• Title/Summary/Keyword: organic additives

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Organic Additives effect affected on the Property of Electrodeposited copper foil (전해동박의 특성에 미치는 유기 첨가제 효과)

  • Lee, K.W.;Rho, S.S.;Choi, C.H.;Kim, S.K.;Son, S.H.;Moon, H.K.;Park, D.H.
    • Proceedings of the KIEE Conference
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    • 2001.07c
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    • pp.1540-1542
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    • 2001
  • In this paper, the amount of additives in the electrode were investigated the relation of the mechanical properties and surface luminance of copper foil. Especially, organic compound of PEG(Poly-ethylene Glycol) was added from 1 to 20ppm for the propose of increasing the mechanical property and the surface state. The surface luminance of copper foil is appealed 69.25 at 2ppm-15A/$dm^2$ and 68.25 at 2ppm-10A/$dm^2$. It guess that 10ppm-10A/$dm^2$ occurred pin-hole. Tensile strength was not showed the significant difference but elongation appealed the most value at 5ppm-15A. We earned that the most PEG value of mechanical properties is 5 PPM.

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Critical Current Density Improvement of Superconducting YBCO Thick Film by using EPD Additives (전착 첨가물에 의한 전기영동 초전도 YBCO 후막선재의 임계전류밀도 개선)

  • Soh, Dea-Wha;Lim, Byong-Jae;Jeon, Yong-Woo;Park, Jung-Cheul;Choi, Sung-Jai
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07a
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    • pp.123-126
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    • 2003
  • The electrophoretic deposition method using the suspension solution with additives under the electric potential was applied for the fabrication of YBCO superconductor wire. This method was able to simplify the fabrication facilities, and produce an uniform and dense thick film. To improve the critical current density of deposited films, the additive PEGs(Poly Ethylene Glycole) with the molecular weight of 600, 1000 and 3400, were used as chemical binders for the suspension solution. The organic additive PEG showed better effects to the properties of YBCO superconductor wire. The PEG improved the adhesion between superconductor particles and suppressed the crack on the surface, which enhanced the surface uniformity and density of YBCO deposited film. It was found that acetone suspension solution showed better deposition properties than the others. The samples fabricated in the solution with the additive, 8 vol.% of 1% PEG(1000), showed the highest critical current density measured as $2300{\sim}2400\;Acm^2$ at 77 K, 0 T.

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Surface Reflectance Reduction of Multicrystalline Silicon Wafers for Solar Cells by Acid Texturing (Acid Texturing에 의한 태양전지용 다결정 실리콘 기판의 표면 반사율 감소)

  • Kim, Ji-Sun;Kim, Bum-Ho;Lee, Soo-Hong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.2
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    • pp.99-103
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    • 2008
  • To improve efficiency of solar cells, it is important to make a light trapping structure to reduce surface reflectance for increasing absorption of sun light within the solar cells. One of the promising methods that can reduce surface reflectance is isotropic texturing with acid solution based on hydrofluoric acid(HF), nitric acid($HNO_3$), and organic additives. Anisotropic texturing with alkali solution is not suitable for multicrystalline silicon wafers because of its different grain orientation. Isotropic texturing with acid solution can uniformly etch multicrystalline silicon wafers unrelated with grain orientation, so we can get low surface reflectance. In this paper, the acid texturing solution is made up of only HF and $HNO_3$ for easy controlling the concentration and low cost compared to acid solution with organic additives. $HNO_3$ concentration and dipping time were varied to find the condition of minimum surface reflectance. Textured surfaces were observed Scanning Electron Microscope(SEM) and surface reflectance were measured. The best result of arithmetic mean(wavelength from 400 nm to 1000 nm) reflectance with acid texturing is 4.64 % less than alkali texturing.

Investigation of Surface Reflectance Reduction for Multicrystalline Silicon Solar Cells with Acid Texturing (Acid Texturing에 의한 다결정 실리콘 태양전지의 표면 반사율 감소에 대한 연구)

  • Kim, Ji-Sun;Kim, Bum-Ho;Lee, Eun-Joo;Lee, Soo-Hong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.16-17
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    • 2007
  • To improve efficiency of solar cells, it is important to make a light trapping structure to reduce surface reflectance for increasing absorption of sun light within the solar cells. One of the promising methods that can reduce surface reflectance is isotropic texturing with acid solution based on hydrofluoric acid(HF), nitric acid($HNO_3$), and organic additives. Anisotropic texturing with alkali solution is not suitable for multicrystalline silicon wafers because of its different grain orientation. Isotropic texturing with acid solution can uniformly etch multicrystalline silicon wafers unrelated with grain orientation, so we can get low surface reflectance. In this paper, the acid texturing solution is made up of only HF and $HNO_3$ for easy controling the concentration and low cost compared to acid solution with organic additives. $HNO_3$ concentration and dipping time were varied to find the condition of minimum surface reflectance. Textured surfaces were observed Scanning Electron Microscope(SEM) and surface reflectance were measured. The best result of arithmetic mean(wavelength from 400nm to 1000nm) reflectance with acid texturing is 4.64% less than alkali texturing.

