• 제목/요약/키워드: open-circuit

검색결과 1,167건 처리시간 0.028초

Influence of surface morphology and thickness of molecular thin films on the performance of SubPc-$C_{60}$ photovoltaic devices

  • Kim, Jin-Hyun;Gong, Hye-Jin;Yim, Sang-Gyu
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제40회 동계학술대회 초록집
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    • pp.336-336
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    • 2011
  • Over the past decades, organic semiconductors have been investigated intensely for their potential in a wide range of optoelectronic device applications since the organic materials have advantages for very light, flexible and low cost device fabrications. In this study, we fabricated small-molecule organic solar cells (OSCs) based on chloro[subphthalocyaninato]boron(III) (SubPc) as an electron donor and $C_{60}$ as an electron acceptor material. Recently SubPc, a cone-shaped molecule with $14{\pi}$-electrons in its aromatic system, has attracted growing attention in small-molecule OSC applications as an electron-donating material for its greater open-circuit voltage (VOC), extinction coefficient and dielectric constant compared to conventional planar metal phthalocyanines. In spite of the power conversion efficiency (PCE) enhancement of small-molecule OSC using SubPc and $C_{60}$, however, the study on the interface between donor-acceptor heterojunction of this system is limited. In this work, SubPc thin films at various thicknesses were deposited by organic molecular beam deposition (OMBD) and the evolution of surface morphology was observed using atomic force microscopy (AFM) and field emission scanning electron microscopy (FE-SEM). We also investigated the influence of film thickness and surface morphology on the PCE of small-molecule OSC devices.

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ECAP-Ti와 Alloy의 미세구조와 생체유사용액에서의 부식거동 (Corrosion behavior in SBF and Microstructure of ECAP- Ti and Ti Alloys)

  • 김일용;;김윤종;이승우;신종우;박중근;이성호;김택남
    • 한국재료학회지
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    • 제14권6호
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    • pp.432-435
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    • 2004
  • Ti and Ti alloys are important materials for medical and dental applications. The effect of equal channel angular process(ECAP) and addition of Fe in Ti were studied with optical microstructure and corrosion behavior. Fine grains in Ti was obtained after ECAP. Corrosion behavior of commercial pure(CP)-Ti and Ti alloys was studied by open circuit test and polarization curve test(PCT) at $36.5^{\circ}C$ with SBF in biological environment. The corrosion behavior of ECAP-Ti was similar to that of CP-Ti in PCT, but Ti-Fe alloys were observed to become more corrosive with increasing Fe content.

전도성 접착제 물성에 따른 슁글드 어레이 태양전지 특성 평가 (Characterization of Electrically Conductive Adhesives for Shingled Array Photovoltaic Cells)

  • 지홍섭;최원용;이재형;정채환
    • Current Photovoltaic Research
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    • 제5권3호
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    • pp.95-99
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    • 2017
  • The interconnecting shingled solar cells method shows extremely high ratio active area per total area and has the excellent potential for high power PV (photovoltaic). Compared to the conventional module, it can have much more active area due to busbar-free structure. The properties of ECA (electrically conductive adhesives) are significant to fabricate the shingled array PV since it should be used in terms of electric and structural connection. Various ECA were tried and characterized to optimize the soldiering conditions. The open circuit voltage of shingled array cells showed a three-fold increase and efficiency was also increased by 1.63%. The shingled array cells used in CE3103WLV showed the highest power and in CA3556HF the lowest curing temperature and very fast curing time.

반도체형 고분자를 이용한 태양전지섬유 (A solar Cell Fiber using Semi-conductive Polymers)

  • 송준형;김주용
    • 한국염색가공학회지
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    • 제20권1호
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    • pp.44-47
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    • 2008
  • Organic semi-conductive materials have characteristics such as the advantages of easy formability, low-cost and diversity along with moderate semi-conductive properties. In this paper, we developed a flexible organic-inorganic hybrid solar cell fiber. First, we made a solar cell on the glass and attached the solar cell on the glass fiber similarly. In the latter case, thermal deposition method was employed in order to effectively apply ITO onto fiber surface. The amount of ITO was controlled by varying the temperature from 25, 150 to $300^{\circ}C$. Optimum result was obtained at $150^{\circ}C$ where maximize the deposition amount without significant decomposition of ITO. Despite of maximum open circuit voltage of 0.39V, the resulting current was quite unstable and weak, limiting realistic applications. It was, however, concluded that the flexible solar cell fiber developed showed a possibility of low-weight application from functional clothing for military to space suit mainly due to flexibility and thus wear ability.

