• 제목/요약/키워드: pCR

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커피찌꺼기를 이용한 폐수 중의 Pb, Cr, Cd의 제거에 관한 연구 (A Study on Removal of Pb, Cr, Cd in Wastewater Using Exhausted Coffee)

  • 임성훈;정문식;박석환
    • 한국환경보건학회지
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    • 제21권1호
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    • pp.21-28
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    • 1995
  • The removal of heavy metals from synthetic wastewater containing Pb, Cr, Cd using previously washed and dried exhausted coffee was studied varying cohcentration, pH and temperature. All the heavy metals were removed in 3.0 minutes and the removal efficiency was maximum 80~90% with different pH and temperature conditions. The differences in removal efficiency between exhausted coffee and activated carbon under the same conditions were not seen. The removal efficiency was slightly increased with increasing pH in Cd and increasing temperature in Cr, respectively. The batch adsorption kinetics and adsorption equilibrium were examined and described by a first order reversible reaction and Freundlich isotherm, respectively. And the removal of Pb was found to have the best removal efficiency.

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Nitrogen-doped carbon nanosheets from polyurethane foams and removal of Cr(VI)

  • Duan, Jiaqi;Zhang, Baohua;Fan, Huailin;Shen, Wenzhong;Qu, Shijie
    • Carbon letters
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    • 제22권
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    • pp.60-69
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    • 2017
  • Nitrogen-doped carbon nanosheets with a developed porous structure were prepared from polyurethane foams by hydrothermal carbonization following $ZnCl_2$ chemical activation. Scanning electron microscopy, thermogravimetric analysis, Fourier transform infrared spectroscopy, solid state $^{13}C$ nuclear magnetic resonance (NMR) spectra and X-ray photoelectron spectroscopy were used to characterize the nitrogen-doped carbon nanosheet structure and composition. The removal of Cr(VI) by the N-doped carbon nanosheets was investigated. The results showed that the maximum removal capacity for chromium of 188 mg/g was found at pH=2.0 with PHC-Z-3. pH had an important effect on Cr(VI) removal and the optimal pH was 2.0. Moreover, amino groups and carboxyl groups in the nitrogen-doped carbon nanosheet played important roles in Cr(VI) removal, and promoted the reduction of Cr(VI) to Cr(III).

CONTACT THREE CR-SUBMANIFOLDS OF A (4m + 3)-DIMENSIONAL UNIT SPHERE

  • Kim, Hyang-Sook;Kim, Young-Mi;Kwon, Jung-Hwan;Pak, Jin-Suk
    • 대한수학회지
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    • 제44권2호
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    • pp.373-391
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    • 2007
  • We study an (n+3)($n\;{\geq}\;7-dimensional$ real submanifold of a (4m+3)-unit sphere $S^{4m+3}$ with Sasakian 3-structure induced from the canonical quaternionic $K\"{a}hler$ structure of quaternionic (m+1)-number space $Q^{m+1}$, and especially determine contact three CR-submanifolds with (p-1) contact three CR-dimension under the equality conditions given in (4.1), where p = 4m - n denotes the codimension of the submanifold. Also we provide necessary conditions concerning sectional curvature in order that a compact contact three CR-submanifold of (p-1) contact three CR-dimension in $S^{4m+3}$ is the model space $S^{4n_1+3}(r_1){\times}S^{4n_2+3}(r_2)$ for some portion $(n_1,\;n_2)$ of (n-3)/4 and some $r_1,\;r_2$ with $r^{2}_{1}+r^{2}_{2}=1$.

