• 제목/요약/키워드: over-potential

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Electrogeneration of Hypochlorite Ions using a Dimensionally Stable Anode-Type (Ti/PtPd(10%)Ox) Electrode

  • Teresa Zayas;Miriam Vega;Guillermo Soriano-Moro;Anabella Handal;Miguel Morales;Leonardo Salgado
    • Journal of Electrochemical Science and Technology
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    • 제15권2호
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    • pp.268-275
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    • 2024
  • The study examined the electrogeneration of hypochlorite ions (ClO-) via electrolysis of aqueous NaCl solutions using a dimensionally stable anode-type (DSA-type) electrode based on platinum and palladium oxides supported on titanium mesh (Ti/PtPd(10%)Ox). The electrogenerated ClO- was quantified on the basis of the absorption band at 292 nm (Aλ = 292) of the UV-Vis spectrum. The effect of initial pH, concentration of NaCl, cell potential difference and electrolysis time were investigated in this study. The results showed that the electrolysis of aqueous NaCl solutions increases the solution pH up to high values (≥ 8.0) that favor the formation of ClO- over chlorine or hypochlorous acid. The hypochlorite concentration increases significantly at pH values > 7.0 and shows a linear trend with increasing NaCl concentration and with increasing cell potential difference. When the cell potential and NaCl concentration are held constant, the maximum hypochlorite value during electrolysis depends on both the cell potential and NaCl concentration. The Ti/PtPd(10%)Ox anode favors the production of hypochlorite ions, making this anode a promising material for use in electrochemical oxidation of wastewater via an indirect mechanism.

단독주택에 대한 울산시 거주자의 주의식 연구 (A Study of Potential Buyers' Consciousness of Single-Family Housing in Ulsan)

  • 김지숙;양세화
    • 가정과삶의질연구
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    • 제28권6호
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    • pp.35-46
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    • 2010
  • The purpose of the study was to identify the potential buyers' consciousness of single-family housing to provide useful data to help future single-family housing supplies in Ulsan. The study selected residents in Ulsan, who were over twenty and had an interest in living in a single-family housing. A survey was conducted from September 11, 2008 to September 25, 2008. The sample consisted of 364 persons who are currently live in Ulsan metropolitan area. The results are as following. About two thirds of the sample had the desire to live in a single-family housing. Moving into a single-family housing had financial preparation as the greatest issue. When moving into a single-family housing, the convenience of the residential district was the greatest consideration, whether or not it is a green environment, pollution level, etc. The potential buyers valued environment-friendly features and also had a very strong desire to own their own house. Many of them wanted to design and build their own single-family housing within a budget of 100-200 million KRW. In terms of the location, there was a higher preference for the riverside or lakeside rural areas outside the city. In terms of size, the preference was less than $330m^2$, which includes $99-132m^2$ for residential. When considering a single-family housing the direction was the most important feature, along with eco-friendly and safer materials and equipments. When building the single-family housing the potential buyers considered the community spaces first with a preference for having three bedrooms and two bathrooms. For the exterior, they wanted a unique shape of roof and there were high preferences for brown and beige colors. In terms of housing complexes, the potential buyers preferred individual unit types over complexes. If they preferred housing complexes, they wanted the cluster form complex with about 10-30 units. The complex also required a park-like setting with a guard system, which shows that convenience and safety were the most important features. In terms of complex management, they considered environmental management as the most important feature. The potential buyers were willing to pay belw 200,000 KRW, which showed their desire to minimize financial burdens.

대류권계면 접힘에 의한 영동지방 집중호우사례의 특성분석 (An analysis of Characteristics of Heavy Rainfall Events over Yeongdong Region Associated with Tropopause Folding)

  • 이혜영;고혜영;김경익;윤일희
    • 한국지구과학회지
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    • 제31권4호
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    • pp.354-369
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    • 2010
  • 2006년 10월 22일에서 24일에 걸쳐 한반도 강릉지역에서 강한 집중호우가 발생했다. 이 기간에 대해서 집중호우가 발생하기 전과 강우강도가 가장 강했을 때 나타나는 종관적, 운동학적 특성을 조사하기 위하여 본 연구에서는 지상일기도, 상층일기도, 적외위성영상, 자동기상관측장비(AWS) 자료, NCEP(National Centers for Environmental Prediction) 전구분석자료를 이용하였다. 분석 기간 동안 강릉에서 관측된 총 강수량은 316.5 mm이고, 최대 순간풍속은 $63.7m\;s^{-1}$이다. 일기도를 분석해보면 집중호우가 시작하기 전 온대저기압이 한반도 중부에서 발달하였으며 한반도 북부에 역전기압골이 형성되어 있다. 또한 300 hPa 상층일기도에서는 서해와 한반도 남부에 제트기류가 위치하며, 위치 소용돌이도 이상과 관련된 절리 저기압이 한반도 북서부에서 발달하고 있다. 강우강도가 가장 강했을 때의 특성을 좀 더 자세히 알아보기 위하여 강릉지역의 위치 소용돌이도 이상과 바람, 위치 소용돌이도의 시간-연직 단면도, 연직운동, 발산장과 수렴장, 역학적 온위의 연직분포에 대해 조사하였다. 종관적, 운동학적 과정을 분석해 본 결과 대류권계면 접힘이 집중호우 발생에 큰 역할을 한 것으로 사료된다.

