• Proceedings of the Korean Vacuum Society Conference
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• 2010.08a
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• pp.242-242
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• 2010

SiO2박막을 이온 감지막으로 이용한 pH농도센서를 제작하였다. 현재 많은 연구중인 pH센서, pH-ISFET(pH-Ion Sensitive Field Effect Transistor)는 용액과 기준전극간의 전기화학적 변위차를 이용하여 pH를 센싱한다. pH-ISFET는 기존 CMOS공정을 그대로 이용할 수 있고, 이온감지막의 변화만으로 다양한 센서를 제작할 수 있어 최근 많은 연구가 진행 중이다. 하지만 FET를 제작하기 위한 공정의 복잡성과 용액의 전위를 정해주고 FET에 바이어스를 인가해줄 기준전극이 반드시 필요하다는 제한성이 있다. 따라서 본 연구에서는 SOI 기판을 이용하여 간단한 구조의 pH센서를 제작하였다. 센서는 (100)결정면을 가지는 p-타입 SOI(Silicon On Insulator)기판을 사용하였으며 포토리소그래피 공정을 이용하여 back-gated MOSFET구조로 제작하였다. 이온감지막으로 사용할 SiO2박막은 RF 스퍼터링을 이용하여 $100{\AA}$ 증착하였다. 바이어스는 기존 pH-ISFET와는 다르게 기준전극 대신 기판을 backgate로 사용하여 FET에 바이어스를 인가해 주었다. pH 용액 주입을 위해 PDMS재질의 챔버를 제작하고 실리콘글루를 이용하여 센서에 부착하였다. pH12부터 pH4까지 단계적으로 누적시키며 챔버에 주입하였고, pH에 따른 드레인전류의 변화를 관찰하였다. pH용액을 챔버에 주입시, pH농도에 따라 제작된 센서의 문턱전압이 오른쪽으로 이동하는 결과를 관찰할 수 있었다. 결과적으로, 구조가 간단한 pseudo MOSFET을 이용하여 pH센서의 적용가능성을 확인하였으며 SiO2박막 역시 본 pH센서의 이온감지막의 역할과 센서의 안정성을 향상시킬 수 있다는 점을 확인하였다.

• Nuclear Engineering and Technology
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• v.15 no.3
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• pp.179-187
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• 1983

The pH of containment spray and sump water following a LOCA for KNU 5'||'&'||'6 and KNU 1 was calculated to see if pH design criteria of containment spray system established by USNRC were met. The pH calculations have been made for the two cases; maximum pH and minimum pH. For KNU 5'||'&'||'6, results showed that long term sump pH values calculated for the maximum pH and minimum pH case well met the pH requirement of at least 8.5 and spray pH for the maximum case slightly exceeded the range of design criteria (8.5 to 11.0). For KNU 1, pH requirement of long term sump pH was also met, however, spray pH value for the maximum pH case was very largely greater than that of current pH requirement. (No pH requirement of containment spray water has been established at the time of designing KNU 1) In order to find the design parameters of containment spray system which are expected to meet the spray pH requirement, several calculations were wade, by changing the input parameters to "LCCAPH". Finally, it was shown that the boric acid concentration in RWST (refueling water storage tank), which was the primary sources of containment spray water during injection mode, be maintained the range of 2750 ppm to 2850 ppm, or tile flow rate of NaOH added to spray water he kept between 10 gpm to 24 gpm.

• Journal of Animal Science and Technology
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• v.45 no.5
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• pp.835-840
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• 2003

Two hundreds and twenty three pork carcasses of commercial breeds were studied for comparing to technical quality characteristics of pork identified by National Pork Producers Council(NPPC) scale. pH and conductance(C) were taken in 1(pH$_1$, C$_1$), 3(pH$_3$, C$_3$), 6(pH$_6$, C$_6$) and 24hr(pHu, Cu) postmortem on 4~5th thoracic vertebrae. Visual color and CIE value were estimated in longissimus dorsi(LD) muscle in 24hr postmortem on the two sites(4~5th thoracic vertebrae and last vertebrae) using National Pork Producers Council(NPPC) scale and color difference meter. Significant differences were observed in pH$_1$, pHu, Cu, CIE L$^{*}$ value, water holding capacity(WHC) and juiciness at all scales(p〈0.05). But, pH and CIE L$^{*}$value were considerably affected by postmortem time and measuring site. NPPC scale was highly related with CIE L$^{*}$(R$^2$=0.77) and WHC(R$^2$=0.66), and moderately related with C$_{u}$(R$^2$=0.59) and pH$_{u}$(R$^2$=0.54), and poorly related with pH$_3$(R$^2$=0.32), pH$_6$(R$^2$=0.28) and C$_1$～C$_6$(R$^2$=0.03~0.18).

