• Title/Summary/Keyword: oxygen ratio

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Measurement of Ignition Delay Time of Methane/Oxygen Mixtures by Using a Shock Tube (충격파관을 이용한 메탄/산소 혼합기의 점화지연시간 측정)

  • Han, Hee Sun;Wang, YuanGang;Kim, Chul Jin;Sohn, Chae Hoon
    • Journal of the Korean Society of Combustion
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    • v.22 no.1
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    • pp.8-13
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    • 2017
  • Ignition delay time of methane/oxygen mixture is measured experimentally with the shock tube in order to obtain the data for high pressure conditions where gas turbines and internal combustion engines are operating. The shock tube experiment is validated first over the temperature range of 1400-2000 K at 10 bar and with the various equivalence ratios of 0.5, 1 and 2. The measured ignition delays are compared with the data from the literatures. And then, experiments are conducted for non-explored conditions, i.e., at 40 bar and with the equivalence ratio of 1.5. The present experimental data show a good agreement with the available ones from the literatures and reasonable dependence on pressure and equivalence ratio. In addition, the effects of the temperature and equivalence ratio on ignition delay time are analyzed.

Physical Properties of ITO/PVDF as a function of Oxygen Partial Pressure (산소 분압 조절에 따른 ITO/PVDF 박막 물성 조절 연구)

  • Le, Sang-Yub;Kim, Ji-Hwan;Park, Dong-Hee;Byun, Dong-Jin;Choi, Won-Kook
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.10
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    • pp.923-929
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    • 2008
  • On the piezoelectric polymer, PVDF (poly vinylidene fluoride), the transparent conducting oxide (TCO) electrode material thin film was deposited by roll to roll sputtering process mentioned as a mass product-friendly process for display application. The deposition method for ITO Indium Tin Oxides) as our TCO was DC magnetron sputtering optimized for polymer substrate with the low process temperature. As a result, a high transparent and good conductive ITO/PVDF film was prepared. During the process, especially, the gas mixture ratio of Ar and Oxygen was concluded as an important factor for determining the film's physical properties. There were the optimum ranges for process conditions of mixture gas ratio for ITO/PVDF From these results, the doping mechanism between the oxygen atom and the metal element, Indium or Tin was highly influenced by oxygen partial pressure condition during the deposition process at ambient temperature, which gives the conductivity to oxide electrode, as generally accepted. With our studies, the process windows of TCO for display and other application can be expected.

Mechanism of Lung Damage Induced by Cyclohexane in Rats (Cyclohexane에 의한 랫드의 폐손상 기전)

  • 전태원;윤종국
    • Toxicological Research
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    • v.18 no.2
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    • pp.159-165
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    • 2002
  • Recently, we reported (korean J. Biomed. Lab. Sci., 6(4): 245-251, 2000) that cyclohexane (l.56 g/kg of body wt., i.p.) administration led to lung injury in rats. However the detailed mechanism remain to be elucidated. This study was designed to clarify the mechanism of lung damage induced by cyclohexane in rats. First, lung damage was assessed by quantifying bronchoalveolar lavage fluid (BAL) protein content as well us by histopathological examination. Second, activities of serum xanthine oxidase (XO), pulmonary XO and oxygen free radical scavenging enzymes. XO tope conversion (O/D + O, %) ratio and content of reduced glutathione (GSH) were determined. In the histopathological findings, the vasodilation, local edema and hemorrhage were demonstrated in alveoli of lung. And vascular lumens filled with lipid droplets, increased macrophages in luminal margin and increased fibroblast-like interstitial cells in interstitial space were observed in electron micrographs. The introperitoneal treatment of cyclohexane dramatically increased BAL protein by 21-fold compared with control. Cyclohexane administration to rats led to a significant rise of serum and pulmonary XO activities and O/D + O ratio by 47%,30% and 24%, respectively, compared witれ control. Furthermore, activities of pulmonary oxygen free radical scavenging enzymes such as superoxide dismutase, glutathione peroxidase and glutathione S-transferase, and GSH content were not found to be statistically different between control and cyclohexane-treated rats. These results indicate that intraperitoneal injection of cyclohexane to rats may induce the lipid embolism in pulmonary blood vessel and lead to the hypoxia with the ensuing of oxygen free radical generation, and which may be responsible for the pulmonary injury.

