• Polymer(Korea)
• /
• v.25 no.5
• /
• pp.719-727
• /
• 2001

Recently it was found that the charge carrier transport properties are significantly enhanced due to effective intermolecular $\pi$-orbital overlapping and low disorder of hopping sites caused by self-organization of liquid crystal molecules. In this study, the xerographic properties of a double-layer photoconductor doped with nematic liquid crystal, 4-pentyl-4'-cyanoterphenyl (5CT), as a charge-carrier transport material to enhance the charge-tarrier mobility were investigated. From the results of measured surface voltage properties for the photoconductor doped with various concentrations of liquid crystal, 5CT, the initial voltage was found to increase with the concentration of 5CT and the dark decay decreased with the concentration of 5CT. The highest sensitivity was obtained at a specific concentration, 40wt% 5CT. The fluorescence behavior of the carrier transport layer (CTL) was also investigated. It was found that the charge-carrier transport properties of the organic photoconductor depend on the charge-carrier transport properties of the complex. The TNF : 5CT (40 wt%) and OXD : 5CT (40 wt%)samples showed the highest sensitivity because the greatest charge transport complex was termed between the charge-carrier transport materials in these samples.

• Journal of the Korean Graphic Arts Communication Society
• /
• v.12 no.1
• /
• pp.107-131
• /
• 1994

• Progress in Superconductivity
• /
• v.4 no.2
• /
• pp.99-103
• /
• 2003

We studied the nonequilibrium superconductivity due to tunnel injection of polaronic quasiparticle (QP) from organic photoconductor. The transport properties of an organic copper (II) phthalocyanine (Cu -Pc)/d-wave superconductor were investigated in dark and under ultraviolet (UV) radiation for performance of a novel $high -T_{c}$ superconducting three terminal device. We observed that the injection of polaronic QP from the organic Cu -Pc film into the $Bi_2$S $r_2$$CaCuO_{8+{\delta}}$ film generated a substantially larger nonequilibrium effect as compared to the normal QP injection current. We could increase the current gain by UV excitation of the organic photoconductor injector. The tunneling spectroscopy of a Cu -Pc/BSCCO junction exhibited a small enhancement of the zero bias conductance peak under the W excitation. The above phenomena are of importance in developing optically controlled three terminal superconducting device.e.

• Korean Journal of Materials Research
• /
• v.9 no.5
• /
• pp.473-477
• /
• 1999

Xerographic properties of double-layer photoconductor doped with 4-butyl-4'-methoxyazobenzene (BMAB) as charge-carrier transport material were investigated. BMAB can undergo reversible trans-cis isomerization by light with appropriate wavelength. In the results of measured surface voltage properties for photoconductor doped with BMAB, TNF: BMAB(4-wt%) sample with trans form showed the lowest dark decay, the lowest residual voltage, and the highest sensitivity among cis form. The trans isomer of BMAB has ordering orientation because the molecule possesses a rodlike shape, while the cis isomer has random orientation due to its bent shape. Therefore the molecular arrangement of trans form enhanced charge-carrier transport mobility.

• Journal of the Korean Graphic Arts Communication Society
• /
• v.16 no.3
• /
• pp.43-60
• /
• 1998

The photosensitive properties and spectroscopic characteristics in the organic photoconductor(OPC) with carrier generation layer(CGL) of poly(vinylbutyral)(PVB) and polycarbonate(PC) doped with titanyl phthalocyanine(TiOPc) were investigated. The change of crystal structure of TiOPc dispersed with PVB and PC was shown by UV-visible reflective spectrum and FT-IR spectrum and mainly caused by the difference of solubility of solvent and the interaction between TiOPc and binder. The particle size of TiOPc dispersed with PVB measured by SEM was smaller than in PC. The crystal structure of TiOPc dispersed with PVB was amorphous type and in PC was $\alpha$type. It was found that the photosensitive properties of OPC were dependent on the change of absorbance and ionization potential of TiOPc occurred from the difference of crystal structure. In this work, the photosensitivity of OPC of TiOPc dispersed with PVB was better than PC due to the crystal type and the smaller particle size.

• Journal of the Korean Graphic Arts Communication Society
• /
• v.9 no.1
• /
• pp.27-44
• /
• 1991

In this research, double-layered photoconductor consist of the carrier generation layer(CGL) of ${\varepsilon}$ type copper phthalocyanine thin film by an aqueous coating method and the carrier transport layer(CGL) of polyvinyl carbazol(PVK) by spin coating. We inverstigated effect of the surfactant solution and cathod electrolysis to the crystal type of ${\varepsilon}$-CuPc in CGL with TEM, SEM and X-ray diffraction spectroscopy and studied the mechanism of an aqueous coating for the preparation of CGL. The effect of the washing of CGL about the electrophotographic characteristics of the ${\varepsilon}$-CUPC/PVK double-layered photoconductors is studied also.

• Journal of the Korean Graphic Arts Communication Society
• /
• v.15 no.1
• /
• pp.97-109
• /
• 1997

In this work, appearance part of dot gain, and relationship between ton jump and dot gain was studied using the round dot, the square dot, the line dot and the elliptical dot. Each dot pattern were different that was the conners of the round dot touch at 78%, the corners of the square dot and the line dot touch at 100% and the corners of the elliptical dot touch at approximately 40~60%. The result of this work, when the corners join between dots take place tone scale jump and dot gain, and different position of dot gain in each dot patterns.

• Journal of the Korean Graphic Arts Communication Society
• /
• v.15 no.1
• /
• pp.71-83
• /
• 1997

In recent years, various kinds of organic photoreceptors have been used for copy machines based on electrophotography. Most of them are constructed into layered devices in which a photogeneration layer is separated from a charge transport layer. They are usually used with application of negative charges. Organic pigment have received considerable attention with phthalocyanine, squaraine, and azo compounds being used to construct zerograpgic photoreceptors with enhanced long wavelength sensitivity, residual potential and zerograpgic gain of squaraine photoconductor were measured from the photoinduced discharge curve. Most of synthesized squaraine derivative couldn`t use for CGM(charge generation material), but it knew that a part of one was able to use it within the possibility. A few appliance is used it know about dependence on CTM(charge transport material) of squaraine derivative. It could know that experiment`s result is 2.5-bis(4-N-N`-diethylaminophenyl)-1,3,4-oxadiazole(OXD) is the bestproduct.

• Journal of the Korean Graphic Arts Communication Society
• /
• v.12 no.1
• /
• pp.1.1-11
• /
• 1994

The photosensitive properties and carrier transport in the organic photoconductor with the carrier transport layers(CTL) of polymer matrix doped with two carrier transport materials above carrier generation layer(CGL) containing oxotitanium phthalocyanine (TiOPc) were investigated. The CGL of TiOPc dispersed in poly(vinylbutyral) was formed as thickness of 0.1${\mu}{\textrm}{m}$and the carrier transport layer was prepared by coating polycarbonate and polyester doped with oxadiazoly(OXD), polyvinylcarbazole (PVK), trinitro fluorenone(TNF) as thickness of 10~15${\mu}{\textrm}{m}$, respectively. We have measured half decay exposure,sensitivity and xerographic gain from the photo-induced discharge curve(PIDC). In this work, it was found that the characteristics of carrier transport were mainly caused by the ionization potential difference of constitutive materials in molecularly doped polymer.