• Title/Summary/Keyword: overall mass transfer coefficient

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Experimental Study on Heat and Mass Transfer Characteristics in bundles of horizontal absorption tubes (수평관군 흡수기의 열 및 물질 전달특성에 관한 실험적 연구)

  • 설원실;정용욱;문춘근;윤정인
    • Journal of Advanced Marine Engineering and Technology
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    • v.24 no.3
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    • pp.113-120
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    • 2000
  • On the absorber of absorption chiller/heater, LiBr solution at high concentration is sprinkled on a bundle of horizontal tube cooled by cooling water. In this case, the conditions of LiBr solution and cooling water have an influence on heat/mass transfer coefficient in this system. Therefor it is important to find optimal operation conditions of absorption chiller/heater to save energy. Heat and mass transfer coefficient increased with the increase of solution flow rate, and also heat and mass transfer rate increased but overall heat and mass transfer coefficient decreased by increasing the solution concentration within the experimental range. The superheating of the solution resulted in superior heat transfer character to a state of equilibrium from the point of heat flux and overall heat transfer coefficient.

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Development of Mass Transfer Models for Ammonia Flux Estimation from Sewage Treatment Plants (하수처리장에서의 암모니아 플럭스 산정을 위한 물질전달모형 개발)

  • Sa, Jae-Hwan;Jeon, Eui-Chan;Jeong, Jae-Hak
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.5
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    • pp.701-711
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    • 2006
  • Sewage treatment plants located near to large cities emit extremely higher concentration of odorous materials. This study evaluated flux profiles of ammonia emitted from the water surface of sewage treatment plants using a dynamic flux chamber. Also, an ammonia overall mass transfer coefficient and a mass transfer model was developed in order to estimate fluxes of ammonia using environment parameters and the flux from the sewage treatment plants. The developed mass transfer model was evaluated through a fitness analysis. Comparison modeled flux applying empirical overall mass transfer coefficients of ammonia and measured ammonia flux show a high linearity with 0.977. The flux ratio of 1.282 demonstrated highly statistical fitness, also. Modeled flux using the mass transfer model was compared with measured flux. In result, it indicated that empirical overall mass transfer coefficients were similar to measured flux. The mass transfer model using the empirical overall mass transfer coefficient developed in this study was proved to be an easy and effective method to make accurate and precise predictions for ammonia flux discharged from sewage treatment plants.

An analytical model to decompose mass transfer and chemical process contributions to molecular iodine release from aqueous phase under severe accident conditions

  • Giedre Zablackaite;Hiroyuki Shiotsu;Kentaro Kido;Tomoyuki Sugiyama
    • Nuclear Engineering and Technology
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    • v.56 no.2
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    • pp.536-545
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    • 2024
  • Radioactive iodine is a representative fission product to be quantified for the safety assessment of nuclear facilities. In integral severe accident analysis codes, the iodine behavior is usually described by a multi-physical model of iodine chemistry in aqueous phase under radiation field and mass transfer through gas-liquid interface. The focus of studies on iodine source term evaluations using the combination approach is usually put on the chemical aspect, but each contribution to the iodine amount released to the environment has not been decomposed so far. In this study, we attempted the decomposition by revising the two-film theory of molecular-iodine mass transfer. The model involves an effective overall mass transfer coefficient to consider the iodine chemistry. The decomposition was performed by regarding the coefficient as a product of two functions of pH and the overall mass transfer coefficient for molecular iodine. The procedure was applied to the EPICUR experiment and suppression chamber in BWR.