치과주조용 비귀금속 합금의 금속 용출 수준 (Concentration of elemental ions released from non-precious dental casting alloys)

  • 사공준;박수철
    • 대한치과기공학회지
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    • 제35권1호
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    • pp.1-17
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    • 2013
  • Purpose: This study was to assess the extents of the release of metals from the non-precious alloys used for dental casting by measuring the differences in the extents of the release of metals by types of alloys, pH level and elapsed time. Methods: Uniform-sized specimens(10 each) were prepared according to the Medical Device Standard of the Korea Food and Drug Administration(2010) and International Standard Organization(ISO22674, 2006), using four types of alloys(one type of Ni-Cr and one type of Co-Cr used for fixed prosthesis, and one type of Ni-Cr and one type of Co-Cr used for removable prosthesis). A total of 12 metal-release tests were performed at one-day, three-day, and two-week intervals, for up to 20 weeks. The metal ions were quantified using an Inductively Coupled Plasma-Atomic Emission Spectrometer. Results: The results showed that the extent of corrosion was higher in the ascending order of Jdium-$100^{(R)}$, Bellabond-$Plus^{(R)}$, Starloy-$C^{(R)}$, and Biosil-$F^{(R)}$. The lower the pH and the longer the elapsed time were, the greater the increase in metal corrosion. At pH 2.4, the release of Ni from Jdium-$100^{(R)}$, a Ni-Cr alloy, was up to 15 times greater than the release of Co from the Co-Cr alloy from two weeks over time, indicating that the Ni-Cr alloy is more susceptible to corrosion than the Co-Cr alloy. Conclusion: It is recommended that Co-Cr alloy, which is highly resistant to corrosion, be used for making dental prosthesis with a non-precious alloy for dental casting, and that non-precious alloy prosthesis be designed in such a way as to minimize the area of its oral exposure. For patients with non-precious alloy prostheses, a test of the presence or absence of periodontal tissue inflammation or allergic reaction around the prosthesis should be performed via regular examination, and education on the good management of the prosthesis is needed.

각종(各種) 신질환(腎疾患)에서의 혈청(血淸) $\beta_2-microglobulin$ 측정(測定)의 의의(意義) (The Significance of Serum $Beta_2-Microglobulin$ Measurement in Various Renal Diseases)

  • 궁성수;오하영;한진석;이정상
    • 대한핵의학회지
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    • 제19권1호
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    • pp.127-136
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    • 1985
  • To evaluate change of serum $beta_2-microglobulin$ concentration$(s\beta_2-MG)$ and the usefulness of $s\beta_2-MG$ and $s\beta_2-MG/serum$ creatinine concentration(sCr) ratio in various renal diseases, $s\beta_2-MG$ and sCr were measured in 25 normal controls and 90 patients of various renal diseases(16 cases of glomerulonephritis, 12 cases of acute renal failure, 8 cases of chronic renal failure, 24 cases of nephrotic syndrome, 15 cases of tubulointerstitial diseases and 15 cases of lupus nephritis) using $Phadebas^\circledR$ $Beta_2-Micro$ Test kits. The results were as follows; 1) In normal control, the mean value of $s\beta_2-MG$ was $1.65{\pm}0.41mg/l$ and the mean value of $s\beta_2-MG/sCr$ ratio was $0.14{\pm}0.05$. 2) In various renal diseases, the mean value of $s\beta_2-MG$ was $6.74{\pm}5.47mg/l$. The mean value of $s\beta_2-MG/sCr$ ratio was $0.24{\pm}0.11$ and significantly elevated than that of normal control. (p<0.05) 3) The correlation between $s\beta_2-MG$ and sCr in glomerular and tubulointerstitial disease was log $s\beta_2-MG-0.90$ log sCr-0.48 and its correlation coefficient was 0.78(p<0.05). 4) In glomerular disease, the correlation between $s\beta_2-MG$ and sCr was log $s\beta_2-MG-0.89$ log sCr-0.46(r - 0.76) and in tubulointerstitial disease, it was log, $s\beta2-MG-0.95$ log sCr-0.59 (r-0.87). There was no significant difference between the two groups(p<0.05). 5) Among 32 cases of glomerular and tubulointerstitial disease patients, whose sCr was within normal range, 17 cases showed elevated $s\beta_2-MG$. The mean values of $s\beta_2-MG/sCr$ ratio in these patients was $0.30{\pm}0.14$ and significantly elevated than that of normal control(p<0.05). 6) In 15 cases of lupus nephritis, 12 cases showed elevated $s\beta_2-MG$ with normal sCr and 12 cases showed elevated $s\beta_2-MG/sCr$ ratio. With above results, it was found that the $s\beta_2MG$ can be used as an index of glomerular filtration rate as in the case of sCr and that $s\beta_2-MG/sCr$ ratio can be used as a tool in early detection of slightly decreased glomerular filtration rate and in detection of the renal disease of increased $\beta_2-MG$ production.

