• Bulletin of the Korean Chemical Society
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• 제27권11호
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• pp.1757-1762
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• 2006

A solvent sublation using salphen as a ligand was studied and applied for the determination of trace Ni(II), Co(II) and Cu(II) in water samples. The fundamental study was investigated by a solvent extraction process because the solvent sublation was done by extracting the floated analytes into an organic solvent from the aqueous solution. The salphen complexes of Ni(II), Co(II) and Cu(II) ions were formed in an alkaline solution of more than pH 8 and then they were extracted into m-xylene. It was known that the each metallic ion formed 1 : 1 complex with the salphen and the logarithmic values of extraction constants for the complexes were 3.3 5.1 as an average value. Based on the preliminary study, the procedure was fixed for the separation and concentration of the analytes in samples. Various conditions such as the pH of solutions, the influence of $NaClO_4$, the bubbling rate and time of $N_2$ gas, and the type of organic solvent were optimized. The metal-salphen complexes could be extracted into m-xylene from the solution of more than pH 8, but the pH could be shifted to acidic solution of pH 6 by the addition of $NaClO_4$. In addition, the solvent sublation efficiency of the analytes was increased by adding $NaClO_4$. The recovery of 97-115% was obtained in the spiked samples in which given amounts of 0.3 mg/L Ni(II), 0.8 mg/L Co(II) and 0.04 mg/L Cu(II) were added.

• Applied Biological Chemistry
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• 제7권
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• pp.105-117
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• 1966

acaricide로 알려진 phthalimidomethyl O,O-dimethyl phosphorodithioat (Imidan)을 수도(水稻)에 살포(撒布)했을 때 Imidan과 그 대사물질(代謝物質)이 식물(植物)의 생육(生育)에 미치는 영향(影響)을 연구(硏究)하기 위하여 본(本) 실험(實驗)을 하였으며 이의 결과(結果)를 요약(要約)해 보면 다음과 같다. (1) Imian의 대사물질(代謝物質)로 예상(豫想)되는 다음의 8가지 화합물(化合物)을 합성(合成) 또는 정제(精製)하여 공시약제(供試藥劑)로 사용(使用)하였다. (a) N-Hydroxy methyl phthalimide (b) Phalimide (c) Phthalamdic acid (d) Phthalic acid (e) Anthranilic acid (f) p-amino benzoic acid (g) p-hydroxu benzoic acid (h) Benzoic acid (2) 상기(上記) 물질중(物質中)에서 (a),(c),(d),(e)와 Imidan의 각(各) 10 ppm과 20 ppm 의 Buffer Solution 을 만들어 밀 종자(種子)를 가지고 coleoptile straight growth test를 해 본 결과(結果) Imidan 은 10 ppm 과 20 ppm에서 모두 control 보다 생장(生長)의 촉진효과(促進?果)를 보였으며 기중(其中) phthalamidic acid 10 ppm 이 가장 좋은 성적(成績)을 보였다. 이것으로 보아 Imidan 자체(自體)는 생장(生長) 억제(抑制)의 효과(?果)를f 보이나 이것이 일단(一但) 생체내(生體內)에서 가수분해(加水分解)를 비롯한 각종(各種) 대사작용(代謝作用)을 받으면 그 대사산물(代謝産物)이 식물생장(植物生長)을 촉진(促進)하는 효과(?果)를 보이는 것 같다. (Table 1, Fig. 1 참조(參照)) (3) xylene을 용매(溶媒)로 하여 Imidan 유제(乳劑)를 만들고 이것을 희석(稀釋)하여 20 ppm, 100 ppm 및 200 ppm 의 각(各) 농도(濃度) 유화액(乳化液)을 조제(調製)한 후 이것을 배지(培地)로 하여 수도종자(水稻種子)를 발아(發芽)시킨 후 12 일(日)에 shoot와 root의 길이를 측정(測定)하였다. 이의 결과(結果)를 보면 root는 Imidan 20 ppm에서, shoot 는 Imidan 100 ppm에서 모두 xylene만의 유제구(乳劑區)인 control 보다 좋은 효과(?果)를 보였으며 여기에서 흥미(興味)있는 것은 용매(溶媒)로 사용(使用)된 xylene은 수도종자(水稻種子) 뿌리의 발육(發育)에 심(甚)한 억제효과(抑制效果)를 보이는 것 같다. (Table 2, Table 5 참조(參照)) (4) 벼를 pot에 심고 2회(回)에 걸쳐 control, Imidan, N-hydroxy methyl phthalimide, anthranilic acid 및 phthalimide의 10, 25, 50, 100 ppm 농도(濃度)의 각(各) 유제(乳劑)를 살포하고 일정기간후(一定期間後) 생육상(生育相)을 조사(調査)하였더니 Imidan 구(區)와 N-hydroxy methyl phthalimide 구(區)가 control 보다 좋은 성적(成績)을 보였다. (5) Imidan 250 ppm 유제(乳劑)를 수도엽면(水稻葉面)에 살포(撒布)하고 3 일(日), 5 일(日), 7 일(日) 및 14일후(日後)에 일정량(一定量)의 엽경(葉莖)을 채취(採取)하여 acetone으로 추출(抽出)k고 acetonitrile을 가지고 prechromatographic piriication 을 거쳐 paper chromatography에 의(依)하여 다음과 같은 대사물질(代謝物質)을 검출(檢出)하였다. Imidan $(Rf:\;0.97{\sim}0.98)$, N-hydroxy methyl phthalimide (Rf: 0.87), phthalimide $(Rf:\;0.86{\sim}0.87)$, phthalamidic acid $(Rf:\;0.13{\sim}0.14)$, phthalic acid $(Rf:\;0.02{\sim}0.03)$, benzoic acid $(Rf:\;0.42{\sim}0.43)$ 및 p-amino benzoic acid 또는 p-hydroxy benzoic acid $(Rf:\;0.08{\sim}0.09)$와 Rf=0.73, 0.59, 0.33, 0.23, 0.07의 미지물질(未知物質)을 검출(檢出)하였다. 또한 3일(日), 5일(日) 등(等) 초기(初期)에서는 미분해(未分解)의 Imidan과 최초(最初)의 가수분해(加水分解) 산물(産物)인 N-hydroxy methyl phthalimide등(等)이 비교적(比較的) 다량(多量)으로 검출(檢出)되었으나 7일(日), 14일(日) 등(等) 후기(後期)에는 생체내(生體內)에서 더 많은 분해(分解)를 받아 상기(上記) 이성분(二成分)은 양(量)이 감소(減少)되고 phthalic acid, phthalamidic acid benzoic acid 및 p-hydroxy benzoic acid 또는 p-amino benzoic acid등(等)의 양(量)이 증가(增加)되는 것을 볼 수있었으며 도체상(稻體上)에 살포(撒布)된 Imidan 은 체내(體內)에 흡수(吸收)되어 14일(日)이 경과(經過)되면 대부분(大部分)이 분해(分解)를 받는 것으로 보여진다. 이상(以上)의 결과(結果)로 보아 Imidan은 자체(自體)로서는 식물생장(植物生長) 촉진작용(促進作用)이 없으나 식물체내(植物體內)에서 여러 가지 대사작용(代謝作用)(enzyme의 작용(作用))을 맡아서 각종(各種) phthaloyl 영향(影響)을 주는 것으로 생각(生覺)된다.

