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Influence of N-P-K Nutrient Levels on Ozone Susceptibility of Tomato Plants (N-P-K 양분 수준이 토마토의 오존 감수성에 미치는 영향)

  • Ahn, Joo-Won;Ku, Ja-Hyeong
    • Korean Journal of Environmental Agriculture
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    • v.17 no.4
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    • pp.352-357
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    • 1998
  • This experiment was conducted to find out the effects of major nutrient levels(N, P, K) on ozone susceptibility of tomato plants(Lycopersicon esculentum Mill, cv. Pink Glory). Plants were grown in water culture system. A half-strength of Hoagland's nutrient solution was considered as a standard formulation($N_{100}$ $P_{100}$ $K_{100}$). The levels of major nutrients were adjusted through addition or removal of several fertilizer salts from the standard solution. Top growth was significantly decreased at the low nitrogen level or phosphorus removal condition. P- and K-contents of leaves were greatly decreased by removal of salts containing P and K from the nutrient solution. The rate of ozone injury was significantly increased when potassium was removed. However, the influence of nitrogen and phosphorus levels or high potassium level on injury occurrence did not show statistical significance compared to the standard solution. Ozone exposure resulted in reduction of chlorophyll, and increase of ethylene production, electrolyte leakage and malondialdehyde(MDA) contents. These changes were much more enhanced in plants grown at the potassium removal solution. Whereas the activity of superoxide dismutase(SOD) was low at the potassium removal treatment and this tendency remained after ozone exposure. These results indicated that potassium nutrient level in tomato plants is closely associated with the susceptibility to ozone injury.

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Hydrolysis Mechanism of N-(benzenesulfonyl)-C-(N-methylanilino)imidoyl Chloride Derivatives (N-(benzenesulfonyl)-C-(N-methylanilino)imidoyl Chloride 유도체의 가수분해 반응 메카니즘)

  • Kwon, Ki-Sung;Song, Yun-Yi
    • Journal of the Korean Chemical Society
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    • v.39 no.8
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    • pp.650-656
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    • 1995
  • Rate Constants of hydrolysis of N-(benzenesulfonyl)-C-(N-methylanilino)imidoyl chlorides were determined by UV spectrophotometry in 50% (v/v) aqueous methanol at 25$^{\circ}C.$ On the basis of rate equation, substituent effect, solvent effect, salt effect, thermodynamic parameters and hydrolysis product analysis, it may be concluded that the hydrolysis of N-(benzenesulfonyl)-C-(N-methylanilino)imidoyl chlorides proceed through $S_N1$ mechanism via azocarbonium ion intermediate below pH 9.0, while aebove pH 10.0 the hydrolysis proceeds through nucleophilic addition-elimination ($Ad_{N-E}$) mechanism.

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THE ZAGREB INDICES OF BIPARTITE GRAPHS WITH MORE EDGES

  • XU, KEXIANG;TANG, KECHAO;LIU, HONGSHUANG;WANG, JINLAN
    • Journal of applied mathematics & informatics
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    • v.33 no.3_4
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    • pp.365-377
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    • 2015
  • For a (molecular) graph, the first and second Zagreb indices (M1 and M2) are two well-known topological indices, first introduced in 1972 by Gutman and Trinajstić. The first Zagreb index M1 is equal to the sum of the squares of the degrees of the vertices, and the second Zagreb index M2 is equal to the sum of the products of the degrees of pairs of adjacent vertices. Let $K_{n_1,n_2}^{P}$ with n1 $\leq$ n2, n1 + n2 = n and p < n1 be the set of bipartite graphs obtained by deleting p edges from complete bipartite graph Kn1,n2. In this paper, we determine sharp upper and lower bounds on Zagreb indices of graphs from $K_{n_1,n_2}^{P}$ and characterize the corresponding extremal graphs at which the upper and lower bounds on Zagreb indices are attained. As a corollary, we determine the extremal graph from $K_{n_1,n_2}^{P}$ with respect to Zagreb coindices. Moreover a problem has been proposed on the first and second Zagreb indices.