XPS Investigation and Field Emission Property of the Ar Plasma Processed Carbon Nanotube Films

  • Lee, Sun-Woo;Lee, Boong-Joo;Oda, Tetsuji
    • Transactions on Electrical and Electronic Materials
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    • v.9 no.2
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    • pp.52-56
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    • 2008
  • Carbon nanotube films were fabricated by the catalytic CVD method. Plasma processed time effects on the field emission property were studied. The atomic structure was observed by using X-ray photoelectron spectroscopy (XPS). The surface composition changes were observed on the plasma processed CNT films. The O1s/C1s signal ratio and the Fls/Cls signal ratio changed from 1.1 % to 24.65 % and from 0 % to 3.1 % with plasma process time, respectively. We could guess it from these results that the Ar plasma process could change the surface composition effectively. In the case of the original-CNT film, no carbon shift was observed. In the case of the Ar plasma processed CNT films, however the oxygen related carbon shifts were observed. This oxygen related carbon shift at higher binding energy implies the increment of amount of the oxygen. It's possible that the increment of these bonds between carbon and oxygen results in the improvement of field emission performance.

Effect of Oxygen on the Magnetic and Recording Characteristics of Magneto-Optical Disk (광자기 디스크의 기록 및 자기적 특성에 산소가 미치는 영향)

  • Choe, G.
    • Journal of the Korean Magnetics Society
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    • v.3 no.3
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    • pp.229-233
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    • 1993
  • The effects of differential partial pressures of oxygen during sputtering on the magnetic and recording characteristics of magneto-optical disks were investigated. Different flows of oxygen were deliberately introduced into the sputtering chamber to have a variety of partial pressures of oxygen during sputtering. A residual gas analyzer was employed to monitor the oxygen peak before, during, and after sputtering and to estimate the reacted oxygen amount. Most of the oxygen introduced into the chamaber was reacted during sputtering. As the partial pressure of oxygen increased, the oxygen content of the TbFeCoCr film increased also. The oxygen appeared to be bound as Tb-O, effectively decreasing the magnetically active Tb content of the film The coercivity decreased but the squareness of the Kerr hysteresis loops was still excellent. The perpendicular anisotropy was not significantly affected by oxygen amount. The carrier-to-noise ratio, includi!1g the write power sensitivity and bias field sensitivity did not change too much with oxygen content in the film The disks sputtered with oxygen showed better bias field sensitivity with lower write power threshold than the disk sputtered without oxygen, due to high demagnetization during domain formation. No significant degradation of coercivity for the disk sputtered oxygen was observed during an accelerated aging test.

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Prediction of Biodiesel Combustion, CO and NOX Emission Characteristics in Accordance with Equivalence Ratio (당량비 변화에 따른 바이오디젤 연소 및 CO, NOX 생성 특성 예측)

  • Lim, Young Chan;Suh, Hyun Kyu
    • Journal of the Korean Society of Combustion
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    • v.21 no.1
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    • pp.1-7
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    • 2016
  • This study was performed to provide the basic information of the combustion, CO and $NO_X$ characteristics of biodiesel in accordance with equivalence ratio. The closed homogeneous reactor model used for the analysis. The analysis conditions were set to 900 K of the initial temperature, 20 atm of initial pressure and equivalence ratio was changes from 0.6 to 1.4. The results of analysis were predicted and compared in terms of combustion temperature, combustion pressure, CO and $NO_X$ emissions. The results of combustion characteristics showed that ignition delay was decreased and the combustion temperature and combustion pressure was increased in accordance with equivalence ratio. CO emission was decreased in lean condition(${\Phi}$ < 1.0), however, CO emission was increased in rich condition(${\Phi}$ > 1.0) because oxygen supply insufficient. $NO_X$ emission showed the largest amount in condition 0.8 of equivalence ratio because the oxygen concentration was sufficient.

