• 제목/요약/키워드: optimal mixture gas

검색결과 65건 처리시간 0.03초

Optical Properties of Multi-layer TiNO/AlCrNO/Al Cermet Films Using DC Magnetron Sputtering

  • Han, Sang-Uk;Park, Soo-Young;Kim, Hyun-Hoo;Jang, Gun-Eik;Lee, Yong-Jun
    • Transactions on Electrical and Electronic Materials
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    • 제16권5호
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    • pp.280-284
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    • 2015
  • Among many the oxynitrides, TiNO and AlCrNO, have diverse applications in different technological fields. We prepared TiNO/AlCrNO/Al thin films on aluminum substrates using the method of dc reactive magnetron sputtering. The reactive gas flow, gas mixture, and target potential were applied as the sputtering conditions during the deposition in order to control the chemical composition. The multi-layer films have been prepared in an Ar and O2+N2 gas mixture rate. The surface properties were estimated by performing scanning electron microscopy (SEM). At a wavelength range of 0.3~2.5 μm, the exact composition and optical properties of thin films were measured by Auger electron spectroscopy (AES) and Ultraviolet-visible-near infrared (UV-Vis-NIR) spectrophotometry. The optimal absorptance of multi-layer films was exhibited above 95.5% in the visible region of the electromagnetic spectrum, and the reflectance was achieved below 1.89%.

300 kHz 조건에서의 초음파화학적 산화반응에 대한 연속식 가스 주입 효과 (Effect of Gas Sparging on Sonochemical Oxidation in a 300 kHz Sonoreactor)

  • 서지은;손영규
    • 한국물환경학회지
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    • 제34권6호
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    • pp.642-649
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    • 2018
  • The effect of gas sparging on sonochemical oxidation was investigated in a 300 kHz sonoreactor under various liquid height/volume conditions ($5{\sim}30{\lambda}$, 3.4 ~ 9.0 L), determined by the wavelength of the applied frequency. The electrical input power was maintained constant for all cases . Sonochemical activity drastically decreased from $15{\lambda}$ and the liquid height of $10{\lambda}$ was suggested as the optimal height for 300 kHz without gas sparging. In our previous research, the sonochemical activity observed was five-times higher when air sparging was applied for 36 kHz. On the other hand, no enhancement was obtained at 10, 15, 25 and $30{\lambda}$ using air sparging (1, 3, and 6 L/min) for 300 kHz in this study $20{\lambda}$ and optimization of gas sparging was conducted at $20{\lambda}$ using various gases including air, Ar, $O_2$, $N_2$, and mixtures of Ar and $O_2$. It was found that gas sparging using pure Ar or pure $O_2$ resulted in lower sonochemical activity compared to that of air sparging due to the imbalance between the intensity of cavitation phenomena and the generation of oxidizing radical species. Consequently, the gas mixture of $Ar:O_2$ = 80 % : 20 % (DO saturation ${\approx}100%$) was suggested as an optimal gas sparging condition.

회전식 화학증착 장치 내부의 유동해석을 통한 최적 유량 평가 (COMPUTATIONAL ASSESSEMENT OF OPTIMAL FLOW RATE FOR STABLE FLOW IN A VERTICAL ROTATING DISk CHEMICAL VAPOR DEPOSITION REACTOR)

  • 곽호상
    • 한국전산유체공학회지
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    • 제17권1호
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    • pp.86-93
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    • 2012
  • A numerical investigation is conducted to search for the optimal flow rate for a rotating-disk chemical vapor decomposition reactor operating at a high temperature and a low pressure. The flow of a gas mixture supplied into the reactor is modeled by a laminar flow of an ideal gas obeying the kinetic theory. The axisymmetric two-dimensional flow in the reactor is simulated by employing a CFD package FLUENT. With operating pressure and temperature fixed, numerical computations are performed by varying rotation rate and flow rate. Examination of the structures of flow and thermal fields leads to a flow regime diagram illustrating that there are a stable plug-like flow regime and a few unfavorable flow regimes induced by mass unbalance or buoyancy. The criterion for sustaining a plug-like flow regime is discussed based on a theoretical scaling argument. Interpretation of the flow regime map suggests that a favorable flow is attainable with a minimum flow rate at the smallest rotation rate guaranteeing the dominance of rotation effects over buoyancy.

