• Title/Summary/Keyword: orientation (property)

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Room-Temperature Deposition of ZnO Thin Film by Pulsed Vacuum Arc and Effect of Oxygen Gas Ratio on Its Electrical Properties (펄스형 진공 아크법에 의한 ZnO 박막의 상온합성 및 이의 전기적 특성에 미치는 산소분압비의 영향)

  • Shin Min-Geun;Byon Eungsun;Lee Sunghun;Kim Do-Geun;Jeon Sang-Jo;Koo Bon Heun
    • Journal of Surface Science and Engineering
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    • v.38 no.5
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    • pp.193-197
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    • 2005
  • Highly c-axis oriented Zinc oxide (ZnO) films were successfully deposited at room temperature by oxygen ion-assisted pulsed filtered vacuum arc. The effect of oxygen gas ratio ($O_{2}/O_{2}+Ar$ on the preferred orientation, surface morphology and resistivity of the ZnO films were investigated. Highly crystalline ZnO films with (002) orientation were obtained at over $13\%$ of oxygen gas ratio. Increasing oxygen gas ratio up to $80\%$ was found to improve crystallinity of the films. From hall measurements, it was found that the film has n-type characteristic and carrier concentration and its mobility were closely related with oxygen gas ratio. Minimal resistivity of $3.6{\times}10^{-3}{\Omega}{\cdot}cm$ was obtained in the range of $20\%$ to $40\%$ of oxygen gas ratio.

Effects of Precursor Concentration and Current on Properties of ZnO Nanorod Grown by Electrodeposition Method (전착법으로 성장된 산화아연 나노막대의 특성에 전구체 농도 및 전착 전류가 미치는 효과)

  • Park, Youngbin;Nam, Giwoong;Park, Seonhee;Moon, Jiyun;Kim, Dongwan;Kang, Hae Ri;Kim, Haeun;Lee, Wookbin;Leem, Jae-Young
    • Journal of Surface Science and Engineering
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    • v.47 no.4
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    • pp.198-203
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    • 2014
  • ZnO nanorods have been deposited on ITO glass by electrodeposition method. The optimization of two process parameters (precursor concentration and current) has been studied in order to control the orientation, morphology, and optical property of the ZnO nanorods. The structural and optical properties of ZnO nanorods were systematically investigated by using field-emission scanning electron microscopy, X-ray diffractometer, and photoluminescence. Commonly, the results show that ZnO nanorods with a hexagonal form and wurtzite crystal structure have a c-axis orientation and higher intensity for the ZnO (002) diffraction peaks. Both high precursor concentration and high electrodeposition current cause the increase in nanorods diameter and coverage ratio. ZnO nanorods show a strong UV (3.28 eV) and a weak visible (1.9 ~ 2.4 eV) bands.

Identification and Optimization of Dominant Process Parameters Affecting Mechanical Properties of FDM 3D Printed Parts (압출적층조형 공정 기반 3D 프린팅 제품 기계적 특성의 지배적 공정인자 도출 및 최적화에 관한 연구)

  • Kim, Jung Sub;Jo, Nanhyeon;Nam, Jung Soo;Lee, Sang Won
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.41 no.7
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    • pp.607-612
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    • 2017
  • Recently, additive manufacturing (AM) technology, also known as 3D printing technology, has attracted attention as an innovative production method to fabricate functional components having complex shapes with saving materials. In particular, a fabrication of poly lactic acid (PLA) parts through a fused deposition modeling (FDM) technique has attracted much attention in the medical field. In this paper, an experimental study on the identification of dominant process parameters influencing mechanical properties of PLA parts fabricated by the FDM process is conducted, and their optimal values for maximizing the mechanical properties are obtained. Three process parameters are considered in this research, namely, layer thickness, a part orientation and in-fill. It is known that thin layer thickness, part orientation diagonal to the tension direction, and full in-fill are optimal conditions to maximize the mechanical properties.

Dielectric and Pyroelectric Prooperties of (Ba,Sr)TiO$_3$ Thin Films Grown by RF Magntron Sputtering (RF 마그네트론 스퍼터링 방법으로 제조한 (Ba,Sr)TiO$_3$ 박막의 유전 및 초전특성)

  • 박재석;김진섭;이정희;이용현;한석룡;이재신
    • Journal of the Korean Ceramic Society
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    • v.36 no.4
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    • pp.403-409
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    • 1999
  • The dielectric and pyroelectric properties of $Ba_{0.66}$$Sr_{0.38}$$TiO_{3}$(BST) thin films growtn on Pt/Ti/NON/Si us-ing RF magnetron sputtering have been investigated. With increasing the substrate temperature during de-position of the BST film in the range of 300-$600^{\circ}C$ the dielectric and pyroelectric constants of the film were increased due to improved crystallinity of the film. In addition the dependence of the microstructural and electrical properties of BST films onthe deposition temperature of the bottom Pt electrode was studied. The preferred orientation of the BST films as well as the microstructure of the Pt film was greatly in-fluenced by the deposition temperature of the bottom Pt electrode was studied. The preferred orientation of the BSt films as well as the microstructure of the Pt film was greatly in-fluenced by the deposition temperature of the bottom Pt electrodes. and thus so were the pyrolelectric pro-perties of the BST film. The highest value of pyroelectric coefficient at room temperature obtained in this work was $nCcm^{-2}K^{-1}$ which is much higher than those previously reported on other perovskite fer-roelectric thin films.

