• 에너지공학
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• 제8권4호
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• pp.560-566
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• 1999

가압 조건하에서의 석탄가스화 특성을 규명하기위해 , 온도 압력 , 산소/석탄비, 수증기/석탄비 등을 변화시켜가며 로토탄(sub A)에 대하여 PDTF(Pressuized drop tube furnace)실험을 수행하였다. 실험결과, 상압 조건에서보다 가압조건에서의 가스화가 탄소전환율과 냉가스효율의 측면에서 더 유리한 것으로 측정되었다. 최대의 냉가스효율을 보이는 산소/석탄비의 증가가 냉가스효율의 증가를 가져왔다. 압력이 증가할수록 열분해에 의한 탄소전환의 비중은 감소하고 대신 기고반응에 의한 탄소전환의 비중이 증가하였다.

• 한국전기전자재료학회논문지
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• 제22권2호
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• pp.107-113
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• 2009

In order to improve air stability, we proposed a new active layer of an organic TFT by synthesizing P3HT/POSS conjugated polymer. P3HT/POSS OTFTs with the various P3HT/POSS volume ratios were fabricated and characterized. With the P3HT/POSS volume ratio of 1:1, we achieved the field-effect mobilities of ${\sim}1.19{\times}10^{-3}\;cm^2/v{\cdot}sec$ in the saturation region and the current on/off ratio of ${\sim}2.51{\times}10^2$. The resulting current on-off ratio was much higher than that of the P3HT-based OTFTs and resulted from the dramatic decrease of the off-current. Since the off-current can be reduced by preventing oxygen in atmosphere from doping the P3HT/POSS active layers, this new active layer shows its ability to avoid oxygen doping in atmosphere. Therefore, the improvement of the air stability can be achieved by employing the P3HT/POSS active layers.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2010년도 제39회 하계학술대회 초록집
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• pp.168-168
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• 2010

Transparent conduction oxides (TCOs) films is extensively reported for optoelectronic devices application such as touch panels, solar cells, liquid crystal displays (LCDs), and organic light emitting diodes(OLEDs). Among the many TCO film, indium tin oxide(ITO) is in great demand due to the growth of flat panel display industry. However, indium is not only high cost but also its deposits dwindling. Therefore, many studies are being done on the transparent conductive oxides(TCOs). We fabricated a target of IZTO(In2O3:ZnO:SnO2=70:15:15 wt.%) reduced indium. Then, IZTO thin films were deposited on glass substrates by pulsed DC magnetron sputtering with various oxygen flow ratio. The substrate temperature was fixed at the room temperature. We investigated the electrical, optical, structural properties of IZTO thin films. The electrical properties of IZTO thin films were dependent on the oxygen partial pressure. As a result, the most excellent properties of IZTO thin films were obtained at the 3% of oxygen flow rate with the low resistivity of $7.236{\times}10^{-4}{\Omega}cm$. And also the optical properties of IZTO thin films were shown the good transmittance over 80%. These IZTO thin films were used to fabricated organic light emitting diodes(OLEDs) as anode and the device performances studied. The OLED with an IZTO anode deposited at optimized deposition condition showed good brightness properties. Therefore, IZTO has utility value of TCO electrode although it reduced indium and we expect it is possible for the IZTO to apply to flexible display due to the low processing temperature.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2011년도 제40회 동계학술대회 초록집
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• pp.87-87
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• 2011

Oxide semiconductors are attractive materials for thin-film electronics and optoelectronics due to compatibility with synthesis on large-area, glass and flexible substrate. However, development of thin-film electronics has been hampered by the limited number of semiconducting oxides that are p-type. We report on the effect of the oxygen partial pressure ratio in the gas mixture on the electrical and optical properties of spinel Mg:$ZnCo_2O_4$ thin films deposited at room temperature using RF sputtering, that exhibit p-type conduction. The thin-films are deposited at room temperature in a background of oxygen using a polycrystalline Mg:$ZnCo_2O_4$ ablation target. The p-type conduction is confirmed by positive Seebeck coefficient and positive Hall coefficient. The electrical resistivity and carrier concentration in on dependent Mg:$ZnCo_2O_4$ thin films were found to be dependent on the oxygen partial pressure ratio. As a result, it is revealed that the Mg:$ZnCo_2O_4$ thin-films were greatly influenced on the electrical and optical properties by the oxygen partial pressure condition. The visible region of the spectrum of 36~85%, and hole mobility of 1.1~3.7 $cm^2$/Vs, were obtained.

