.10 and 0.15 respectively. SNPs with an absolute value more than 4 standard deviations from the mean were selected as threshold markers, among the selected SNPs, protein-coding genes of pH45m and pH24h were detected in 6 and 4 SNPs, respectively. The distribution of coding genes were detected at pH45m and were detected at pH24h.

Problem Analysis of the Experiments Illustrating pH Effects on Enzyme Activities in High School Science Textbooks - Focus on Starch-Iodine Reaction - (고등학교 과학 교과서에서 "pH가 효소의 작용에 미치는 영향" 실험의 문제점 분석 -녹말과 요오드 반응을 중심으로-)

  • Ji, Jae-Hwa;Jeong, Dae-Hong
    • Journal of The Korean Association For Science Education
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    • v.29 no.8
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    • pp.923-933
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    • 2009
  • In this study, analysis was carried out on science experiment in high school textbooks, illustrating 'the effect of pH on enzyme activity.' Five of the total 16 science textbooks introduced in this experiment, and the experimental conditions therein were analyzed. Textbook analysis revealed that pH of below 3 was used for 'acidic condition' and that of over 11 was used for 'basic' condition. Using the experimental conditions described in the textbooks, review experiments were performed. Buffering effect with the addition of saliva was found in the pH region around 7 when buffer solution was not used to control pH as was in the textbooks. The enzyme activity experiments were performed controlling pH from pH 2 to 13 with buffer. The color of the sample was blue from pH 2 to 4, and then disappeared from pH 5 to 8, reflecting that starch was digested owing to enzyme activity. In pH 9 light blue color appeared, indicating de-activation of enzyme under this basic condition. However, the blue color of the sample became lighter at pH 10 and disappeared from pH 11, which was different from the expected behavior anticipating dark blue color due to de-activation of enzyme under strong basic condition. These results can wrongly influence students to interpret that enzyme can be activated in this pH condition. So, we analyzed the reason for the color of the sample turning light blue in pH 10 and disappeared from pH 11. The analysis resulted that ${I_3}^-$ and/or ${I_5}^-$ subunits of polyiodides within the starch helix in starch-iodine complex, showing blue, decreases above pH 10 due to disproportionation to HOI, ${IO_3}^-$, and $I^-$ by the reaction with $OH^-$.

Relation between Leaching Characteristics of the positive Ions and Phosphate Removal by granular Converter Slag for the different Conditions and Concentrations of Phosphate (인산염 농도와 폐수조건 변화에 따른 입상 전로슬래그의 양이온 용출 특성과 인산염 제거의 관계에 관한 연구)

  • Lee, In-Gu;Lee, Sang-Ho
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.8 no.2
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    • pp.372-379
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    • 2007
  • The converter slag can be used to remove phosphate ion into the form of solid state from the wastewater. This research aims to evaluate the change of pH, alkalinity, leaching of positive ion in the wastewater and the removal of phosphate from the initial condition of wastewater. The change of pH was abruptly increased upto pH 11 for the initial condition of pH from 7.0 to 8.5 fer 0.5 unit of pH. The alkalinity was steadily increased from 10 hours of reaction time not same as pH increase. The removal of phosphate was very effective till 10 hours of reaction then it was slow after that time. The positive ion, magnesium ion was leached from the concentration of 2.0 mg/L to 4.3mg/L at the reaction time of 27 hours and 36 hours. Therefore, converter slag can be used to remove the phosphate in the form of Struvite from the wastewater.

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