Performance and Heat Transfer Characteristics of Heat Pump System Using Refrigerant Mixtures (혼합냉매를 사용한 열펌프 시스템의 성능과 열전달 특성)

  • Kim, T.S.;Shin, J.Y.;Ro, S.T.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.4 no.4
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    • pp.360-369
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    • 1992
  • A heat pump system is constructed to evaluate its performance and heat transfer characteristics with mixtures of R22/R142b as working fluids. The heat transfer in the evaporator and the overall performance are measured and analyzed in terms of the compositions and relevant variables. Possibility of capacity modulation by changing composition is observed without degradation of heat transfer coefficients and coefficient of performance. The cooling capacity is varied continuously within 200 percent based on minimum capacity at constant compressor speed. For similar cooling capacity, COP is improved by mixing two refrigerants and shows maximum value at 60% mass fraction of R22. Average heat transfer coefficients of mixtures decrease in comparison with pure refrigerants at similar cooling capacity and mass flow rate. However, the overall heat transfer coefficients decrease moderately. A cycle simulation is performed in order to manifest the advantages of using refrigerant mixtures, considering experimentally observed heat transfer characteristics.

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Kinetics of CO2 Absorption in Aqueous DETA and DEEA Solutions by Wetted-Wall Column (젖은 벽탑을 이용한 디에틸렌트리아민과 디에틸에탄올아민 수용액의 CO2 흡수속도 측정)

  • You, Jong Kyun;Lee, Jun;Hong, Yeon Ki
    • Korean Chemical Engineering Research
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    • v.60 no.4
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    • pp.582-587
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    • 2022
  • Biphasic solvents are attracting attention as energy-reducing solvents for capturing CO2 from flue gas in combustion process. In this study, considering diethylenetriamine (DETA) and diethylethanolamine (DEEA) mixed solvents, one of the biphasic solvents by blending of two types of amines, the CO2 absorption rates of DETA and DEEA was measured by wetted wall column. The effects of DETA and DEEA concentrations and operating temperature on the overall mass transfer coefficient were investigated. As a result, the overall mass transfer coefficient was proportional to the DETA concentration. However, in the case of the DEEA concentration, the effect was small and when the concentration was exceeded, the overall mass transfer coefficient decreased. The DETA aqueous solution showed little change in the overall mass transfer coefficient with the operating temperature, whereas the DEEA aqueous solution increased the overall mass transfer coefficient with the operating temperature. As a result of obtaining the observed reaction rate constant under the pseudo-first-order reaction assumption, it was found that the observed reaction rate constant in DETA aqueous solution was proportional to the DETA concentration, but DEEA did not fit the pseudo-first-order reaction assumption.

Thermal Performance Characteristics of Closed-Wet Cooling Tower (밀폐형 냉각탑의 열성능 특성에 관한 실험적 연구)

  • Sarker, M.M.A.;Kim, E.P.;Moon, C.G.;Yoon, J.I.
    • Journal of Power System Engineering
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    • v.9 no.2
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    • pp.88-92
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    • 2005
  • The experiment of thermal performance about closed-wet cooling tower was conducted in this study. A closed cooling tower is a device similar to a general cooling tower, but with cooling tower replaced by a heat exchanger. The test section for this experiment has the process that the cooling water flows from the top of the heat exchanger to the bottom side in the inner part of the tube, and spray water flows in the gravitational direction in the outer side. Air comes in direct contact with the spray water at the outer side of the tube while passing from the lower the upper part having a counterflow to the spray water. The heat transfer pipe used in this experiment is a bare-type tube having an outer diameter of 15.88mm. The heat exchanger is consisted of seven rows and fifteen columns. In this experiment, thermal performance of the cooling tower is derived from overall heat transfer coefficients between the process fluid and sprayed water and volumetric overall mass transfer coefficient between sprayed water and air.

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Dynamic Behavior of an Internal Loop Reactor during Scale-up (내부순환반응기의 Scale-up에 따른 동력학적 특성의 변화)

  • 최윤찬;박영식
    • Journal of Environmental Science International
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    • v.6 no.1
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    • pp.25-31
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    • 1997
  • The variations of gas hold-up, overall volumetric oxygen mass transfer coefficients and liquid circulation velocity in an internal loop reactor were investigated to manifest scale-up effect. The relationship between superficial gas velocity and gas hold-up were found as Ugr = 0.045 $\varepsilon$r in the pilot-scale and Ugr = 0.056 $\varepsilon$r in the bench-scale reactor. The overall volumetric oxygen mass tractsfer coefficient, KLa was slightly increased in the pilot-scale than in the bench-scale reactor. Flow regime was changed from the bubble flow to the churn-turbulent flow when the superficial gas velocity reached to 3.5 - 4 cm/sec in the pilot-scale.