• 한국수소및신에너지학회논문집
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• 제18권1호
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• pp.46-51
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• 2007

LSM powder material for an oxygen-electrode(anode) of High Temperature Steam Electrolysis (RISE) was synthesized by a Modified-Glycine nitrate process(GNP). Amount of nitric acid and its concentration was varied to find out an appropriate composition for the oxygen-electrode(anode). In order to optimize the amount of Glycine used as an oxidant of self-combustion process, the ratio of Glycine to Anion was varied. $La_{0.8}Sr_{0.2}MnO_3$, $La_{0.5}Sr_{0.5}MnO_3$, and $La_{0.2}Sr_{0.8}MnO_3$ were synthesized in this study. Those LSM were dried for overnight to remove moisture from the material at $110^{\circ}C$ and were calcined 2 hours at $650^{\circ}C$ and were sintered in a furnace for 5 hours at $1400^{\circ}C$. Their structures, surface morphologies, surface areas, and weight changes were investigated with XRD, SEM, BET, and TG/DTA. The best perovskite phase for the oxygen-electrode of HTSE was obtained with $La_{0.8}Sr_{0.2}MnO_3$ formula in which 100 ml of 3M nitric acid was used in the preparation of its formula. The optimized ratio of Glycine to Anion was 2.

• 한국물환경학회지
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• 제20권3호
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• pp.197-205
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• 2004

Batch test methods have developed for a long time to measure kinetic and stoichiometric parameters which are required to perform steady state design and mathematical modelling of activated sludge processes. However, at various So/Xo ratios, abnormal behaviors of ordinary heterotrophic organism in batch tests have been reported in many researches. Thus, in this research, abnormal behaviors of heterotrophs in batch tests were investigated at various So/Xo conditions by measuring and interpreting oxygen utilization rate. As So/Xo ratio increased, the calculated values of maximum specific growth rates, ${\mu}_{H,max}$ and $K_{MP,max}$, increased. However, at a certain point of So/Xo (around 10mgCOD/mgMLAVSS), ${\mu}_{H,max}$ and $K_{MP,max}$ values started to decrease. According to this observation, three prominent behaviours of heterotrophs were identified at various So/Xo conditions. (1) At low So/Xo region (below 5 mgCOD/mgMLAVSS), the oxygen utilization rate of heterotrophs in batch tests were almost stable and consequently yielded lower maximum specific growth rate. (2) At high So/Xo region (up to 5~10 mgCOD/mgMLAVSS), oxygen utilization rate incresed sharply with time and indicated more upward curvature than the predicted OUR with conventional activated sludge model, which consists of single hetetrotrophs group. Thus, in this region, competition model of two organisms, fast-grower and slow-grower, seemed to be appropriate. (3) At extremely high So/Xo region (over 10mgCOD/mgMLAVSS), significant oxygen utilization rate was still observed even after depletion of readily biodegradable COD. This might be caused by retarded utilization of intermediates which were generated by self inhibition mechanism in the process of RBCOD uptake.

• 한국추진공학회지
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• 제22권1호
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• pp.28-35
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• 2018

전단 동축형 인젝터를 통해 분사된 기체메탄-기체산소 확산화염의 가연한계와 구조분석을 위해 인젝터 리세스와 추진제 공급유량에 따른 연소실험이 수행되었다. 연구 결과, 추진제 운동량 플럭스 비가 증가함에 따라 높은 산화제 레이놀즈 수 구간에서도 안정적인 부착화염이 관찰되었으며, 인젝터 리세스는 화염의 형태와 가연한계에 큰 영향을 미치지 않음을 확인하였다. 자발광 기법을 통해 가시화된 부착화염은 추진제 분사조건이 변함에도 불구하고 항상 일정한 지점에서 최대 OH 라디칼 방사강도를 나타내었으며, 그 강도는 리세스에 의해 심하게 감소함을 확인하였다.