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Utilization of Space based Digital Information for Land Information around the Acreage of a Lot (필지 중심 토지정보화를 위한 공간기반 수치정보의 활용방안)

  • Jung, Dae-Young;Shin, Young-Chul;Jung, Young-June
    • Journal of the Korean Association of Geographic Information Studies
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    • v.8 no.3
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    • pp.11-22
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    • 2005
  • It is necessary to arrange and analyze the collected research date to get regularity such as characteristics, merits and demerits, and possibility in city when constructing land information by analyzing linkage and utilization of cadastral information as the fundamental data for land information around the acreage of a lot and by expressing the purpose of each digital data construction with map. In short, that is the work to classify data, to make chart or map, or to analyze using statistical technique. Some information in land utilization had been used by computerization, but several problems were found in common use of total divisions. The most important problem is, in the case of drawing information, that topographical map with building boundary and land registration map with acreage boundary cannot be used together. In the case of property information, common utilization of property information that is basically needed and standard measurement of usage classification are necessary. The characteristics of the land usage data by the rearrangement of the cadastral information. etc. is presented as the basic data for the land information orientation, and the analyzing result of the data should be expressed and controlled on the map as the fundamental survey for the establishment of the land information oriented planning supports the physical space planning of the land cadaster finally. In this research, the problem in establishing current land information around acreage of a lot was found to research data to be needed in land information for utilizationof space based digital information, and was studied the method in relation to GIS.

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Effects of Slope Orientation and Altitude on the Forage Yield and Botanical Composition of Alpine Pasture (고산지대초지의 사향지별 및 표고별 차이에 따른 수량과 식생변화에 관한 연구)

  • 김동암;김희경;권찬호;조무환;이종경
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.11 no.4
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    • pp.236-243
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    • 1991
  • A field experiment was conducted during the growing season of 1985 to determine the effects of slope orientation, north and south facing exposures and three different altitudes, 800, 1,000 and 1,200m a.s.1. on the dry matter yield, forage quality and botanical composition of alpine pasture. 1. Total dry matter yield of alpine pasture was influenced by slope orientation and altitude. An average forage yield of both exposures at 1,000m a.s.1. was 9,301kg/ha compared with 10,274kg/ha at 800m a.s.1. and the productivity express in relative percentage decreased by 9.5% per 200m attitudinal increase. 2. An average forage yield of both altitudes, 800 and 1,000m a.s.1. on the south facing exposure was 21.5% higher than that on the north exposure. 3. Crude protein concentration of forage grown on both exposures was lowest at 800m a.s.1. increasing gradually as the altitude increased, but crude fiber concentration decreaced in a manner opposite to that of crude protein. 4. Forage grown on the north facing exposure had a higher concentration of crude protein than that grown on the south facing exposure at the same altitude, but lower concentraion of crude fiber. 5. Orchardgrass and timothy were two main species on both exposures at 800m a.s.1. but timothy was only dominant species at 1,000 and 1,200m a.s.1. and performed well up to 1,200m a.s.1. in alpine area. The economic production limit of orchardgrass would be about 800m a.s.1. in the alpine pasture. 6. No soil property differences were found between the north and south facing exposures as well as three different altitudes in the alpine pasture. It seemed that the previous pasture fertilization of the experimental field completely overshadowed any soil property differences from slope orientation and altitude.

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Effect of the hetero-epitaxial ZnO buffer layer for the formation of As-doped ZnO thin films (Hetero-epitaxial ZnO 버퍼층이 As-doped ZnO 박막의 증착조건에 미치는 영향)

  • Lee, Hong-Chan;Choi, Won-Kook;Shim, Kwang-Bo;Oh, Young-Jei
    • Journal of Sensor Science and Technology
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    • v.15 no.3
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    • pp.216-221
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    • 2006
  • ZnO thin films prepared by PLD method exhibit an excellent optical property, but may have some problems such as incomplete surface roughness and crystallinity. In this study, undoped ZnO buffer layers were deposited on (0001) sapphire substrates by ultra high vacuum pulse laser deposition (UHV-PLD) and molecular beam epitaxy (MBE) methods, respectively. After post annealing of ZnO buffer layer, undoped ZnO thin films were deposited under different oxygen pressure ($35{\sim}350$ mtorr) conditions. The Arsenic-doped (1, 3 wt%) ZnO thin layers were deposited on the buffer layer of undoped ZnO by UHV-PLD method. The optical property of the ZnO thin films was analyzed by photoluminescence (PL) measurement. The ${\theta}-2{\theta}$ XRD analysis exhibited a strong (002)-peak, which indicates c-axis preferred orientation. Field emission-scanning electron microscope (FE-SEM) revealed that microstructures of the ZnO thin films were varied by oxygen partial pressure, Arsenic doping concentration, and deposition method of the undoped ZnO buffer layer. The denser and smoother films were obtained when employing MBE-buffer layer under lower oxygen partial pressure. It was also found that higher Arsenic concentration gave the enhanced growing of columnar structure of the ZnO thin films.