• 분석과학
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• 제20권6호
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• pp.474-482
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• 2007

보육시설은 미취학전 아이들에게 중요한 실내 환경이며 하루 중 가장 많은 시간을 보내는 영유아들에 잠재적인 유해한 건강영향을 줄 수 있다. 따라서 본 연구는 2006년 2월에서 12월에 걸쳐 서울에 위치한 보육시설 29개 시설을 선정하여 실태조사를 하였다. 측정물질은 휘발성유기화합물 중 7개의 물질(벤젠, 톨루엔, 에틸벤젠, m, p-자일렌, 스틸렌, o-자일렌 및 TVOC)을 선정하였다. 보육시설에서의 TVOC, 톨루엔, m, p-자일렌, 에틸벤젠, 벤젠 그리고 스틸렌의 평균농도는 $318.7{\mu}g/m^3$, $51.6{\mu}g/m^3$, $11.7{\mu}g/m^3$, $6.5{\mu}g/m^3$, $4.2{\mu}g/m^3$, $3.6{\mu}g/m^3$이고, 정성분석된 TVOC 중 톨루엔은 17.6%로 가장 많은 비중을 차지하였다. TVOC와 톨루엔의 실내/실외 농도비는 각각 2.0, 1.6으로 나타났다. TVOCs의 계절에 따른 오염물질의 특성결과는 여름이 $433.9{\mu}g/m^3$로 가장 높게 나타났으며, 다른 계절은 겨울 280.5, 봄 298.3 및 가을 $264.6{\mu}g/m^3$로 비슷한 경향으로 나타났다.