• Journal of the Korean Society for Nondestructive Testing
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• v.22 no.4
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• pp.347-353
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• 2002

A structure of a glass electrode-type pH sensor for measuring any concentration of $H^+$ in an aqueous solution was embodied with bulk micromachining technology. Two open well structures were formed, and a reference electrode was secured by the Ag/AgCl thin film in the sloped side of the etched structure. A sensitive membrane of an indicator electrode for generating a potential by an exchange reaction to $H^+$ was made with a glass containing Na 20% or more finely so that its thickness might be $100{\mu}m$ or so, and then it was bonded to one pyramidal structure. A liquid junction for a current path was formed by filling an agar in the anisotropically etched part of the Si wafer, which had a size of $50{\mu}m{\times}50{\mu}m$, and then bonded it to the other. After complete fabrication of each part, it was filled with a 2M KCl reference solution and encapsulated the sensor structure with a cold expoxy. The potential value of fabricated pH sensor was about 90mV/pH in the standard pH solutions.

• Microbiology and Biotechnology Letters
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• v.9 no.2
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• pp.91-97
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• 1981

A thermophilic soil isolate Bacillus sp. Y-127 was selected for the production of thermostable amylase. The strain was used for the enzyme production and the thermostable amylase was characterized. The optimum cultural conditions for the enzyme production were 6$0^{\circ}C$ at pH 7.0 for 32 hours using a mineral medium containing 2% soluble starch and 0.2% yeast extract. The extra-cellular enzyme was purified about 123-folds with about 6% recovery. The purified enzyme was stable at pH between 4.0 and 7.0, and temperature up to 6$0^{\circ}C$.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.37 no.1
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• pp.73-82
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• 2017

In Korea, previous certification of water supply infrastructure was mainly focused on economical and physical aspects. Recently, hygienic safety of water supply service has become a sensitive and important issue to our people for evaluating the water quality with growth of economy and education system. According on water quality in 497 Korean water supply facilities, pH values in the supplied water have ranged between 5.8-8.5. However, little is known about metal leachability at the pH conditions observed in the real water supply systems because a fixed pH condition (pH 7.0) has been used in the current standard method, 'Hygienic Safety Testing Method', in water supply. In this work, we examined the effects on heavy metal leachability with pH differences in the water supply pipes which are typically used in Korea. As a result, the amounts of metal leachability were tended to increase when pH levels were decreased. Especially at pH 5.8, Cu leachability from Cu pipes was found to exceed the public health standard level even after applying a normalization factor (NF) given by the current Korea standard method. The Cr and Cu leached from stainless steel pipes, Cd, Pb, Cu, and Zn from Cu-based pipe fittings, and Zn from Zn-based pipe fittings were exceeded the Korean hygienic safety standards while, after applying the NF, concentrations of the leached metals were satisfied with the current Korean standard. The findings from this work provide implications on the needs of reforming the current hygienic safety standard methodology.

• KSBB Journal
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• v.19 no.3
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• pp.221-225
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• 2004

Bacillus polyfermenticus SCD derived from Bacillus sp., which is commonly called as Bisroot$^{ⓡ}$. The goal of this study, is to Increase stability of Bacillus polyfermenticus SCD in low pH, high temperature and high glucose concentration via three layer coating. The viability of coated Bacillus polyfermenticus SCD increased to 30%, 20%, 14% in the condition of pH 2 4 6 than that of uncoated Bacillus polyfermenticus SCD at 37$^{\circ}C$ for 4 h. Final viability of the coated Bacillus polyfermenticus SCD in 80$^{\circ}C$ increased to 40% than that of uncoated Bacillus polyfermenticus SCD. In high glucose concentration coated Bacillus polyfermenticus SCD is more stable than uncoated about 50%. In conclusion, the three layer coated Bacillus polyfermenticus SCD is very stable for low pH, high temperature and high glucose concentration.

