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Convenient Synthesis of N-Sulfinylamines Catalytic Effects of Tertiary Amines

  • Park, Koon-Ha (Department of Chemistry, College of Arts and Science, Chung Nam National University) ;
  • Park, Myeong-Soon (Department of Chemistry, College of Arts and Science, Chung Nam National University)
  • Published : 1990.12.20

Abstract

Catalytic effects of tertiary amines on N-sulfinylation of p-toluenesulfonamide, p-toluidine, and p-toluamide have been investigated by proton NMR studies. Though the catalytic effects were dependent on the substrates, 4-dimethylaminopyridine, pyridine and triethylamine exerted stronger catalytic effects than imidazole and N,N-dimethylaniline. Among the substrates employed, p-toluenesulfonamide turned out to be catalyzed greater than p-toluidine and p-toluamide.

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  1. ChemInform Abstract: Convenient Synthesis of N-Sulfinylamines, Catalytic Effects of Tertiary Amines. vol.22, pp.28, 1990, https://doi.org/10.1002/chin.199128047