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A study on the efficacy of low viscous nanosized biopolymer on the mechanical and hydraulic properties of organic silt

  • Govindarajan Kannan;Evangelin Ramani Sujatha
    • Geomechanics and Engineering
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    • v.34 no.3
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    • pp.221-231
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    • 2023
  • Biopolymer stabilization is a sustainable alternative to traditional techniques that cause a lesser negative impact on the environment during production and application. The study aims to minimize the biopolymer dosages by sizing the bio-additives to the nanoscale. This study combines the advantages of bio and nanomaterials in geotechnical engineering applications and attempts to investigate the behaviour of a low viscous biopolymer, nano sodium carboxymethyl cellulose (nCMC), to treat organic soil. Soil is treated with 0.25%, 0.50%, 0.75% and 1.00% of nano-bio additive, and its effect on the plastic behaviour, compaction characteristics, strength, hydraulic conductivity (HC) and compressible nature are investigated. The strength increased by 1.68 times after 90 days of curing at a dosage of 0.5% nCMC through the formation of gel threads connecting the soil particles that stiffened the matrix. The viscosity of 1% nCMC increased exponentially, deterring fluid flow through the voids and reduced the HC by 0.85 times after curing for 90 days. Also, beyond the optimum dosage of 0.50%, the nCMC forms a film around the soil particles that inhibits the inter-particle cohesion causing a reduction in strength. Experimental results show that nCMC can effectively substitute conventional additives to stabilize the soil.

Effects of Feeding Nattokinase as Natural Feed Additives on Milk Production and Blood Metabolites in Lactating Dairy Cows (천연 사료첨가제 Nattokinase 공급에 따른 젖소의 산유능력 및 혈액성상에 미치는 영향)

  • Lim, Dong-Hyun;Park, Joong-Kook;Kim, Hyeon-Shup;Ki, Kwang-Seok;Lee, Hyun-June;Kwon, Eung-Gi;Kim, Mi-Kyoung;Kim, Chang-Hyun;Kim, Sang-Bum
    • Korean Journal of Organic Agriculture
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    • v.19 no.4
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    • pp.553-563
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    • 2011
  • This experiment was conducted to determine the effect of nattokinase (NK) additives on milk production and composition, and blood metabolites in dairy cows. The two kinds of nattokinase with high fibrinolytic activity were produced by two strains of bacteria, Bacillus amyloliquefacines (NK1) and Bacillus subtilis (NK2). Total fifteen Holstein cows (average $1.83{\pm}0.37$ parity; average milk yield $23.2{\pm}3.2$ kg/d) were randomly assigned to three treatments (5 animals per treatment). Cows were fed TMR supplemented with 0g, 100g and 100g for control, NK1 and NK2 treatment, respectively for 4 weeks. Milk yield was significantly higher (p<0.05) for NK1 (22.89 kg/d) than for control (21.07 kg/d) and NK2 (21.36 kg/d). Somatic cell counts in NK treatments were significantly lower than that in control group (58,000 vs. 21,000 and 35,000 cells/ml, control vs. NK1 and NK2). Serum ALT levels in all treatment were similar to the range of 32.00~35.83 IU/L, but AST levels in NK1 (85.67 IU/L) was significantly decreased compared with those in control and NK2 (121.67 and 117.67 IU/L respectively). Serum T-CHO levels in NK1 (145.33 mg/dl) was significantly decreased (p<0.05) compared with that in control (179.00 mg/dl) and NK2 (176.17 mg/dl). This finding showed that NK1 additives could possibly have a positive effect in lactation performance of mid-lactation dairy cows by increasing milk yield, reducing somatic cell count, improving liver function and decreasing cholesterol in blood.

Preparation and characterization of SRF(Solid Refuse Fuel) using heavy oil fly ash (중유회를 활용한 고형연료 제조 및 특성)

  • Min, Hong;Cho, Sung-su;Seo, Minhye;Lee, Soo-Young;Choi, Changsik
    • Journal of the Korea Organic Resources Recycling Association
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    • v.27 no.4
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    • pp.83-90
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    • 2019
  • In this study, the characteristics of the SRF (Solid Refuse Fuel) prepared by blending each of the additives (citrus peel, waste wood, coal) in the heavy oil fly ash, evaluating the heavy oil fly ash recyclability. Recycling SRFs were fabricated by pellet extruding method after blending the heavy oil fly ash and additives based on 30% moisture content. As a result, the formability of the SRFs was excellent under condition of blending heavy oil fly ash with coal or citrus peel and the highest calorific value was 4,274 kcal/kg at heavy oil fly ash mixed with coal. Therefore, the formability and calorific value were improved when the heavy oil fly ash was mixed with coal(20 wt%) at 30% moisture content. From these results, the applicability of SRFs with additives was confirmed by using the heavy oil fly ash from J thermal power plant.

