• Journal of the Korean Electrochemical Society
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• v.19 no.3
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• pp.57-62
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• 2016

The over-discharging phenomena in sodium-nickel chloride batteries were investigated in relation to decomposition of molten salt electrolyte and consequent metal co-deposition. From XRD analysis, the material deposited on graphite cathode current collector was revealed to be by-product of molten salt electrolyte decomposition. In particular, the result showed that the Ni-Al alloys ($Al_3Ni_2$, $Ni_3Al$ and $Al_3Ni$) were electrochemically deposited on graphite current collectors in line with over-discharging behaviors. It is assumed that the $NiCl_2$ solubility in molten salt electrolytes leads to the co-deposition of Ni-Al alloys by increasing metal deposition potential above 1.6 V (vs. $Na/Na^+$). The cell tests have revealed that the composition of molten salt electrolytes modified by various additives makes a decisive influence on the over-discharging behaviors of the cells. It was revealed that NaOCN addition to molten salt electrolytes was advantageous to suppress over-discharge reactions by modifying the characteristics of molten salt electrolytes. NaOCN addition into molten salt electrolytes seems to suppress Ni solubility by maintaining basic melts. The cell using modified molten salt electrolyte with NaOCN (Cell D) showed relatively less cell degradation compared with other cells for long cycles.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.5 no.4
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• pp.706-715
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• 2001

TCP typically offers reasonable end-to-end performance to users regardless of the bandwidth and error characteristics of particular network technology, The robustness of TCP has contributed to its success in the internet environment. The role of communications is already well established in the office environment. With the advent of cheap, affordable broadband communications and the increasing complexity of consumer goods, it seems natural to extend the network into homes. In-home networking means a high-speed communication among the digital appliances within a home. Introduction of application over high-speed home network using TCP/IP protocol is increasing. The integrated environment of internet and home network is demanding as well. We have validated TCP model over high speed home network environment, investigated the throughput behavior of TCP over IEEE 1399 home networks, and evaluated a potential solution for high performance of TCP over IEEE 139t home networks. The simulation model has produced several interesting results in the performance of TCP over IEEE 1394 home network.

• Journal of Ship and Ocean Technology
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• v.3 no.4
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• pp.1-14
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• 1999

The improved Green integral equation using the Kelvin-type Green function in known free of irregular frequencies where the integral over the inner free surface integral is removed from the integral equation, resulting in an overdetermined integral equation. The solution of the overdetermined Green integral equation is shown identical with the solution of the improved Green integral equation Using the B-spline higher order panel method, the overdetermined equation is discretized in two different ways; one of the resulting linear system is square and the other is redundant. Numerical experiments show that the solutions of both are identical. Using the present methods, the exact values and higher derivatives of the potential at any place over the wetted surface of the body can be found with much fewer panels than low order panel method.

• Proceedings of the IEEK Conference
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• 2005.11a
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• pp.821-824
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• 2005

Probe storage is one of the strong candidates for future mobile storage device since it has potential of recording density over I $Tb/in^2$ with r/w speed over 100 Mbps. It also uses silicon-processing technology that suits the purpose of small form factor. In this paper, write characteristics of resistive probe that can rotate the field direction of PZT by field-induced resistance changes in a small resistive region at the apex of the tip will be presented. Also, the relationship between the size of tip and the available write width is investigated for different source bias conditions. For this study, two-dimensional computer simulation ($SILVACO^{TM}$) was performed. With optimum design, the width of the writing electric field can be smaller than 50nm

• Bulletin of the Korean Chemical Society
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• v.28 no.10
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• pp.1683-1688
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• 2007

This paper presents a novel simple method for introducing gold nanoparticles in a poly(4-vinylpyridine) (PVP) polymer layer over a glassy carbon (GC) electrode with the aim of forming a tunable electrochemical interface against a cationic ruthenium complex. Initially, AuCl4 ? ions were spontaneously incorporated into a polymer layer containing positively charged pyridine rings in an acidic media by ion exchange. A negative potential was then applied to electrochemically reduce the incorporated AuCl4 ? ions to gold nanoparticles, which was confirmed by the FE-SEM images. The PVP layer with an appropriate thickness over the electrode blocked electron transfer between the electrode and the solution phase for the redox reactions of the cationic Ru(NH3)6 2+ ions. However, the introduction of gold nanoparticles into the polymer layer recovered the electron transfer. In addition, the electron transfer rate between the two phases could be tuned by controlling the number density of gold nanoparticles.