• 한국대기환경학회지
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• 제28권4호
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• pp.435-445
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• 2012

The aim of this study is to understand the characteristics of volatile oranic compounds (VOCs) and provide information about the present Indoor Air Quality (IAQ) at residential apartments. All samples were collected in 60-min interval using the tenax absorption trap between May, 2011 and February, 2012. And the effects of environmental factors such as temperature, humidity and construction characteristics were analyzed in relation to the measured concentrations. The results of this study showed that the mean concentration of VOCs was lower than the Ministry of the Environment's standards for maintenance of indoor air quality. The correlation analysis showed that ethylbenzene and xylene (r=0.916, p<0.01), toluene and ehtylbenzene (r=0.810, p<0.01), toluene and xylene (r=0.803, p<0.01) and toluene and styrene (r=0.588, p<0.01) were significant. The result of regression analysis was found that the influenece factors associated with the concentration of VOCs were the age and location of the apartment, remodeling, the temperature and the season.

• 공업화학
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• 제5권1호
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• pp.90-98
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• 1994

구연산-초산-유산계에서 구연산의 반응추출에 영향을 미치는 여러 인자를 규명하기 위하여 추출제로 2급과 3급아민 및 용매화추출제를, 용매로 n-butylacetate, MIBK, kerosine 및 xylene 등을, modifier로서 tributyl-phosphate(TBP)와 isodecanol이 이용되었다. 그 외에 수용액상의 pH와, 온도의 영향을 연구하였고 평형상수도 얻었다. NaOH, $Na_2CO_3$ 및 $K_2HPO_4$ 알칼리 수용액에 의한 재추출 실험도 하였다. 실험결과 구연산의 추출에서 2급아민인 di-isotridecylamine(DITDA)이 추출도와 선택성에서 가장 좋았고 용매로서는 n-butylacetate가, modifier로서는 TBP가 우수하였다. 이외에도 수용액의 pH와 추출계의 온도가 낮을수록 추출도가 높았다. 재추출도는 stripping상의 염기도와 온도가 낮을수록 높아졌고 알카리 농도가 커질수록 높아졌다.

• 한국생물공학회:학술대회논문집
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• 한국생물공학회 2002년도 생물공학의 동향 (X)
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• pp.180-183
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• 2002

Pseudomonns putida BCNU171 had the tolerant ability to several other organic solvents headed by toluene and xylene. Several mutants were made by mating of BCNUl71, pJFF350 to clarify the structure tolerance gene related. From this mutants the 7 of mutants related with toluene sensitive mutants were selected. pBCNUT-2, pBCNUT-4, pBCNUT-9 was transformed, and from this separated plasmid DNA sequences the gene having high homology was searched. In the case of toluene sensitive mutant it was todX gene (pBCNU4) related with cell membrane, ttgE gene (pBCNU2, pBCNU9) and ttgF gene (pBCNU2, pBCNU9).

• 한국산업보건학회지
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• 제11권1호
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• pp.70-77
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• 2001

This study was conducted to identify the current status of occupational safety and health by checklist and to evaluate the airborne exposure to chemicals and to provide the appropriate recommendation for safety and health of laundries. A total of 20 laundries located in tile Gyungi district area were surveyed from July 20 to September 15, 2000. The prevalence of laundries having a stove and gas range were found to be 25 % and 55 %, respectively. Smoking is not allowed in 60 % of the laundries. Only 10 % of dry-cleaners were isolated. Ventilation systems in laundries had not been annually inspected. Most of the workers didn't put on respirators, MSDS were not available, and storage bottles did not contain warning labels. The bulk samples of dry cleaning agent include many chemicals that are not controlled by the MOL in Korea. The detected airborne organic solvents in the laundries were benzene, toluene, p-xylene, m-xylene, o-xylene, perchloroethylene, and 2-butoxy ethanol. The airborne concentrations of organic solvents were much less than the occupational exposure limits proposed by the Ministry of Labor(MOL) in Korea. But the concentrations of benzene exceeded the TLV of ACGIH. This study showed that the current status of occupational safety and health was not appropriate for workers in laundries. It is recommended that laundry workers should be educated for the treatment and storage of hazardous organic solvents to improve the occupational safety and health of the working environment as well as MSDS usage. Also, extended research and survey for the organic solvents that are not controlled by the MOL has to be conducted.