New Graphene Electronic Device Structure for High Ion/Ioff Ratio

  • 정현종
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제43회 하계 정기 학술대회 초록집
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    • pp.112-112
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    • 2012
  • Graphene has been considered as one of the potential post Si-materials due to its high mobility. [1] However, since graphene is semi-conductor with zero band gap, it is difficult to achieve high Ion/Ioff ratio, one of the most important requirements for commercial devices. There have been many attempts to open its band gap for high Ion/Ioff ratio, but most of them end up lowering the mobility. [2-5] Thus, we proposed and demonstrated a new device structure for graphene transistor based on one of the unique properties of graphene for high Ion/Ioff: using this approach, we were able to achieve the ratio over $10^5$. [6] Our device has several major advantages over previously proposed graphene based electronic devices. Since our device does not alter the given properties of graphene, such as opening the band gap, it has no fundamental issues on mobility degradations. In addition, our device is fully compatible with current Si technology and we were able to fabricate the devices with 6 inch wafer scale with CVD (Chemical Vapor Deposition) grown graphene. In this presentation, we will discuss about the details of our graphene device including the device structure and the detailed understanding of working mechanism. We will present device characteristics including I-V curves with $10^5$ on/off ratio. We will also present the performance of an inverter based on our devices. Finally, we will discuss the current issues and their potential solutions.

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참치 선망 어선의 선형개발에 관한 연구 (A Study on the development of Tuna Purse Seiner)

  • 김인철
    • 수산해양기술연구
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    • 제35권3호
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    • pp.335-342
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    • 1999
  • The purpose of present research is to develop and efficient numerical method for the calculation of potential flow and predict the wave-making resistance for the application to ship design of tuna purse seiner. Havelock was considered the wave resistance of a post extending vertically downwards through the water from the surface, its section by a horizontal plane being the same at all depths and having its breadth small compared with its length. This enables us to elucidate certain points of interest in ship resistance. However, the ship has not infinite draft. So, the problem which is investigated ind detail in this paper is the wave resistance of a mathematical quadratic model in a uniform stream. The paper deals with the numerical calculation of potential flow around the series 60 with forward velocity by the new slender ship theory. This new slender ship theory is based on the asymptotic expression of the Kelvin-source, distributed over the small matrix at each transverse section so as to satisfy the approximate hull boundary condition due to the assumption of slender body. The numerical results using the panel shift method and finite difference method are compared with the experimental results for wigley mono hull. There are no differences in the wave resistance. However, it costs much time to compute not only wave resistance but also wave pattern over some range of Froude numbers. More improvements are strongly desired in the numerical procedure.

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Distribution and Vertical Structures of Water Masses around the Antarctic Continental Margin

  • Kim, Seong-Joong;Lee, Bang-Yong
    • Ocean and Polar Research
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    • 제27권3호
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    • pp.277-288
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    • 2005
  • Spatial distribution and vertical structures of water masses around the Antarctic continental margin are described using synthesized hydrographic data. Antarctic Surface Water (AASW) over the shelf regime is distinguished from underlying other water masses by the cut-off salinity, varying from approximately 34.35 to 34.45 around Antarctica. Shelf water, characterized by salinity greater than the cut-off salinity and potential temperature less than $-17^{\circ}C$, is observed on the Ross Sea, off George V Land, off Wilkes Land, the Amery Basin, and the Weddell Sea, but in some shelves AASW occupies the entire shelf. Lower Circumpolar Deep Water is present everywhere around the Antarctic oceanic regime and in some places it mixes with Shelf Water, producing Antarctic Slope Front Water (ASFW). ASFW, characterized by potential temperature less than about $0^{\circ}C$ and greater than $-17^{\circ}C$, and salinity greater than the cut-off salinity, is found everywhere around Antarctica except in the Bellingshausen-Amundsen sector. The presence of different water masses over the Antarctic shelves and shelf edges produces mainly three types of water mass stratifications: no significant meridional property gradient in the Bellingshausen and Amundsen Seas, single property gradient where ASFW presents, and a V-shaped front where Shelf Water exists.