실험계획법에 의한 진공유리의 모서리부 최적 접합공정조건 결정 (Determination on the Optimal Sealing Conditions of the Vacuum Glass Edge Parts using Design of Experiments Technique)

  • 이종곤;전의식;김영신;박호
    • 한국생산제조학회지
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    • 제21권1호
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    • pp.40-45
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    • 2012
  • The glass edge sealing is one of the vacuum glazing core manufacturing process and it needs the high reliability for the vacuum keeping. Conventionally, the glass edge sealing had been being researched by the method that pasted the flit on the glass edge part and bonded two sheets of glass. But this way has the defect that can't make tempered glass. In order to remedy it's faults, in this paper, the glass edge was sealed by using the hydrogen mixture gas torch within the furnace. The parameter having an effect on the glass edge sealing through the basic test was set. And the correlation of the thickness of the glass edge and parameter were analyzed through the design of experiment. By using the Taguchi method, the optimal process condition for the glass edge sealing was drawn and the validity was verified.

Effects of Replacement of Concentrate Mixture by Broccoli Byproducts on Lactating Performance in Dairy Cows

  • Yi, X.W.;Yang, F.;Liu, J.X.;Wang, J.K.
    • Asian-Australasian Journal of Animal Sciences
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    • 제28권10호
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    • pp.1449-1453
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    • 2015
  • The objective of the present study was to determine the effects of feeding pelletized broccoli byproducts (PBB) on milk yield and milk composition in dairy cows. In Trial 1, an in vitro gas test determined the optimal replacement level of PBB in a concentrate mixture in a mixed substrate with Chinese wild ryegrass hay (50:50, w/w) at levels of 0, 10%, 20%, 30%, or 40% (dry matter basis). When the concentrate was replaced by PBB at a level of 20%, no adverse effects were found on the gas volume or its rate constant during ruminal fermentation. In trial 2, 24 lactating cows (days in milk = $170.4{\pm}35$; milk yield = $30{\pm}3kg/d$; body weight = $580{\pm}13kg$) were divided into 12 blocks based on day in milk and milk yield and randomly allocated to two dietary treatments: a basic diet with or without PBB replacing 20% of the concentrate mixture. The feeding trial lasted for 56 days; the first week allowed for adaptation to the diet. The milk composition was analyzed once a week. No significant difference in milk yield was observed between the two groups (23.5 vs 24.2 kg). A significant increase was found in milk fat content in the PBB group (p<0.05). Inclusion of PBB did not affect milk protein, lactose, total solids or solids-not-fat (p>0.05). These results indicated that PBB could be included in dairy cattle diets at a suitable level to replace concentrate mixture without any adverse effects on dairy performance.

Effect of H2 on Formation Behavior of Carbon Nanotubes

  • Chung, Uoo-Chang
    • Bulletin of the Korean Chemical Society
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    • 제25권10호
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    • pp.1521-1524
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    • 2004
  • The effect of $H_2$ gas on the carbon nanotubes (CNTs) synthesis with CO-$H_2$ gas mixture was investigated using mass measurements and scanning electron microscopy (SEM). The maximum weight and yield of the synthesized carbon were obtained when the mixture ratio of $H_2$: CO was 3 : 7 and 9 : 1, respectively. In case of 100% carbon monoxide (CO) without hydrogen ($H_2$) addition, the weight of carbon increased, but CNTs were not observed. The CNTs began to be made when the contents of $H_2$ reaches at least 10%, their structures became more distinct with an increase of $H_2$ addition, and then the shapes of CNTs were more thin and straight. When the contents of $H_2$ was 80% ($H_2$ : CO = 8 : 2), the shapes and growth of CNTs showed an optimal condition. On the other hand, when the contents of $H_2$ was higher than the critical value, the shapes of CNTs became worse due to transition into inactive surface of catalyst. It was considered that the inactive surface of catalyst resulted from decrease of carbon (C) and $H_2$ concentration by facilitation of methane ($CH_4$) gasification reaction (C + 2$H_2$ ${\rightarrow}$ $CH_4$) between C and $H_2$ gases. It was also found that H2 addition had an influence considerably on the shape and structure of CNTs.

디젤 예혼합 압축착화 엔진에서 배기가스 재순환과 과급의 영향 (Effect of EGR and Supercharging on the Diesel HCCI Combustion)

