• Title/Summary/Keyword: p.p.-ring

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Ab Initio Study of Mechanism of Forming Spiro-Heterocyclic Ring Compound Involving Si and Ge from Dichlorosilylene Germylidene (Cl2Si-Ge:) and Acetone

  • Liu, Dongting;Ji, Hua;Lu, Xiuhui
    • Bulletin of the Korean Chemical Society
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    • v.33 no.12
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    • pp.4079-4083
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    • 2012
  • The mechanism of the cycloaddition reaction between singlet state dichlorosilylene germylidene ($Cl_2Si=Ge:$) and acetone has been investigated with B3LYP/6-$31G^*$ and B3LYP/6-$31G^{**}$ method, from the potential energy profile, we predict that the reaction has one dominant reaction pathway. The presented rule of the reaction is that the two reactants firstly form a Si-heterocyclic four-membered ring germylene through the [2+2] cycloaddition reaction. Because of the 4p unoccupied orbital of Ge atom in the Si-heterocyclic four-membered ring germylene and the ${\pi}$ orbital of acetone forming a ${\pi}{\rightarrow}p$ donor-acceptor bond, the Si-heterocyclic four-membered ring germylene further combines with acetone to form an intermediate. Because the Ge atom in the intermediate hybridizes to an $sp^3$ hybrid orbital after the transition state, then, the intermediate isomerizes to spiro-heterocyclic ring compound involving Si and Ge (P4) via a transition state.

THE STRUCTURE OF THE RADICAL OF THE NON SEMISIMPLE GROUP RINGS

  • Yoo, Won Sok
    • Korean Journal of Mathematics
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    • v.18 no.1
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    • pp.97-103
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    • 2010
  • It is well known that the group ring K[G] has the nontrivial Jacobson radical if K is a field of characteristic p and G is a finite group of which order is divided by a prime p. This paper is concerned with the structure of the Jacobson radical of such a group ring.

Cytogenetic evaluation of a patient with ring chromosome 9 presenting failure to thrive and developmental delay (성장부진과 발달지연을 보인 환아에서 확인된 환상 9번 염색체 1례의 세포유전학적인 연구)

  • Park, Yun Mi;Nho, Han Nae;Kim, Sook Za;Ahn, Young Min
    • Clinical and Experimental Pediatrics
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    • v.51 no.4
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    • pp.426-430
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    • 2008
  • We report clinical, cytogenetic, and fluorescence in situ hybridization (FISH) studies of a patient with ring chromosome 9. She presented with failure to thrive, facial dysmorphysm and mild psychomotor development delay in the absence of major malformations. Peripheral blood karyotype of the patient was 46,XX,r(9)(p24q34). G-band analysis suggested no loss of material in the ring chromosomes. FISH analysis using the subtelomere-specific sequences on chromosome 9p and 9q, revealed 46,XX,r(9)(p24q34),ish r(9)(D9S913-,D9S325+). Failure to detect any hybridization of a probe for the subtelomeric sequences in the ring 9p terminal suggested that this ring arose from breakage in the distal short arm. The cytogenetic and FISH data in our case provided further evidence for the existence of a "complete ring" phenotype with incomplete subtelomeric sequences.

ON ANNIHILATIONS OF IDEALS IN SKEW MONOID RINGS

  • Mohammadi, Rasul;Moussavi, Ahmad;Zahiri, Masoome
    • Journal of the Korean Mathematical Society
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    • v.53 no.2
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    • pp.381-401
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    • 2016
  • According to Jacobson [31], a right ideal is bounded if it contains a non-zero ideal, and Faith [15] called a ring strongly right bounded if every non-zero right ideal is bounded. From [30], a ring is strongly right AB if every non-zero right annihilator is bounded. In this paper, we introduce and investigate a particular class of McCoy rings which satisfy Property (A) and the conditions asked by Nielsen [42]. It is shown that for a u.p.-monoid M and ${\sigma}:M{\rightarrow}End(R)$ a compatible monoid homomorphism, if R is reversible, then the skew monoid ring R * M is strongly right AB. If R is a strongly right AB ring, M is a u.p.-monoid and ${\sigma}:M{\rightarrow}End(R)$ is a weakly rigid monoid homomorphism, then the skew monoid ring R * M has right Property (A).