• 한국물환경학회지
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• 제37권2호
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• pp.92-102
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• 2021

In this study, the distribution characteristics according to the type of BOD and the effect of nitrogenous oxygen demand (NOD) and algal oxygen demand on BOD in three streams (Bokhacheon, Byeongseongcheon, and Gulpocheon) were evaluated. Although the BOD and NOD concentrations demonstrated a difference in the three streams, the carbonaceous BOD(CBOD)/BOD ratio was 0.75 (p=0.053, one-way ANOVA), and there was no significant difference in the three streams (r2≥0.92, p<0.0001). The NOD concentration of the Bokhacheon with high NH3-N was 1.7±1.3 mg/L, which was the highest among the three streams and showed a significant correlation with BOD. Seasonal variations in NOD in the three streams did not show a significant correlation with changes in NH3-N concentration (r2<0.28, p≥0.1789), and there was no significant difference in NOD even though NH3-N concentration in Gulpocheon was about twice that of Byeongseongcheon (p=0.870, one way ANOVA). The particulate CBOD(PCBOD)/CBOD ratio of the three streams was 0.55~0.64, and about 60% of the biodegradable organic matter was present in the particulate form. When the Chl.a concentration in the stream was more than 7 ㎍/L, the PCBOD tended to increase with the Chl.a concentration (r2=0.61, p=0.003). In the three streams, particulate NOD accounted for 81% of NOD; however, despite the large variation in NH3-N concentration (0.075~3.182 mg/L), there was no significant difference in soluble NOD(SNOD) concentration that ranged from 0.1 to 0.3 mg/L. In this study, the low contribution rate of SNOD to NOD is considered as a result of the removal of nitrifying bacteria along with the particles during the filtration process.

• 대한기계학회논문집B
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• 제27권11호
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• pp.1548-1562
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• 2003

This paper is the first of several companion papers which compare the methods of Air-fuel ratio determination. There are many methods which calculate Air-Fuel ratio from exhaust emission. Most of them are based on the simple chemical equations, which use balance of atom, and the error of the calculation is negligible as far as the instrumentation accuracy is guaranteed. They assume homogeneous mixture and complete combustion to the extent of oxygen availability. Because of these simple assumptions, they cannot offer the information about the fuel distribution state and the malfunction of instrument. For these limitations, Eltinge offered new one based on stricter mathematical model. This result coincides with the others very well and gives more information about the mixture state and instrumentation. Consequently this might be a general solution for Air-fuel ratio determination and exhaust composition. The objects of the calculation, however, were not commercial fuels except gasoline and the compensation method of unburned hydrocarbon was not appropriate to recent analyzer. Moreover he did not consider the fuel which contains oxygen, such as methanol, ethanol and blend of gasoline-alcohol. In this paper, Eltinge chart is expanded to the arbitrary fuel composition as the reference exhaust compositions for the purpose of further discussions about Air-fuel ratio determination methods and the charts fur gasoline, diesel, methanol, M85, liquefied petroleum gas(LPG), natural gas(NG), propane, butane are illustrated.

• 한국양식학회지
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• 제20권1호
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• pp.31-40
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• 2007

가막만, 여자만과 사량도에서 피조개(Scapharca broughtonii) 치패의 살포시기와 양식장 환경에 따른 피조개의 성장과 생존율 감소 요인을 파악하였다. 피조개는 여자만과 가막만에서는 2004년 11월에 인공산 치패를 바닥식으로 살포하였으며, 사량도에서는 2005년 3월초에 중국산과 국내산 치패를 바닥식으로 살포하였다. 살포된 피조개의 치패는 2005년 3월부터 12월까지 매월 성장과 생존율을 측정하였으며, 양식장의 수질(수온, 염분, DO, 영양염, Chl. a)과 퇴적물(산소투과 깊이, 미세산소 분포, 강열감량과 COD) 환경을 조사하였다. 조사기간 동안 피조개의 누적 생존비는 가막만에서 가장 높았으며, 여자만에서는 대부분 폐사하였다. 피조개 개체의 성장은 여자만과 가막만에서 5월에 가장 빠른 것으로 나타났으며, 사량도에서는 국내산이 중국산보다 빠른 성장을 보였다. 여자만에서 피조개의 높은 폐사(>65%)는 하계의 수온 상승, 저염분 수괴의 유입과 퇴적물의 낮은 DO 농도가 영향을 미치는 것으로 나타났다. 계절에 따른 가막만과 사량도에서 피조개의 생존비는 영양염과 퇴적물의 COD 농도에 영향을 받는 것으로 나타났다. 피조개의 성장과 폐사는 양식장 환경과 살포시기에 따라 차이를 보였다.