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Heat and Mass Transfer between Hot Waste Gas and Cold Water in a Direct Contact Heat Exchanger (직접접촉식 열교환기내에서 물과 배기가스의 직접접촉에 의한 열 및 물질전달)

  • 이금배
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.16 no.6
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    • pp.1171-1178
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    • 1992
  • An experiment was performed to describe the heat and mass transfer occurring between hot waste gas and cold water through direct contact in a direct contact heat exchanger. This model was then used to obtain an equation of overall heat transfer coefficent based on heat exchanger volume. The diffusion heat transfer rate is 2-3 times larger than the convection heat transfer rate as results of condensation of the water vapor contained in the waste gas. The boiler efficiency increases over 10%.

Carbon Dioxide Absorption in a Packed Column Using Guanidine-based Superbase Solution (구아니딘계 초염기 흡수제에 의한 충진탑에서의 이산화탄소 포집 특성)

  • Choi, Young Min;Hong, Yeon Ki;You, Jong Kyun
    • Korean Chemical Engineering Research
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    • v.54 no.5
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    • pp.648-652
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    • 2016
  • The study of $CO_2$ absorption in a packed column by 1,1,3,3-tetramethylguanidine (TMG) dissolved in ethylene glycol is presented. Absorption column of inner diameter 1 in and 0.6 m length was filled with Protruded-packing $0.16in{\times}0.16in$. We investigated the effect of operating conditions on overall mass transfer coefficients as well as on $CO_2$ removal efficiency. The loading values reached at about $1.0mol_{CO2}/mol_{TMG}$. In case of absorbent with lean $CO_2$ loading, the overall mass transfer coefficient was proportional to the concentration of TMG. However, in the range of more than ${\alpha}=0.5molCO_2/molTMG$, the overall mass transfer coefficients decreased with the concentration of TMG. It is due to the increasing of mass transfer resistance in liquid phase as increasing of viscosity at higher loading values.

Heat Transfer Characteristics of Fin-Tube Heat Exchanger Coated with FAPO Zeolite Adsorbent at Different Operating Conditions (FAPO 제올라이트 흡착제 코팅을 통한 핀-관 열교환기 운전조건별 열전달 성능특성)

  • Jeong, Chul-Ki;Kim, Yong-Chan;Bae, Kyung-Jin;Cha, Dong-An;Kwon, Oh-Kyung
    • Journal of Power System Engineering
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    • v.21 no.3
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    • pp.93-101
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    • 2017
  • In conventional adsorption chamber, adsorbent is embedded in between heat exchanger fins by wire mesh. This method impedes heat and mass transfer efficiency. So in this study, to improve the heat transfer performance of heat exchanger, a fin-tube exchanger was coated with FAPO (Ferroaluminophosphate) zeolite adsorbent. The fin-tube heat exchanger has a fin pitch of 1.8 mm with a variation of adsorbent coating thickness of about 0.1 mm, 0.15 mm and 0.2 mm. By varying cooling water temperature and chilled water temperature respecively, heat transfer rate and overall heat transfer coefficient were investigated. As a result, the heat transfer rate and overall heat transfer coefficient increase with decreasing cooling water temperature and increasing chilled water temperature. Under the basic conditions, the heat transfer rate of heat exchanger with 0.2 mm coating thickness is 11% and 43% higher than that of 0.1 mm and 0.15 mm, respectively. The overall heat transfer coefficient is $189.1W/m^2{\cdot}^{\circ}C$, it is two times lager than that of 0.1 mm.