• 한국환경과학회지
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• 제17권12호
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• pp.1381-1390
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• 2008

Emission characteristics of volatile organic compounds (VOCs) were investigated in the flue gas emitted from wood drying process for plywood manufacturing. The moisture content of raw timber was average 48%, and its density was $831.55kg/m^3$. But the moisture content of dried wood is needed less than around 10%, thus the moisture contents of flue gas should be remarkably high(about 18.2 V/V%). Therefore, the vapor in flue gas is equivalent to 320 ton-vapor/day when 1100 ton-wood/day is treated in the wood drying process. The temperature of flue gas ranges from $140^{\circ}C\;to\;150^{\circ}C$ in each dryer stack with exception of the input site of wood(about $110^{\circ}C$). The velocity of flue gas in each stack ranges from 1.7 to 9.7m/sec. In order to assess the concentrations and attribution rate of odorous compounds, it was analyzed about 40 VOCs in the flue gases. It was found that the major odorous compounds were 8 compounds, and the concentrations of major VOCs(ppm) were as follows; benzene: $0.054{\sim}0.052$, toluene: $1.011{\sim}2.547$, ethylbenzene: $0.472{\sim}2.023$, m,p-xylene: $0.504{\sim}3.245$, styrene: $0.015{\sim}0.148$, o-xylene : $0.271{\sim}1.097$, ethanol: $11.2{\sim}32.5$, ${\alpha}$-pinene: $0.908{\sim}10.578$, ${\beta}$-pinene: $0.982{\sim}14.278$. The attribution rate of terpenes (${\alpha}$-pinene, ${\beta}$-pinene) was about 60.56%, and that of aromatics and alcohols was about 22.77%, and 16.67%, respectively. It is suggested that the adequate control device should be used to control both the water soluble and non-soluble compounds because both compounds were mixed in flue gas.

• 한국산업보건학회지
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• 제20권3호
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• pp.192-202
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• 2010

This study aimed to suggest the severity of indoor air pollutants in screen gold arenas which were not sufficiently investigated in Korea up to now and to help users to enjoy golf in more pleasant indoor environment. The indoor environment survey was conducted with 21 screen gold arenas in Seoul from Oct. 28, 2008 to March 13, 2009. Indoor air quality was measured and analyzed in accordance with the Air Pollution Process Test Method specified bu NIOSH(2005). The screen golf arenas are mostly in the underground floors in this study, 4 on the ground floors(19.0%) and 17 in the underground floors(81.0%). In the air in screen golf arenas, the geometric mean of benzene, toluene, ethylbenzene and xylene were 2.92 ${\mu}g/m^3$, 70.34 ${\mu}g/m^3$, 14.00${\mu}g/m^3$ and 31.43 ${\mu}g/m^3$, respectively, which exceeded the exposure limites. Each arena exceeded the exposure limit for one pollutant each. However, styrene didn't exceed the limit as 8.09 ${\mu}g/m^3$. Furthermore, the geometric mean of formaldehyde was 63.11${\mu}g/m^3$ and 7 arenas exceeded the limit. The geometric mean of volatile organic compounds(VOCs) was 428.41${\mu}g/m^3$ and 10 arenas exceeded the limit. For the density distribution of pollutants by location, benzene, toluene, ethylbenzene, xylene, styrene and formaldehyde showed higher density distribution in underground spaces, for which the statistically significant difference was not found. However, PM10 showed the statistically significant difference (p<0.05). In accordance with the analysis on the correlation between the density of pollutants in the screen golf arenas, Pearson correlation coefficient between ethylbenzene and styrene was 0.980, very significant correlation(p<0.01). The correlation coefficients between the density of toluene, ethylbenzene, xylene and styrene and that of VOCs were 0.543, 0.434, 0.451 and 0.459, respectively, which demonstrated the statistically significant difference (p<0.05).

• Korean Chemical Engineering Research
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• 제53권6호
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• pp.755-761
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• 2015

광촉매의 VOC 제거 특성 평가에 관한 최근의 연구는 온도 변화가 거의 없는 상태에서 실시되었다. 온도 변화를 적게하기 위해 광량이 높은 UVLED를 챔버 위부에 배치하게 되면 광촉매와의 거리가 멀어져 그만큼 효율이 감소할 수 밖에 없으며 광촉매의 효율 향상을 위해서는 광원과 광촉매의 거리를 가까이 해야 할 필요가 있다. 본 연구에서는 UVLED 광원과 광촉매와의 거리를 가까이 두어 온도가 변하는 VOC 제거 시스템을 제작하였다. 광촉매로는 자외선 광원에서 반응하는 상용 $TiO_2$와 vanadium 이온을 도핑시킨 $TiO_2$를 사용하였으며 제작된 챔버를 이용하여 광촉매 효율을 평가하였다. VOC 제거 평가 시 테스트 전후 온도는 약 $20^{\circ}C$ 상승하여 UVLED 광원에 의해 변화된 온도로 VOC의 농도를 보정하여 온도에 따른 VOC 제거 효율 변화를 확인하였다. 보정 전후의 제거 효율을 비교하면 43~46%의 차이를 보였다. 챔버 내 온도 상승이 p-xylene의 농도 변화에 큰 영향을 주며 이를 보정하여 광촉매의 VOC 제거 효율을 평가할 필요가 있음을 확인할 수 있었다.