The Effects of Levelers on Electrodeposition of Copper in TSV Filling (TSV 필링 공정에서 평활제가 구리 비아필링에 미치는 영향 연구)

  • Jung, Myung-Won;Kim, Ki-Tae;Koo, Yeon-Soo;Lee, Jae-Ho
    • Journal of the Microelectronics and Packaging Society
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    • v.19 no.2
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    • pp.55-59
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    • 2012
  • Defects such as voids or seams are frequently found in TSV via filling process. To achieve defect-free copper via filling, organic additives such as suppressor, accelerator and leveler were necessary in a copper plating bath. However, by-products stemming from the breakdown of these organic additives reduce the lifetime of the devices and plating solutions. In this research, the effects of levelers on copper electrodeposition were investigated without suppressor and accelerator to lower the concentration of additives. Threelevelers(janus green B, methylene violet, diazine black) were investigated to study the effects of levelers on copper deposition. Electrochemical behaviors of these levelers were different in terms of deposition rate. Filling performances were analyzed by cross sectional images and its characteristics were different with variations of levelers.

A Study on the Micellization of Sodium Dodecyl Sulfate in 𝜔-Phenylakylammonium Salt Solution (𝜔-Phenylalkylammonium Salt의 수용액에서 Sodium Dodecyl Sulfate의 미셀에 관한 연구)

  • Ryu, Yeanho;Oh, Jung Hee
    • Applied Chemistry for Engineering
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    • v.8 no.6
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    • pp.1041-1047
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    • 1997
  • The influence of $\omega$-phenylalkylammonium salt on the critical micelle concentration (CMC) of SDS has been examined using the electric conductivity method. CMC of SDS exhibited the tendency to decrease with the length of alkyl group of additives. The effect of temperature on CMC of SDS in additive solutions has been observed in the range of $18^{\circ}C-50^{\circ}C$. The free energy(${\Delta}G_m^{\circ}$) for the micellization of SDS is negative and the entropy(${\Delta}S_m^{\circ}$) is a large positive value. The enthalpy(ΔHm0is positive in low temperature($18^{\circ}C$) and negative in high temperature($>25^{\circ}C$). In the prensence of organic additives, the micellization of SDS was considered as a spontaneous process and to involve a phase transition. The values of ΔGm0has shown the tendency to increase but the values of ${\Delta}S_m^{\circ}$ and ${\Delta}H_m^{\circ}$ to decrease with the length of alklyl group of additive salts. The changes in ${\Delta}\kappa$(difference of specific conductivity) with increasing mole ratio of additives in the mixed solutions indicated the formation of mixed micelles between SDS and additives. The effect of the length of alkyl chain on the micellization of SDS demonstrated the penetration of organic additives into the palisade layer of the SDS micelle.

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Characteristics of Crystallinity and Morphology of Barium Titanate Particles Prepared by Spray Pyrolysis (분무열분해 공정에 의해 합성된 바륨 티타네이트 분말의 결정화 및 형태 특성)

  • Lee, Kyo Kwang;Jung, Kyeong Youl;Kim, Jung Hyun;Koo, Hye Young;Ju, Seo Hee;Kang, Yun Chan
    • Korean Chemical Engineering Research
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    • v.43 no.4
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    • pp.517-524
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    • 2005
  • Barium titanate ($BaTiO_3$) particles were prepared by spray pyrolysis from spray solution containing organic additives. The effects of the type and amount of organic precursors on the crystal structure and morphology of the $BaTiO_3$ particles were investigated. It was found that the morphology of $BaTiO_3$ particles before and after calcination depended on the type of organic additives such as citric acid, ethylene glycol and polyethylene glycol. Among these organic additives, citric acid was the most effective to prepare $BaTiO_3$ particles with nano-structured morphology consisting with uniform size nanometer particles after calcination. It was also found that the phase transformability of the metastable cubic phase to the tetragonal one during calcination could be improved by increasing the content of citric acid in the spray solution. As a result, $BaTiO_3$ particles prepared from spray solution containing high concentration of citric acid had good tetragonality, uniform and fine size, and high BET surface area after calcination. $BaTiO_3$ particles prepared by spray pyrolysis had nanometer size and uniform morphology after simple ball milling process.