NCEP 재분석 자료를 이용한 전지구 지표층의 2000-2009년 풍속 분포 (Global Distribution of Surface Layer Wind Speed for the years 2000-2009 Based on the NCEP Reanalysis)

  • 변재영;최영진;이재원
    • 대기
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    • 제21권4호
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    • pp.439-446
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    • 2011
  • NCEP reanalysis data were analyzed in order to provide distribution of global wind resource and wind speed in the surface layer for the years 2000-2009. Wind speed at 10 m above ground level (AGL) was converted to wind speed at 80 m above the ground level using the power law. The global average 80 m wind speed shows a maximum value of $13ms^{-1}$ at the storm track region. High wind speed over the land exists in Tibet, Mongolia, Central North America, South Africa, Australia, and Argentina. Wind speed over the ocean increased with a large value in the South China Sea, Southeast Asia, East Sea of the Korea. Sea surface wind in Western Europe and Scandinavia are suitable for wind farm with a value of $7-8ms^{-1}$. Areas with great potential for wind farm are also found in Eastern and Western coastal region of North America. Sea surface wind in Southern Hemisphere shows larger values in the high latitude of South America, South Africa and Australia. The distribution of low-resolution reanalysis data represents general potential areas for wind power and can be used to provide information for high-resolution wind resource mapping.

유체환경 중에서 연강재의 간극부식에 관한 연구 (Study on the Crevice Corrosion of Mild Steel in Fluid Environment)

  • 임우조;윤병두
    • 유체기계공업학회:학술대회논문집
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    • 유체기계공업학회 2000년도 유체기계 연구개발 발표회 논문집
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    • pp.373-378
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    • 2000
  • The crevice corrosion of local corrosion occur when the gap exist on metal surface. This crevice corrosion happen to region such as flange of pipe, contact part of casing, under gasket and packing, between valve disk and seat of pump etc. Especially The crevice corrosion of mild steel(SS 400) get serious. This paper was studied on the crevice corrosion of SS 400 in fluid environment. In $0\%,\;2\%,\;3.5\%,\;5\% NaCl$ solution, the aspect of the crevice corrosion and polarization behavior under the crevice corrosion was investigated. And Weight loss rate of SS 400 with crevice and non-crevice was measured according to the NaCl concentration. The main results obtained are as follows : 1) Under crevice corrosion, the corrosion potential become less noble as the concentration of NaCl solution increased. 2) The current density under open circuit potential was high drained as concentration of NaCl solution increased by $3.5\%$ but the concentration increased over $3.5\%$, the current density was low drained. 3) The weight loss rate of SS 400 was increased as concentration of NaCl solution Increased by $3.5\%$, but the concentration increased over $3.5\%$, that of SS 400 was decreased. 4) Effect of oxygen for crevice corrosion in the concentration of $3.5\%$ NaCl solution become sensitive than that $0\%$ NaCl solution.

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Bilirubin의 전압전류법적 파라미터에 미치는 압력의 영향 (Effect of High Pressure on Voltammetric Parameters of Bilirubin)

  • 배준웅;이흥락;김경호;박태명
    • 대한화학회지
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    • 제34권4호
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    • pp.340-344
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    • 1990
  • 미소 백금전극을 작업전극으로 사용하여 0.1 M TEAP-DMSO 용액 중에서 Bilirubin(BR)의 산화반응의 전압전류법적 파라미터에 미치는 압력의 영향을 조사하였다. 1기압에서 1,800기압까지 압력을 증가함에 따라 산화파의 봉우리 전위는 양전위쪽으로 이동하였다. 또 압력의 증가에 따라 봉우리 전류는 계속적으로 감소하였다. BR의 산화전류는 확산지배적인 전류임을 알 수 있었다. 압력증가에 따라서 산화반응의 가역성은 거의 영향을 받지 않았다. 또한 실험 압력범위내(1~1,800기압)에서 산화파의 봉우리 전류와 Bilirubin의 농도 사이에는 좋은 직선성이 성립하였다.

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The Role of Northeast Asian Cities in a Global Urban Network

  • Rozman, Gilbert
    • 지역연구
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    • 제15권2호
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    • pp.5-19
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    • 1999
  • This paper identifies five factors that limited urban network formation in Northeast Asia over the past half millennium, questions the extent to which they are being overcome in the 1990s, and sketches a network of cities that could boost regionalism. It briefly traces the historical evolution of these factors, including comparisons with European integration, while focusing primarily on the policies of the 1990s that have affected their continuing role. First is the factor of closed national markets with weak regional integration. Second is the preeminence of administrative means of integration over commercial ones. Third is the character of localism, shackled by overcentralization and weak cross-border linkages. Fourth is the limited nature of internationalism, dominated by state catch-up policies with one-sided global involvement. Fifth is a lack of regional consciousness. Just as national urban integration was essential for regional networks to form, without regional integration it is difficult to contemplate Northeast Asian cities taking their rightful place in a global urban network. After noting the failures of the 1990s, the paper points to the potential role as dragon's heads for sub-regional urban networks of potential front-line cities: Tumen, Sapporo, Irkutsk, and what I call the Amur triangle. Also of interest are how the capitals of Beijing, Moscow, Seoul, and Tokyo will adjust to a transformed urban network. After all, their current skepticism must be overcome with a program that links the benefits on all sides in order to build trust in regionalism. This requires internationalism and symbols of a balanced approach to each country's needs.

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