• Korean Journal of Metals and Materials
• /
• v.47 no.10
• /
• pp.652-659
• /
• 2009

Many ancient and historical artifacts were made by copper and its alloys. In the case of outdoor exposure artifacts, the surface could be suffered from corrosion and tarnish by the reaction with its environment. In order to preserve the artifacts, surface treatment would be needed and BTA coating has been usually applied to tin-bronze. This paper dealt with the evaluation of the properties of BTA coated film using a linear polarization method and AC impedance measurement. On the base of corrosion rate and film resistance for the specimen formed by coating process, optimum coating conditions are as follows; 3 cycles brushing or 3 cycles spraying coatings for natural dried process and 1 cycle brushing coating or 5 cycles spraying coating for hot-air dried process.

• Journal of the Korean institute of surface engineering
• /
• v.46 no.5
• /
• pp.197-207
• /
• 2013

In the midst of increasing importance of modern cultural assets, especially, most modern bronze objects are exposed to outdoor environment, and as the objects are corroded steadily due to environmental factors the objects lost their original colors on the surface. We performed artificial patinas on the bronze sample per each color of red, black and green and checked cuprite and tenorite which are detected from actual bronze corrosion by analyzing the components. In addition, we applied the existing corrosion removal methods of grinder and sand blaster on a similar sample of bronze mirror per injection pressure and performed comparative analysis on the result with Nd:YAG laser. As a result of Nd:YAG laser cleaning artificial patina from bronze samples, all of the patinas were removed by laser wavelength 1064 nm better than 532 nm. Upon applying to a similar sample of bronze mirror, the artificial patina could be selectively removed from substrates without surface damage when Nd:YAG laser was conducted other than the existing removal method, and so it showed the possibility of application.

• Journal of Conservation Science
• /
• v.33 no.3
• /
• pp.155-165
• /
• 2017

As interest in the public display of art and outdoor sculptures is increasing, the conservation and treatment of these sculptures is becoming increasingly crucial. Long-term exposure to the natural elements and atmospheric pollution can cause corrosion and deterioration in outdoor sculptures. In the case of Kim Chan Shik's "Feeling", which was exhibited in the outdoor sculpture park at the National Museum of Modern and Contemporary Art (MMCA), the patina of the sculpture was damaged during a long outdoor exhibition. Therefore, the treatment process was as follows: recording of condition, sanding, repatination, and wax coating. Consequently, the sculpture was restored similar to the original. Chemical analysis revealed that the sculpture was crafted from bronze and was cast from a quaternary alloy of Cu-Pb-Sn-Zn. The welding is lower in Zn, Sn, and Pb content than the metal used in the sculpture itself. Bright strains contain about 13.0 wt% Sn and 10.5 wt% Pb. The strains are higher in Sn and Pb content than the rest of the metal in the sculpture (7.0 wt% Sn and 4.4 wt% Pb). As a result of component analysis and microstructure observation, the material is estimated to have been made by casting without artificial treatment.

• Journal of Korean Society for Atmospheric Environment
• /
• v.19 no.E2
• /
• pp.51-61
• /
• 2003

The material exposure tests have been carried out since 1993 to evaluate the relationship between air pollution and material corrosion with the cooperation of the researchers in Japan, China, and Korea. The test pieces such as bronze, copper, marble, and carbon steel have been exposed under both unsheltered and rain-sheltered outdoor condition separately at 18 sampling sites in East Asia. At the same time, the concentration of SO$_2$ and NO$_2$ has been measured simultaneously with passive sampler. The meteorological data were collected from the AWS (Auto-mated weather station) In each country and chemical compositions of wet deposition were also analyzed by the bulk sampling of rainfall every month. As the results, it was found that the corrosion rates of test pieces in the ambient air were appeared to be in the order of carbon steel > marble > bronze copper. The corrosion rates of test pieces in the unsheltered outdoor condition were 2.34 to 5.88 times larger than those in rain-sheltered condition. It was also found that the corrosion rate in the heavy polluted area in China was the highest, and the corrosion rates of the metal pieces were generally proportional to SO$_2$ concentration. Between two sites in Korea, the test pieces at Daegu site showed higher corrosion rates that would be due to the higher SO$_2$ concentration.