  • 박세익;국상훈;배충식;김장헌
    • 한국자동차공학회논문집
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    • 제14권5호
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    • pp.58-64
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    • 2006
  • Homogeneous charge compression ignition(HCCI) combustion is an advanced technique for reducing the hazardous nitrogen oxide(NOx) and particulate matter(PM) in a diesel engine. NOx could be reduced by achieving lean homogeneous mixture resulting in combustion temperature. PM could be also reduced by eliminating fuel-rich zones which exist in conventional diesel combustion. However previous researches have reported that power-output of HCCI engine is limited by the high intensive knock and misfiring. In an attempt to extend the upper load limit for HCCI operation, supercharging in combination with Exhaust Gas Recirculation(EGR) has been applied: supercharging to increase the power density and EGR to control the combustion phase. The test was performed in a single cylinder engine operated at 1200 rpm. Boost pressures of 1.1 and 1.2 bar were applied. High EGR rates up to 45% were supplied. Most of fuel was injected at early timing to make homogeneous mixture. Small amount of fuel injection was followed near TDC to assist ignition. Results showed increasing boost pressure resulted in much higher power-output. Optimal EGR rate influenced by longer ignition delay and charge dilution simultaneously was observed.

Control of Odor Emissions Using Biofiltration: A Case Study of Dimethyl Disulfide

  • Kim, Jo-Chun;Bora C. Arpacioglu;Eric R. Allen
    • Journal of Korean Society for Atmospheric Environment
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    • 제18권E3호
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    • pp.153-163
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    • 2002
  • A laboratory- scale dual-column biofilter system was used to study the biofiltration of dimethyl disulfide (DMDS). The gas flow rate and DMDS concentration to the biofilter were varied to study their effect on the remov-al of dimethyl disulfide. Operating parameters such as pH, temperature, and water content were monitored during the biofilter operation and necessary precautions were taken to keep these parameters within the acceptable limits. It was observed that the removal efficiency of DMDS was optimal at neutral pH values. After five month op-eration, the neutralization of the filter beds with sodium carbonate became necessary for the optimum operation of the biofilters. The microbial population already present in the compost mixtures was found to be adequate in treat-ing DMDS. The compost mixtures were found to be similar in terms of biofiltration efficiency of DMDS. However, pressure drops observed in the first column compost mixture (compost/ peat mulch) was extremely high, making this compost economically not feasible. The second mixture (compost/bark) provided pressure drops within accept-able limits. A minimum residence time of 30 seconds at the optimal operating conditions appeared to be adequate for achieving high removal efficiencies (>90%).

고효율 LCD 감광막 제거기술 구현 연구 (A Study on the Realization of the High Efficiency LCD Photoresist Removal Technology)

  • 손영수;함상용;김병인;이성휘
    • 한국전기전자재료학회논문지
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    • 제20권11호
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    • pp.977-982
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    • 2007
  • The realization of the photoresist(PR) removal method with vaporized water and ozone gas mixture has been studied for the LCD TFT array manufacturing. The developed PR stripper uses the water boundary layer control method based on the high concentration ozone production technology. We develop the prototype of PR stripper and experiment to find the optimal process parameter condition like as the ozone gas flow/concentration, process reaction time and thin boundary layer formation. As a results, we realize the LCD PR strip rate over the 0.4 ${\mu}m/min$ and this PR removal rate is more than 5 times higher than the conventional immersion type ozonized water process.

다양한 액상 수위/부피 조건에서의 300kHz 초음파 캐비테이션 산화반응 분석 연구 (Sonochemical Oxidation Reactions in 300 kHz Sonoreactor for Various Liquid Height/Volume Conditions)

  • 이성은;손영규
    • 한국물환경학회지
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    • 제38권5호
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    • pp.211-219
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    • 2022
  • In this study, the effect of liquid height/volume on sonochemical oxidation reactions was investigated in 300 kHz sonoreactors. The gas mixture of Ar/O2 (50:50) was applied in two modes including saturation and sparging, and zero-order reaction (KI dosimetry) and first-order reaction (Bisphenol A (BPA) degradation) were used to quantitatively analyze sonochemical oxidation reactions. For the zero-order reaction, the highest sonochemical oxidation activity was obtained for the liquid height of 5𝛌, and the lowest height for both the gas saturation and sparging conditions. In addition, the sparging did not enhance the sonochemical oxidation activity for all height conditions except for 50𝛌, where very low activity was obtained. It was found that in sonochemiluminescence (SCL) images the sonochemical active zone was formed adjacent to the liquid surface for the gas sparging condition due to the formation of the standing wave field while the active zone was formed adjacent to the transducer at the bottom due to the blockage of ultrasound. For the first-order reaction, the highest activity was also obtained at 5𝛌 and the comparison based on the reactant mass was not appropriate because the concentration of the reactant (BPA) decreased significantly as the reaction time elapsed. Consequently, it was revealed that the determination of optimal liquid height (ultrasound irradiation distance) based on the wavelength of the applied ultrasound frequency was very important for the optimal design of sonoreactors in terms of reaction efficiency and reactor size.