Model-based predictions for nuclear excitation functions of neutron-induced reactions on 64,66-68Zn targets

  • Yigit, M.;Kara, A.
    • Nuclear Engineering and Technology
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    • v.49 no.5
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    • pp.996-1005
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    • 2017
  • In this paper, nuclear data for cross sections of the $^{64}Zn(n,2n)^{63}Zn$, $^{64}Zn(n,3n)^{62}Zn$, $^{64}Zn(n,p)^{64}Cu$, $^{66}Zn(n,2n)^{65}Zn$, $^{66}Zn(n,p)^{66}Cu$, $^{67}Zn(n,p)^{67}Cu$, $^{68}Zn(n,p)^{68}Cu$, and $^{68}Zn(n,{\alpha})^{65}Ni$ reactions were studied for neutron energies up to 40 MeV. In the nuclear model calculations, TALYS 1.6, ALICE/ASH, and EMPIRE 3.2 codes were used. Furthermore, the nuclear data for the (n,2n) and (n,p) reaction channels were also calculated using various cross-section systematics at energies around 14-15 MeV. The code calculations were analyzed and obtained using the different level densities in the exciton model and the geometry-dependent hybrid model. The results obtained from the excitation function calculations are discussed and compared with literature experimental data, ENDF/B-VII.1, and the TENDL-2015 evaluated data.

Infinite Families of Congruences for Partition Functions ${\bar{\mathfrak{EO}}}$(n) and ${\mathfrak{EO}}_e$(n)

  • Riyajur Rahman;Nipen Saikia
    • Kyungpook Mathematical Journal
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    • v.63 no.2
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    • pp.155-166
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    • 2023
  • In 2018, Andrews introduced the partition functions ${\mathfrak{EO}}$(n) and ${\bar{\mathfrak{EO}}}$(n). The first of these denotes the number of partitions of n in which every even part is less than each odd part, and the second counts the number of partitions enumerated by the first in which only the largest even part appears an odd number of times. In 2021, Pore and Fathima introduced a new partition function ${\mathfrak{EO}}_e$(n) which counts the number of partitions of n which are enumerated by ${\bar{\mathfrak{EO}}}$(n) together with the partitions enumerated by ${\bar{\mathfrak{EO}}}$(n) where all parts are odd and the number of parts is even. They also proved some particular congruences for ${\bar{\mathfrak{EO}}}$(n) and ${\mathfrak{EO}}_e$(n). In this paper, we establish infinitely many families of congruences modulo 2, 4, 5 and 8 for ${\bar{\mathfrak{EO}}}$(n) and modulo 4 for ${\mathfrak{EO}}_e$(n). For example, if p ≥ 5 is a prime with Legendre symbol $({\frac{-3}{p}})=-1$, then for all integers n ≥ 0 and α ≥ 0, we have ${\bar{\mathfrak{EO}}}(8{\cdot}p^{2{\alpha}+1}(pn+j)+{\frac{19{\cdot}p^{2{\alpha}+2}-1}{3}}){\equiv}0$ (mod 8); 1 ≤ j ≤ (p - 1).

The Study of anti-cancer mechanism with Cobrotoxin on Human prostatic cancer cell line(PC-3) (전립선 암세포에 대한 Cobrotoxin의 항암(抗癌) 기전(機轉) 연구(硏究))

  • Chae, Sang-jin;Song, Ho-seup
    • Journal of Acupuncture Research
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    • v.22 no.3
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    • pp.169-183
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    • 2005
  • Objective : The purpose of this study was to investigate the anti-caner effect of cobrotoxin on the prostatic cancer cell line (PC-3).The goal of study is to ascertain whether cobrotoxin inhibits tile cell growth and cell cycle of PC-3, or the expression of relative genes and whether the regression of PC-3 cell growth is due to cell death or the expression of gene related to apoptosis. Methods : After the treatment of Pc-3 cells with cobrotoxin, we performed 형광현미경, MTT assay, Western blotting, Flow cytometry, PAGE electrophoresis and Surface plasmon resonance analysis to identify the cell viability, cell death, apoptosis, the changes of cell cycle and the related protein, Adk, MAP kinase. Results : 1. Compared with normal cell, the inhibition of cell growth reduced in proportion with the dose of cobrotoxin(0-16nM) in PC-3. 2. Cell viabilities of 0.1, 1, 4nM cobrotoxin treatment were decreased and those of 8, 16nM were decreased significantly. 3. S phase of cell cycle was decreased at the group of 1, 2, 4, 8, 16nM cobrotoxin, but M phase was increased at 0.1, 1, 2, 4, 8, 16nM cobrotoxin. 4. Cox-2 expression after cobrotoxin was peaked at 12hours and was decreased significantly after 6, 12, 24 hours. 5. The expression of Cdk4 was decreased dose-dependently at 1, 2, 4, 8nM cobrotoxin and was decreased siginificantly at 4, 8nM Cyclin D1 was decreased at 1, 2, 4, 8nM and Cycline E was not changed. Cycline B was decreased at 1, 2, 4, 8nM dose-dependently and was decreased siginificanlty at 2, 4, 8nM. 6. The expression of Akt was decreased at 1, 2, 4, 8nM dose-dependently and was decreased significantly at 2, 4, 8nM. 7. ERK was increased at 1, 2nM and decreased at 4, 8nM, p-ERK was increased at 1, 2, 4 nM, but decreased at 8nM. JNK and p-JNK were increased at 1, 4, 8 nM. p38 was increased at 2nM p-p38 was increased at lnM but decreased significantly at 2, 4, 8nM. 8. The nucli of normal cells were stained round and homogenous in DAPI staining, but those of PC-3 were stained condense and splitted. Apoptosis was increased dose-dependently at 2, 4, 8, 16nM and increased significantly at 2, 4, 8, 16nM. 9. Bax wasn`t changed at 1, 2, 4, 8nM and Bcl-2 was decreased significantly at 1, 2, 4, 8nM. Caspase 3 and 9 weren`t changed at 1, 2, 4nM but were decreased significantly at 8nM. Conclusions : These results indicate that cobrotoxin inhibits the growth of prostate Cancer cells, has anti-cancer effects by inducing apoptosis.