Studies on the Oxygen Permeability and It's Proofness of the Various Commercial Polymer Films (상업용 고분자 필름의 산소투과도 및 산소투과 방지도에 관한 연구)

  • Suh, Hwan-Kyu;Kim, Joon-Soo;Lee, Jung-Keun
    • Elastomers and Composites
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    • v.15 no.1
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    • pp.3-9
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    • 1980
  • The oxygen permeability and it's proofness of te various commercial polymer films have been investigated at the constant pressure and temperature. Oxygen proofness, the reciprocals of the oxygen permeability for the various samples, were determined by means of a coulometric oxygen permeability tester. The testing of sample films was performed at constant temperature $(23{\pm}1^{\circ}C)$ under 1 atm. for 24 hours. The order of the relative proofness observed are as follows; oriented Nylon (O. Nylon)> oriented Polyester (O. PET)>nonoriented Nylon (N. Nylon)>nonoriented Polyester (N.PET)> rigid Polyvinyl chloride (Rigid PVC)>semirigid Polyvinyl chloride (Semirigid PVC)> oriented Polypropylene (O. PP)>plasticized Polyvinyl chloride (P. PVC)> casted Polypropylene (C. PP)> low density Polyethylene (LDPE)>high density Polyethylene (HDPE, Inflation)> high density-polyethylene (HDPE, T-die) The oxygen proofness of the films was increased with the polarity cf polymer, the film thickness and mechanical orientation and decreased with the addition of plasticizer in PVC. For the use of wrapping materials, one film with the polar property in the main chain of the polymer molecule and the others with nonpolar property in it are laminated for the protection from oxygen and moisture.

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Hydrogen Post-annealing Effect of (Pb0.72,La0.28)Ti0.93O3 Films Fabricated by Pulsed Laser Deposition (펄스레이저 증착법으로 제작된(Pb0.72,La0.28)Ti0.93O3박막의 수소후열처리에 관한 전기적 특성 연구)

  • 한경보;전창훈;전희석;이상렬
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.3
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    • pp.190-194
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    • 2003
  • Dielectric thin films of (P $b_{0.72}$,L $a_{0.28}$) $Ti_{0.93}$ $O_3$ (PLT(28)) have been deposited on Pt(111)/Ti/ $SiO_2$/Si(100) substrates in-situ by pulsed laser deposition using different annealing and deposition Processes. We have investigated the effect of hydrogen annealing on the ferroelectric properties of PLT thin films and found that the annealing process causes the diffusion of hydrogen into the ferroelectric film resulting in the destruction of polarization. We have tried to form the film by a two-step deposition process In order to improve electrical property. Two-step process to grow PLT films was adopted and verified to be useful to enlarge the grain size of the film and to reduce the leakage current characteristics. Structural properties and electrical properties including dielectric constant, ferroelectric characteristics, and leakage current of PLT thin films were shown to be strongly influenced by grain size. The film deposited by using two-step Process including pre-annealing treatment has a strongly(111) orientation. However, the films deposited by using single -step process with hydrogen annealing process show the smallest grain size. The film deposited by using two-step process including pre-annealing treatment shows the leakage current density of below 10$^{-7}$ A/c $m^2$ for the field of smaller than 100 kV/cm. However, the films deposited by using single-step process with hydrogen annealing process and pre-annealing process show worse leakage current density than the film deposited by using two-step process including pre-annealing treatment.tment.

Property and Surface Morphology of Copper Foil on the Various Temperature of Electrolyte (전해액 온도에 의한 구리 박막의 표면형상과 물성 변화)

  • Woo, Tae-Gyu;Lee, Man-Hyung;Park, Eun-Kwang;Bae, Tea-Sung;Lee, Min-Ho;Park, Il-Song;Jung, Kwang-Hee;Seol, Kyeong-Won
    • Korean Journal of Metals and Materials
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    • v.47 no.4
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    • pp.256-260
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    • 2009
  • This study examined the effects of plated temperature on the surface morphology and property of an electrodeposited copper foil. The morphology, crystal structure and electric characteristics of the electrodeposited copper foil were examined by scanning electron microscopy, X-ray diffraction, and a four-point probe, respectively. The surface roughness, crystal growth orientation and resistivity could be controlled using various temperature of electrolyte. Large particles were observed on the surface of the copper layer electroplated onto the $30^{\circ}C$. However, a uniform surface, lower resistivity and high flexibility were obtained when a $50^{\circ}C$ electrolyte was used.