• Korean Journal of Organic Agriculture
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• v.23 no.3
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• pp.595-604
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• 2015

Soil chemical properties in paddy fields were found to be varied depending upon different cultivation methods such as environmentally-friendly, conventional, and two-crop farming systems and different topographical regions, namely plain, middle mountainous, and reclaimed land regions. Overall soil pH was found to be in optimal range (pH 5.5~6.5) for rice cultivation, except with conventional cultivation fields of the reclaimed lands in Jeonnam province. Electrical conductivity (EC) was relatively higher in the two-crop cultivation fields than in others. However, the concentrations of available phosphate as $P_2O_5$ were exceptionally higher in the two-crop farming fields, thus in submerged paddy condition the phosphate could be released into streams and rivers. Soil organic matter (SOM) contents were mostly in optimal range ($25{\sim}30g\;kg^{-1}$) for paddy field in Jeonbuk province, but in Jeonnam province they were slightly higher values of the range. The concentrations of available silicate ($SiO_2$) were mostly depended on the cultivation methods and the region, but some of paddy fields contained extremely high $SiO_2$ concentration. Statistical relationships among the soil chemical properties showed as follows: Correlations between EC values and exchangeable cation concentrations, between SOM contents and CEC values, and between available $SiO_2$ concentrations and pH, EC, exchangeable cations, and CEC values were positively significant, whereas total nitrogen concentrations were significantly negatively correlated with the concentrations of exchangeable K and Mg. These results might be very useful to establish benchmark paddy fields contained with certain levels of soil fertility.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.09a
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• pp.272-276
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• 2003

본 연구는 제주지역 지하수의 수질 특성 중 pH에 주목하여 공간적 분포특성을 파악하였다. 먹는 물 수질기준의 경우 pH는 5.8∼8.5의 범위를 요구하고 있다. 제주지하수의 대부분은 이 범위 내에 속하나 특정지역의 경우 상한선을 초과하는 경우도 있다. 이의 원인을 규명키 위한 기초적 조사로서 우선 공간적 분포 특성을 조사하였고 조사결과 지하수위 구성암질 및 오염원과의 명확한 상관성은 판단하기 어려우나 추후 연속적인 측정과 자료분석을 토대로 검토예정이다.

• Journal of Korean Society of Environmental Engineers
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• v.28 no.3
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• pp.286-291
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• 2006

We studied possibility of mixing treatment of livestock wastewater and sewage using Phanerochaete chrysosporium PSBL-1. Our study showed that 97.6% of SS and 95% of T-P removal efficiency was achieved when 2 mL BF02(a coagulant) and 100 mL C-210EL(a cationic polymer) were added to the mixture(2:1, v/v) of livestock wastewater and sewage. We studied treatment characteristic of Phanerochaete chrysosporium PSBL-1, after were mixed pretreated wastewater and sewage by dillution ten times about livestock wastewater. The removal efficiency of NBDCOD(non-biodegradable COD), $NH_3-N$ and T-N was increased according to increase of pH. That is, T-N concentration of effluent was satisfied 60 mg/L by drain water waterqulity standard of livestock wastewater public treatment facilities with 35 mg/L from a lapse of five days at pH 6.7, 51 mg/L from a lapse of three days at pH 8 and 33 mg/L from a lapse of one day at pH 10. Moreover $COD_{Mn}$ concentration of effluent was satisfied 40 mg/L by drain water waterqulity standard of livestock wastewater public treatment facilities after a laps of one day at all pH. Organics and nitrogen concentrations of effluent were higher case with addition of V.A.(veratryl alcohol) than case without addition of V.A.(veratryl alcohol). $COD_{Mn}$ concentration of effluent satisfied drain water qulity standard of livestock wastewater public treatment facilities from a lapse of one day, when C/N rate(3:1) of influent was not controled. T-N satisfied that from a lapse of two days, when C/N rate was controled with $4{\sim}6$.