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Effects of Different Forms of Chromium Supplements on Serum Glucose, Insulin and Lipids in Rats

  • Ohh, Sang-Jip;Kim, Chang-Hyeuk;Shin, Jong-Seo;Sung, Kyung-Il;Kim, Hyun-Sook
    • Preventive Nutrition and Food Science
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    • 제9권4호
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    • pp.342-345
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    • 2004
  • This study evaluated the effects of different forms of chromium supplements on serum glucose, insulin and lipid concentrations in rats. Sprague-Dawley male rats were randomly assigned to one of three dietary groups and fed AIN-76 semi-purified basal diets supplemented with 300 ppb Cr from Cr methionine (CrMet) and Cr chloride $(CrCI_3)$ or without Cr (control). By the end of the $4^{th}$ week, all rats were decapitated, blood collected, and serum glucose, insulin and lipid concentrations were determined. The CrMet and $CrCl_3$ supplementation did not affect weight gain and feed efficiency ratio. However, feed intake was significantly higher in CrMet groups than control (p < 0.05). CrMet-supplemented rats had markedly increased insulin levels (p < 0.05) compared with controls. Serum lipids were not significantly different between the control and the CrMet groups. $CrCl_3$ supplementation decreased total cholesterol and triglyceride, but the decreases were only significant for the control group. $CrCl_3$ supplementation was associated with significant decreases in total cholesterol compared with CrMet supplementation. These results indicate that CrMet supplementation is effective for increasing serum insulin, and $CrCl_32$ may improve lipid concentrations, because we observed decreased serum total cholesterol and an improved total cholesterol/HDL-cholesterol ratio (THR).

Buckling analysis of filament wound composite cylindrical shell for considering the filament undulation and crossover

  • Guo, Zhangxin;Han, Xiaoping;Guo, Meiqing;Han, Zhijun
    • Structural Engineering and Mechanics
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    • 제55권2호
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    • pp.399-411
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    • 2015
  • The buckling equations of filament wound composite cylindrical shell are established. The coefficients $K_{ij}$ and $L_{ij}$ of the buckling equations are determined by solving the equations. The geometric analysis and the effective stiffness calculation for the fiber crossover and undulation region are respectively accomplished. Using the effective stiffness of the undulation region, the specific formulas of the coefficients ${K^{\prime}}_{ij}$ and ${L^{\prime}}_{ij}$ of the buckling equations are determined. Numerical examples of the buckling critical loads have been performed for the different winding angles and stacking sequences cylindrical shell designs. It can be concluded that the fiber undulation results in the less effect on the buckling critical loads $P_{cr}$. $P_{cr}$ increases with the thickness-radius ratio. The effect on $P_{cr}$ due to the fiber undulation is more obvious with the thickness-radius ratio. $P_{cr}$ decreases with the length-radius ratio. The effect on $P_{cr}$ due to the fiber undulation can be neglected when the ratio is large.

Application of an Electric Field Refrigeration System on Pork Loin during Dry Aging

  • Park, Sin-Young;Kim, Hack-Youn;Choe, Juhui
    • 한국축산식품학회지
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    • 제39권4호
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    • pp.668-676
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    • 2019
  • This study aimed to investigate the effect of an electric field refrigeration (EFR) on the quality characteristics of pork loin including dry aging loss, pH, water holding capacity (WHC), cooking loss, color, shear force, thiobarbituric acid reactive substances (TBARS), and microbial growth during dry aging (0, 1, 2, 3, 4, 7, and 9 wk) in comparison with a commercial refrigerator (CR). Total plate counts (TPC) of the CR group approached 8.07 Log CFU/g at 2 wk of dry aging, thus indicating meat spoilage. Cooking loss, lightness, and shear force of EFR were significantly decreased (p<0.05) at subsequent aging weeks in both the EFR and CR. Aging loss, TPC, TBARS levels increased at subsequent aging weeks; however, pH values were not influenced by aging. At the same aging weeks (1 or 2 wk), the EFR group displayed significantly lower values (p<0.05) of aging loss, pH, TPC, and TBARS levels than the CR group. No significant differences in WHC, cooking loss, and shear force was observed until 2 wk of aging between the EFR and CR groups. The present results show that application of the EFR system improves the tenderness, color, and lipid oxidation stability of pork loin and extends its shelf life in comparison with a commercial refrigeration.