Effect of the O2/N2 Ratio on the Growth of TiO2 Nanowires via Thermal Oxidation (열 산화를 이용한 TiO2 나노선의 성장에 미치는 O2/N2 가스비의 영향)

  • Lee, Geun-Hyoung
    • Korean Journal of Materials Research
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    • v.25 no.10
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    • pp.543-546
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    • 2015
  • $TiO_2$ nanowires were grown by thermal oxidation of TiO powder in an oxygen and nitrogen gas environment at $1000^{\circ}C$. The ratio of $O_2$ to $N_2$ in an ambient gas was changed to investigate the effect of the gas ratio on the growth of $TiO_2$nanowires. The oxidation process was carried out at different $O_2$/$N_2$ ratios of 0/100, 25/75, 50/50 and 100/0. No nanowires were formed at $O_2$/$N_2$ ratios of less than 25/75. When the $O_2$/$N_2$ ratio was 50/50, nanowires started to form. As the gas ratio increased to 100/0, the diameter and length of the nanowires increased. The X-ray diffraction pattern showed that the nanowires were $TiO_2$ with a rutile crystallographic structure. In the XRD pattern, no peaks from the anatase and brookite structures of $TiO_2$were observed. The diameter of the nanowires decreased along the growth direction, and no catalytic particles were detected at the tips of the nanowires which suggests that the nanowires were grown with a vapor-solid growth mechanism.

Fundamental Studies on the Manufactruring of prouse Electrode for Plosphoric Acid Fuel Cell. (인산형 연료전지의 다공성전극 제조에 관한 기초적연구)

  • 김영우;박정일;이주성
    • Journal of the Korean institute of surface engineering
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    • v.22 no.2
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    • pp.55-61
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    • 1989
  • A fuel cell which causes electrochemical ratio of conventional with oxygen consists of mainly there parts, such as electrolyte, fuel and oxidant electrode. IN this paper, most efforts were delivered to manufacturing PETE-bonded gas-diffusion electrode, and preparation methods of the porous electrodes has been discussd. A medio temperature, phosphoric acid fuel cell (PAFC) provided with fuel (hydrogen) and oxygen showed oxygen showed excellent performance characteristics with made electrodes. Performance data obtained from hydrgen-oxygen cell were presented to illustrate their properties. It was found that the optimum amounts of platinum in clectrode for hydrgen-oxygen PAFC were about 3mg/cm3 and the PTFE content of gas diffusion layer and catalyst layer were 25% and 15%, respectively.

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Characteristics of ITO/polymeric Films with Change of Oxygen Partial Pressure (산소분압의 변화에 따른 ITO/polymeric 박막의 특성)

  • 신성호;김현후
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.8
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    • pp.846-851
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    • 2004
  • Transparent conducting indium tin oxide (TC-ITO) thin films on polymeric substrates have been deposited by a dc reactive magnetron sputtering without heat treatments. The polymeric substrates are acryl (AC), poly carbornate (PC), and polyethlene terephthalate (PET) as well as soda lime glass is also used to compare with the polymeric substrates. Sputtering parameters are an important factor for high quality of TC-ITO thin films prepared on polymeric substrates. Furthermore, the material, electrical and optical properties of as-deposited ITO films are dominated by the ratio of oxygen partial pressure. As the experimental results, the surface roughness of ITO films becomes rough as the oxygen partial pressure increases. The electrical resistivity of as-deposited ITO films decreases initially, and then increases with the increase of oxygen partial pressure. The optical transmittance at visible wavelength for all polymeric substrates is above 82 %.

The Development of Convenient RQ Measuring Device for Patients Real Time Monitoring (환자의 실시간 모니터링을 위한 간편한 RQ 측정기기의 개발)

  • Kim, Y.S.;Jeon, H.M.;Choi, S.W.;Shim, E.B.
    • Proceedings of the KSME Conference
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    • 2008.11a
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    • pp.1609-1612
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    • 2008
  • RQ(Respiratory Quotient) value is obtained from the ratio of the consumed oxygen and the produced carbon dioxide during the patient's respiration. To investigate the efficacy of insulin and diagnosis the metabolic disorder in short time, the RQ value can be used as important parameter. The measurement of oxygen and carbon dioxide amounts is needed large chamber and complex sensors. But If the atmospheric oxygen and carbon dioxide concentrations do not change, the expiratory oxygen and carbon dioxide can be used to obtain RQ value. A convenient RQ measuring device has been developed by using two sensors for O2 and CO2. The estimation of RQ devices confirms that the RQ device can obtain accurate data by eliminating uncertain factor such as delay time and remaining gases.

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