• Title/Summary/Keyword: oxygen barrier

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Modeling of Dielectric Barrier Discharge Plasma Process for the Removal of Nitric Oxide (유전체 방전 플라즈마 공정에 의한 일산화질소 제거 공정 모델링)

  • Mok, Young-Sun
    • Journal of the Korean Society of Industry Convergence
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    • v.6 no.4
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    • pp.277-289
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    • 2003
  • This study proposes a mathematical model to characterize the removal of nitrogen oxides in a dielectric barrier discharge plasma process. As well as the reactions between nitrogen oxides, water vapor, oxygen and nitrogen, the model takes into account the effect of ethylene often used as a chemical additive to reduce the power consumption of the process on the removal of nitrogen oxides. Since the concentrations of the radicals concerned in the main reactions including O, OH, H and N should be calculated to predict the removal efficiency of nitrogen oxides, they were theoretically derived. The parameters affecting the removal of nitrogen oxides, such as initial concentration, discharge power, humidity, and ethylene concentration were experimentally evaluated, which were compared with the calculated results to verify the validity of the model proposed. The predicted concentrations of several byproducts formed in this process were also presented and discussed. The effects of several parameters mentioned above on the removal of nitrogen oxides were reasonable described by the proposed model.

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Discharge and Ozone Generation Characteristics of a Micro-Size Nonthermal Plasma Generator Using Silicon Oxide Film (실리콘 산화막을 이용한 초소형 비열플라즈마 발생장치의 방전 및 오존발생특성)

  • Kang, Jeong-Hoon;Tae, Heung-Sik;Moon, Jae-Duk
    • Proceedings of the KIEE Conference
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    • 1996.07c
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    • pp.1816-1818
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    • 1996
  • A micro-size nonthermal plasma generator, using a $SiO_2$ film as a dielectric barrier, has been studied experimentally for a high frequency ac voltage in 2LPM oxygen gas fed. The $SiO_2$ film as a micro-size dielectric barrier was made by the wet oxidation of n-type Si wafer($220[{\mu}mt]$). It can be generated ozone, as a nonthermal plasma intensity parameter, at very low level of applied voltage about 1[kV] by using the micro-size dielectric barrier. As a result, in case that have no air gap spacing i.e. surface discharge case shows relatively higher ozone concentration rather than that case of the micro-airgap spacing.

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Effects of Hydrophilic Surface Treatment on SUS Substrates by Using Dielectric Barrier Discharge

  • Joa, Sang-Beom;Kang, In-Je;Yang, Jong-Keun;Lee, Heon-Ju
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.458-458
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    • 2012
  • Fuel Cell is used stacking metal or polymer substrate. This hydro property of substrate surface is very important. Usually, surface property is hydrophilic. The surface oxidation of SUS is investigated through plasma treatments with an atmospheric-pressure dielectric barrier discharge (DBD) for increasing hydrophilic property. The plasma process makes an experiment under various operating conditions of the DBD, which operating conditions are treatment time, plasma gas mixture ratio, the plasma source supply frequency. Two kinds of SUS substrate, SUS-304 and SUS 316L, were used. Discharge frequency has a crucial impact on equipment performance and gas treatment. After the plasma treatment of a SUS plate, highly improved wettability was noted. But, when high oxygen supply, the substrate damaged seriously.

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Contact Resistance and Leakage Current of GaN Devices with Annealed Ti/Al/Mo/Au Ohmic Contacts

  • Ha, Min-Woo;Choi, Kangmin;Jo, Yoo Jin;Jin, Hyun Soo;Park, Tae Joo
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.16 no.2
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    • pp.179-184
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    • 2016
  • In recent years, the on-resistance, power loss and cell density of Si power devices have not exhibited significant improvements, and performance is approaching the material limits. GaN is considered an attractive material for future high-power applications because of the wide band-gap, large breakdown field, high electron mobility, high switching speed and low on-resistance. Here we report on the Ohmic contact resistance and reverse-bias characteristics of AlGaN/GaN Schottky barrier diodes with and without annealing. Annealing in oxygen at $500^{\circ}C$ resulted in an increase in the breakdown voltage from 641 to 1,172 V for devices with an anode-cathode separation of $20{\mu}m$. However, these annealing conditions also resulted in an increase in the contact resistance of $0.183{\Omega}-mm$, which is attributed to oxidation of the metal contacts. Auger electron spectroscopy revealed diffusion of oxygen and Au into the AlGaN and GaN layers following annealing. The improved reverse-bias characteristics following annealing in oxygen are attributed to passivation of dangling bonds and plasma damage due to interactions between oxygen and GaN/AlGaN. Thermal annealing is therefore useful during the fabrication of high-voltage GaN devices, but the effects on the Ohmic contact resistance should be considered.