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Convenient Synthesis of N-Sulfinylamines Catalytic Effects of Tertiary Amines

  • Park, Koon-Ha;Park, Myeong-Soon
    • Bulletin of the Korean Chemical Society
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    • v.11 no.6
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    • pp.494-496
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    • 1990
  • Catalytic effects of tertiary amines on N-sulfinylation of p-toluenesulfonamide, p-toluidine, and p-toluamide have been investigated by proton NMR studies. Though the catalytic effects were dependent on the substrates, 4-dimethylaminopyridine, pyridine and triethylamine exerted stronger catalytic effects than imidazole and N,N-dimethylaniline. Among the substrates employed, p-toluenesulfonamide turned out to be catalyzed greater than p-toluidine and p-toluamide.

Novel Peracetylated N-Lactosyl-1,2,4-Thiadiazolidin-3-one Hydrochlorides: Synthesis and Antimicrobial Studies (Peracetylated N-Lactosyl-1,2,4-Thiadiazolidin-3-one Hydrochlorides: 합성과 항균 연구)

  • Dandale, Anvita S.;Mangte, Dattatraya V.;Deshmukh, Shirish P.
    • Journal of the Korean Chemical Society
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    • v.54 no.3
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    • pp.287-290
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    • 2010
  • In the present work we described oxidative cyclisation of peracetylated lactosyl carbamides with N-phenyl-S-chloro isothiocarbamoyl chloride and structural elucidation of novel peracetylated N-Lactosyl-1,2,4-Thiadiazolidin-3-one hydrochlorides. Antimicrobial activities of the title compounds were determined against bacteria S. aureus, E. coli, P. Vulgaris, P. Aeruginosa and fungi A. Niger, Penicillium.

The Effect of Salt and pH on the Phase Transition Behaviors of pH and Temperature-Responsive Poly(N,N-diethylacrylamide-co-methylacrylic acid)

  • Liu, Tonghuan;Fang, Jian;Zhang, Yaping;Zeng, Zhengzhi
    • Macromolecular Research
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    • v.16 no.8
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    • pp.670-675
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    • 2008
  • A series of pH and temperature-responsive (N,N-diethylacrylamide-co-methylacrylic acid) copolymers were synthesized by radical copolymerization and characterized by elemental analysis, Fourier-transform infrared (FT-IR), nuclear magnetic resonance (NMR) $^1H$, $^{13}C$ and LLS. The effects of salt and pH on the phase transition behaviors of the copolymers were investigated by uv. With increasing NaCl concentration, significant salt effects on their phase transition behaviors were observed. UV spectroscopic studies showed that the phase transition became faster with increasing NaCl concentration. In addition, the phase transition behaviors of copolymers were sensitive to pH. The pH and temperature sensitivity of these copolymers would make an interesting drug delivery system.

Generalized Extending Method for q-ary LCZ Sequence Sets (q진 LCZ 수열군의 일반화된 확장 생성 방법)

  • Chung, Jung-Soo;Kim, Young-Sik;Jang, Ji-Woong;No, Jong-Seon;Chung, Ha-Bong
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.33 no.11C
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    • pp.874-879
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    • 2008
  • In this paper, a new extending method of q-ary low correlation zone(LCZ) sequence sets is proposed, which is a generalization of binary LCZ sequence set by Kim, Jang, No, and Chung. Using this method, q-ary LCZ sequence set with parameters (N,M,L,${\epsilon}$) is extended as a q-ary LCZ sequence set with parameters (pN,pM,p[(L+1)/p]-1,p${\epsilon}$), where p is prime and p|q.