• Journal of Conservation Science
• /
• v.34 no.4
• /
• pp.259-271
• /
• 2018

Outdoor copper alloy is exposed to the atmospheric environment, accelerating corrosion progress compared with indoor copper alloy. In order to prevent corrosion, the outdoor copper alloy is coated with wax to block external corrosion factors. However, corrosion of the inside of the coating film is highly likely to continue without the internal corrosion prevention treatment. B.T.A, which is used as a copper alloy water-soluble corrosion inhibitor, has a high possibility of being harmful to the human body and is mainly used to treat excavated artifacts. This study had selected the water-soluble corrosion inhibitor, which was easier to use than the existing wax and B.T.A being used in corrosion inhibition treatment for outdoor copper alloy. A comparative study was conducted on B.T.A, which is a water-soluble corrosion inhibitor used on excavated artifacts, and $VCI^{(R)}$, $Rus^{(R)}$, and L-cys, an amino acid corrosion inhibitor, used for tin bronze test pieces. The experimental method was conducted for a certain period of time with the salt, acid, and air pollution affecting the corrosion of outdoor copper alloy. Based on experiment results, it was concluded that the best water - soluble copper alloy corrosion inhibitor in the atmospheric environment is $VCI^{(R)}$. and it could be considered to be applied in replacement of B.T.A due to its low harmfulness. In addition, $VCI^{(R)}$ is judged to serve as a corrosion inhibitor for outdoor copper alloy because it showed the best result even in the outdoor exposure test which is a real atmospheric environment.

• Journal of the Korean Institute of Landscape Architecture
• /
• v.33 no.3 s.110
• /
• pp.43-55
• /
• 2005

Since 1990s, increasing number of public arts have been installed in housing projects in Korea. Most of them were made of granite, bronze and stainless steel and were sculptures as well. Then it resulted in monotony. New technology and community need various Dials in material and genre of Public art. The author wonders if people really want granite sculpture, so started the study of public arts in housing projects. Unfortunately most of people related public art wanted granite sculpture. But there were some hope in survey. They wanted the other genre and material like ceramic wall, art fountain and landmark tower. This means that they care about real world like vandalism and Product Liability, but also want more fantastic and beautiful world in the second step. Recently, the facades of apartments are changing rapidly as more diverse materials in their forms, textures, and colors. And landscape designs are changing their clothes in every second as well. According to these flows public arts in apartments needs more diversified trial within genres and materials to avoid monotonous outdoor.

• Journal of Environmental Science International
• /
• v.11 no.5
• /
• pp.445-454
• /
• 2002

Material exposure experiments were performed to evaluate the relationship between air pollution and material corrosion rates based on collaboration with researchers in China, Japan, and Korea. Qualitative and quantitative atmospheric corrosion was estimated from damage caused to bronze, copper, steel, marble, cedar, cypress, and lacquer plates exposed to outdoor and indoor conditions in certain East Asian cities. The effects of atmospheric and meteorological factors on the damage to the copper plates and marble pieces were estimated using a regression analysis. The results indicated that sulfur dioxide produced the most destruction of the materials, especially in South Korea and China. In Japan, the copper plates were damaged as a result of natural conditions and sea salt. Copper was also found to be damaged by the surface deposition of sulfur and chlorine. Meanwhile, marble was substantially degraded by gaseous sulfur dioxide, yet sulfate ions in rain had no effect. Accordingly, the analysis of air pollution from the perspective of material damage was determined to be very useful in evaluating and substantiating the intensity of air pollution in East Asia.

• Journal of the Korean Institute of Landscape Architecture
• /
• v.39 no.2
• /
• pp.1-9
• /
• 2011

This study concerns the Baekje Traditional Garden, one of the open spaces in the Lotte Resort in the Baekje Historical Reappearance Complex, which is part of the comprehensive plan for specific areas in the Baekje cultural area. The Baekje Traditional Garden has historic value, and its excellent garden style influenced the ancient Japanese gardens. This study dealt with three issues: (1) The context in which Lotte Buyeo Resort accepted the Baekje Traditional Garden, particularly the background and process of such; (2) The original form of the Baekje Traditional Garden; and (3) How the Baekje Traditional Garden should be represented in the open space of the resort. Representation is accomplished in two ways: using the structure of the original garden and in the borrowing of elements. For representation using the structure of the original garden, Imrugak was used as the main entrance space, and Wolsunjung was represented from the Ganbuklee remains. In the rear garden are wave watercourses and other garden facilities of the Wanggungri site in Iksan. Borrowing of elements, on the other hand, was accomplished in the plant plan and detailed development. In addition, mountaintops (three mountains and five mountain summits), a clean stream between mountains, and a pine forest are visualized in the garden. This is the representative landscape of the Taoist hermit world that appeared in the Baekje Gilt Bronze Incense Burner and Landscape pattern. The significance of this study is twofold. First, the Baekje Traditional Garden is a fresh trail because there has been no previous research concerning it. Second, while past research concerning traditional spaces focused on the results of representation, this study focused on the process of representation. This means that this research work tried to extend the study concerning the representation of traditional spaces from the conceptual to the practical approach. This study, however, also has its limitations. The authenticity of the representation suggested in this study may be questioned later because efforts have been made to preserve the original Baekje Traditional Garden. In addition, this study should seek a balance between authenticity on one hand and amusement and diversity of experience on the other, because the site is a resort.