Removal Efficiency of Heavy Metals and Nutrients by Zeolite and Basic Oxygen Furnace Slag (제올라이트와 제강슬래그에 의한 중금속과 영양염류 복합오염물질의 제거 효과)

  • Kim, Yongwoo;Oh, Myounghak;Park, Junboum;Kwon, Osoon
    • Journal of the Korean GEO-environmental Society
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    • v.15 no.11
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    • pp.13-19
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    • 2014
  • Permeable reactive barrier has been recognized as the one of representative methods for remediation of contaminated groundwater. Reactive barrier system containing two and more reactive materials can remove multiple contaminants such as nutritive salts and heavy metals. In this study, removal efficiency of multiple contaminants was evaluated when both zeolite and basic oxygen furnace slag were used as reactive materials. Sequential batch test which consists of two materials was performed to evaluate removal efficiency comparing the reaction order of them against nutritive slats including ammonium and phosphate and heavy metal including cadmium. As a result, zeolite-basic oxygen furnace slag sequence batch test showed the best efficiency for removal of multiple contaminants including nutritive salts and heavy metal.

Extent and persistence of dissolved oxygen enhancement using nanobubbles

  • Tekile, Andinet;Kim, Ilho;Lee, Jai-Yeop
    • Environmental Engineering Research
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    • v.21 no.4
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    • pp.427-435
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    • 2016
  • In this study, change in water-dissolved oxygen (DO) was analyzed under various synthetic water qualities and nanobubbles (NBs) application conditions, such as gas type, initial DO as well as water dissolved, suspended and organic matters contents. When oxygen, rather than air, was introduced into nitrogen-desorbed ultra-pure water, the stagnation time was significantly increased. It took ten days for DO concentration to drop back to saturation. The higher the initial DO concentration, the longer particles were observed above saturation due to particle stability improvement. The oxygen mass transfer rate of 0.0482 mg/L/min was found to reach a maximum at an electrolytic concentration of 0.75 g/L, beyond which the transfer rate decreased due to adsorption of negative ions of the electrolyte at the interface. High levels of turbidity caused by suspended solids have become a barrier to dissolution of NBs oxygen into the water solution, and thus affected the transfer performance. On the other hand, by applying NBs for just an hour, up to 7.2% degradation of glucose as representative organic matter was achieved. Thus, NBs technology would maintain a high DO extent for an extended duration, and thus can improve water quality provided that water chemistry is closely monitored during its application.

Synchrotron radiation photoelectron spectroscopy study of oxygen doping effect by oxygen plasma treatment to inverted top emitting organic light emitting diodes

  • Hong, Ki-Hyon;Kim, Ki-Soo;Kim, Sung-Jun;Choi, Ho-Won;Tak, Yoon-Heung;Lee, Jong-Lam
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.118-120
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    • 2009
  • We reported that the evidence of oxygen doping to copper-phthalocyanine (CuPc) by $O_2$-plasma treatment to Au electrode of inverted top emitting organic light emitting diodes (ITOLEDs). The operation voltage of OLEDs at 150 mA/$cm^2$ decreased from 16.1 to 10.3 V as oxygen atoms indiffued to CuPc layer using $O_2$-plasma. Synchrotron radiation photoelectron spectroscopy results showed that a new bond of Cu-O appeared and the energy difference between the highest occupied molecular orbital and $E_F$ is lowered by 0.20 eV after plasma treatment. Thus the hole injection barrier was lowered, reducing the turn-on voltage and increasing the quantum efficiency of OLEDs.

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Characterization of Silica/EVOH Hybrid Coating Materials Prepared by Sol-Gel Method

  • Kim, Seong-Woo
    • Journal of the Korean Applied Science and Technology
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    • v.26 no.3
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    • pp.288-296
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    • 2009
  • In this study, the silica-based hybrid material with high barrier property was prepared by incorporating ethylene-vinyl alcohol (EVOH) copolymer, which has been utilized as packaging materials due to its superior gas permeation resistance, during sol-gel process. In preparation of this EVOH/$SiO_2$ hybrid coating materials, the (3-glycidoxy-propyl)-trimethoxysilane (GPTMS) as a silane coupling agent was employed to promote interfacial adhesion between organic and inorganic phases. As confirmed from FT-IR analysis, the physical interaction between two phases was improved due to the increased hydrogen bonding, resulting in homogeneous microstructure with dispersion of nano-sized silica particles. However, depending on the range of content of added silane coupling agent (GPTMS), micro-phase separated microstructure in the hybrid could be observed due to insufficient interfacial attraction or possibility of polymerization reaction of epoxide ring in GPTMS. The oxygen barrier property of the mono-layer coated BOPP (biaxially oriented polypropylene) film was examined for the hybrids containing various GPTMS contents. Consequently, it is revealed that GPTMS should be used in an optimum level of content to produce the high barrier EVOH/$SiO_2$ hybrid material with an improved optical transparency and homogeneous phase morphology.