• Journal of Ocean Engineering and Technology
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• v.11 no.2
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• pp.91-99
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• 1997

This paper presents theoretical formulations and numerical computations for predicting first-and second-order hydrodynamic force on a ship advvancing in waves. The theoretical formulation leads to linearized radiation and diffration problems solving the three-dimensional Green function integral equations over the mean wetted body surface. Green function representing a translating and pulsating source potantial for infinite water depth is used. In order to solve integral equations for three dimentional flows using Green function efficiently, the Hoff's method is adopted for numerical calculation of the Green function. Based on the first-order solution, the mean seconder-order forces and moments are obtained by directly integrating second-order pressure over the mean wetted body surface. The calculated items are carried out for analyzing the seakeeping characteristics of Series 60. The calculated items are hydrodynamic coefficients, wave exciting forces, frequency response functions and addd resistance in waves.

• Journal of Ocean Engineering and Technology
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• v.23 no.3
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• pp.59-64
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• 2009

Bridge types such as the suspension bridges and the cable stayed bridges maintained by cables present the dangerous possibility of a ship running through the bottom of the bridge. Due to hangers and main cables in the upper structural system, the bridge is also susceptible to disasters. However, these cable bridges are usually used for long span bridges over the sea. This structure is relatively more exposed to disasters, such as wind, hail, and earthquake, than other structures. This structure also has the potential to cause car accidents on account of the poor visibility due to foggy conditions. If a fire breaks out because of a car accident due to wind, a car explosion will likely occur.

• Journal of Power Electronics
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• v.16 no.4
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• pp.1367-1374
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• 2016

This paper presents a discrete-time version of voltage and current limited operation using an enhanced direct torque and flux control method for interior permanent magnet synchronous motor (IPMSM) drives. A command voltage vector for airgap torque and stator flux regulation can be uniquely determined by the finite-settling-step direct torque and flux control (FSS-DTFC) algorithm under physical constraints. The proposed command voltage vector trajectories can be developed to achieve the maximum inverter voltage utilization for the discrete-time current limit (DTCL)-based FSS-DTFC. The algorithm can produce adequate results over a number of the potential secondary upsets found in the steady-state current limit (SSCL)-based DTFC. The fast changes in the torque and stator flux linkage improve the dynamic responses significantly over a wide constant-power operating region. The control strategy was evaluated on a 900W IPMSM in both simulations and experiments.

• Journal of Powder Materials
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• v.21 no.2
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• pp.93-96
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• 2014

Cobalt coated tungsten carbide-cobalt composite powder has been prepared through wet chemical reduction method. The cobalt sulfate solution was converted to the cobalt chloride then the cobalt hydroxide. The tungsten carbide powders were added in to the cobalt hydroxide, the cobalt hydroxide was reduced and coated over tungsten carbide powder using hypo-phosphorous acid. Both the cobalt and the tungsten carbide phase peaks were evident in the tungsten carbide-cobalt composite powder by X-ray diffraction. The average particle size measured via scanning electron microscope, particle size analysis was around 380 nm and the thickness of coated cobalt was determined to be 30~40 nm by transmission electron microscopy.

• Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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• v.10 no.S_1
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• pp.29-33
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• 2001

A numerical simulation was carried out to investigate the mechanism of snowfall around the Seoul region during a cold air-outbreak in the winter season. A particular case was selected for this study(Dec. 19, 1999). The inflow directions of the synoptic flow in the upper and lower levels were westerly and north-westerly, respectively. Plus, there was a deep trough and thermal ridge at a level of 500/700/850 hPa over the Bal-Hae region, in the northern part of the Korean peninsula. According to the model results, snowfall occurred around the Seoul region with the simultaneous existence of a strong static instability in the lower atmosphere, northerly or westerly dry air advection, and strong thermal advection toward the Seoul region. There was a strong convergence thereby indicating the existence of convective rolls in the clouds. The main energy source of convection over the Yellow sea was a sensible heat flux. The main moisture source was convection. Radiative cooling in the cloud layer intensified the static instability in the lower atmosphere.