시멘트 수화에 따른 6가 크롬의 고정화 특성 (Binding of the Hexavalent Chromium Ions in the Process of Cement Hydration)

  • 정민선;황준필;홍성인;안기용
    • 한국구조물진단유지관리공학회 논문집
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    • 제17권6호
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    • pp.88-94
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    • 2013
  • 시멘트 내 6가 크롬은 피부질환이나 암을 유발할 수 있는 유해한 인체에 유해한 이온으로 잘 알려져 있다. 본 연구에서는 사람에게 영향을 주는 시멘트 내 6가 크롬의 정량적 분석을 하고자 시멘트 및 시멘트 경화체 내 6가 크롬의 고정화에 대해 평가하였다. 국내에서 생산되는 일반 포틀랜드 시멘트 3종과 플라이애쉬, 고로슬래그 미분말, 실리카퓸을 사용하여 수용성 및 산가용성 6가 크롬을 분광광도법으로 측정하였다. 측정결과, 시멘트 내 수용성 6가 크롬의 농도는 10.5-18.9 mg/kg-cement 범위였으며 혼화재료 내 수용성 6가 크롬의 양은 매우 적게 측정되었다. 시멘트 내 산가용성 6가 크롬의 농도는 172.4-318.2 mg/kg-cement 범위로 측정되었으며 수용성 6가 크롬에 비해 증가하였다. 그러나 크롬의 pH에 의존적인 용해 특성에 따라 용매의 pH가 저감된다고 하여 산가용성 6가 크롬의 농도가 항상 크게 측정되지는 않았다. 시멘트 수화 후 수용성 6가 크롬은 2.0 mg/kg-cement 정도로 감소하였으며 이는 크롬산-에트링게이트 생성에 의한 결과임을 확인할 수 있었다.

Cr(VI) Resistance and Removal by Indigenous Bacteria Isolated from Chromium-Contaminated Soil

  • Long, Dongyan;Tang, Xianjin;Cai, Kuan;Chen, Guangcun;Shen, Chaofeng;Shi, Jiyan;Chen, Linggui;Chen, Yingxu
    • Journal of Microbiology and Biotechnology
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    • 제23권8호
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    • pp.1123-1132
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    • 2013
  • The removal of toxic Cr(VI) by microorganisms is a promising approach for Cr(VI) pollution remediation. In the present study, four indigenous bacteria, named LY1, LY2, LY6, and LY7, were isolated from Cr(VI)-contaminated soil. Among the four Cr(VI)-resistant isolates, strain LY6 displayed the highest Cr(VI)-removing ability, with 100 mg/l Cr(VI) being completely removed within 144 h. It could effectively remove Cr(VI) over a wide pH range from 5.5 to 9.5, with the optimal pH of 8.5. The amount of Cr(VI) removed increased with initial Cr(VI) concentration. Data from the time-course analysis of Cr(VI) removal by strain LY6 followed first-order kinetics. Based on the 16S rRNA gene sequence, strain LY6 was identified as Pseudochrobactrum asaccharolyticum, a species that had never been reported for Cr(VI) removal before. Transmission electron microscopy and energy dispersive X-ray spectroscopy analysis further confirmed that strain LY6 could accumulate chromium within the cell while conducting Cr(VI) removal. The results suggested that the indigenous bacterial strain LY6 would be a new candidate for potential application in Cr(VI) pollution bioremediation.