Conformations of Tetrahomodioxa-p0phenylcalix[4]arene Alkyl Ethers

  • No, Kwang-Hyun;Park, Young-Ja
    • Bulletin of the Korean Chemical Society
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    • v.23 no.11
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    • pp.1629-1634
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    • 2002
  • Reaction of tetrahomodioxa p-phenylcalix[4]arene with alkyl halide and NaH in DMF leads to the title tetra-alkylated derivatives, 7,13,21,27-tetra-phenyl-29,30,31,32-tetraalkyloxy-2,3,16,17-tetrahomo-3,17-dioxacalix [4]arenes, their preferred conformations were determined by NMR spectra as C-1,2-alternate. The molecular structure of allyl derivative has been solved by X-ray diffraction methods. The molecules have a conformation with pseudo center of symmetry. The benzene ring A is up, ring C is down, B and D rings are flat with respect to the plane of the macrocyclic ring.

GENTRAL SEPARABLE ALGEBRAS OVER LOCAL-GLOBAL RINGS I

  • Kim, Jae-Gyeom
    • Bulletin of the Korean Mathematical Society
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    • v.30 no.1
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    • pp.61-64
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    • 1993
  • In this paper, we show that if R is a local-global domain then the Question holds. McDonald and Waterhouse in [6] and Estes and Guralnick in [5] introduced the concept of local-global rings (so called rings with many units) independently. A local-global ring is a commutative ring R with 1 satisfying; if a polynomial f in R[ $x_{1}$, .., $x_{n}$] represents a unit over $R_{P}$ for every maximal ideal P in R, then f represents a unit over R. Such rings include semilocal rings, or more generally, rings which are von Neumann regular mod their Jacobson radical, and the ring of all algebraic integers.s.s.

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Identities in a Prime Ideal of a Ring Involving Generalized Derivations

  • ur Rehman, Nadeem;Ali Alnoghashi, Hafedh Mohsen;Boua, Abdelkarim
    • Kyungpook Mathematical Journal
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    • v.61 no.4
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    • pp.727-735
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    • 2021
  • In this paper, we will study the structure of the quotient ring R/P of an arbitrary ring R by a prime ideal P. We do so using differential identities involving generalized derivations of R. We enrich our results with examples that show the necessity of their assumptions.

ON THE COHOMOLOGICAL DIMENSION OF FINITELY GENERATED MODULES

  • Bahmanpour, Kamal;Samani, Masoud Seidali
    • Bulletin of the Korean Mathematical Society
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    • v.55 no.1
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    • pp.311-317
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    • 2018
  • Let (R, m) be a commutative Noetherian local ring and I be an ideal of R. In this paper it is shown that if cd(I, R) = t > 0 and the R-module $Hom_R(R/I,H^t_I(R))$ is finitely generated, then $$t={\sup}\{{\dim}{\widehat{\hat{R}_p}}/Q:p{\in}V(I{\hat{R}}),\;Q{\in}mAss{_{\widehat{\hat{R}_p}}}{\widehat{\hat{R}_p}}\;and\;p{\widehat{\hat{R}_p}}=Rad(I{\wideha{\hat{R}_p}}=Q)\}$$. Moreover, some other results concerning the cohomological dimension of ideals with respect to the rings extension $R{\subset}R[X]$ will be included.

THE EFFECT OF INVESTMENT'S W/P RATIO ON THE FIN OF PARTIAL DENTURE METAL CASTINGS (매몰재의 혼수비가 국부의치 금속구조물의 Fin에 미치는 영향에 관한 실험적 연구)

  • Choi, Sub-Ho
    • The Journal of Korean Academy of Prosthodontics
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    • v.16 no.1
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    • pp.45-47
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    • 1978
  • We use investment to retain the mould of the wax pattern in making dental metal castings. A fin on the metal casting is occasionally formed due to several factors. The factors making the fin are improper burn out time and temperature, improper W/P ratio of investment and lining of asbestos in casting ring. The purpose of this study is to investigate the effect of W/P ratio of investment on the fin formation. Except the W/P ratio of investment which used to invest the wax pattern, the study was done under same condition; burn out time and temperature, W/P ratio of refractory cast(W/P=0.12) and asbestos lining in casting ring. The obtained result is that the fin is more likely to be formed on the casting which invested with higher W/P ratio of investment to that of refractory cast.

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