저니켈 스테인리스강의 화학적 부동태막 형성에 산화제가 미치는 영향 (Study on the Effects of Oxidant on Chemical Passivation Treatment of Low Nickel Stainless Steel)

  • 최종범;이경황;윤용섭
    • 한국표면공학회지
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    • 제51권3호
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    • pp.172-178
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    • 2018
  • In this paper, effects of potassium permanganate, pottasium dichromate, sodium molybdate on lean duplex stainless steel were studied by GDOES, OCP, potentiodynamic curves. The stainless steels were chemically passivated in each nitric acid solutions containing 4wt.% oxidants for 1 hour. As a result, when potassium dichromate or sodium molybdate was added, content of Fe was decreased and content of Cr was increased. Consequently, corrosion resistance of passive film was increased. But in case of potassium permanganate was added, contrastively, content of Fe was increased and content of Cr was decreased. So corrosion resistance was decreased. Adding sodium molybdate in nitric acid for chemical surface treatment process was the most effective among oxidants and also it showed the most stable anti-corrosion in SST.

유동센서 보정용 캘리브레이션 제트 시스템 개발 (Development of Calibration Jet System for Calibrating a Flow Sensor)

  • 장조원;변영환
    • 한국항공운항학회지
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    • 제11권1호
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    • pp.41-55
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    • 2003
  • A calibration jet system using separate blower is developed to calibrate a flow sensor effectively. Designed open circuit type mini calibration jet system, which has the dimension of $0.5m(W){\times}1.17m(H)$ is small compared with conventional calibration jet systems. The exit of nozzle has exchangeable contractions with a cross section area of $38.5cm^2$ , and a cross section area of $113.1cm^2$, respectively. The ranges of wind speed at exit of exchangeable nozzles are $7.5{\sim}42\;m/s$ and $1.8{\sim}16.5\;m/s$, respectively. The input power for the high pressure blower is 1.18kW. The turning vanes for corner was rolled flat plate parallel to the flow direction. The flow conditioning screen was located immediately downstream of the wide-angle diffuser. The honeycomb and two flow conditioning screens were located in the stagnation chamber. From the economical point of view and the simplicity of the calibration jet system set up and handling, it can be said that the developed calibration jet system is an effective calibration jet system. This system can also be used to calibrate the flow sensor with high resolution.

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선박용 Al-황동세관의 SCC에 미치는 부식환경의 영향 (Effect of corrosion environment on the SCC of Al-brass tube for vessel)

  • 임우조;정해규
    • 수산해양기술연구
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    • 제39권4호
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    • pp.291-297
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    • 2003
  • Al-brass is usually used as the tube material of vessel's heat exchanger for seawater cooling system because it has high thermal conductivity and good mechanical properties and high corrosion resistance due to cuprous oxide (Cu20) layer against seawater. However, Al-brass tubes of heat exchanger for vessel at the actual environment is reported that local corrosion such as stress corrosion cracking occurred by synergism effect between mechanical factor and corrosion environment In this paper, the effect of corrosion environment on the stress corrosion cracking of Al-brass in various NH4OH of 3.5% NaCl solution, under flow by constant displacement tester. Based on the test results, the behavior of polarization, stress corrosion crack propagation and dezincification phenomenon of Al-brass are investigated. The main results are as follows:(1) Increasing range of potential from open circuit potential to repassivation gets lower, as the contain rate of NH4OH gets higher. (2) As contain rate of NH4OH gets higher, SCC of Al-brass is become activation but the protection film(Cu20) of Al-brass is created in 3.5% NaCl solution. (3) According as content of NH4OH increases in 3.5% NaCl solution, the dezincifiction area is spread. It is concluded that dezincification occurred by localized preferential anodic dissolution at stress focusing region.

Ni-Fe/YSZ 코어-쉘 구조 연료극을 사용한 다전지식 고체산화물 연료전지의 전기화학적 특성 (Electrochemical Properties of Segmented-in-series SOFC Using Ni-Fe/YSZ Core-shell Anode)

  • 안용태;지미정;황해진;이민진;홍선기;강영진;최병현
    • 한국세라믹학회지
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    • 제51권4호
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    • pp.357-361
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    • 2014
  • An Ni-Fe/YSZ core-shell structured anode for uniform microstructure and catalytic activity was synthesized. Flat tubular segmented-in-series solid oxide fuel cell-stacks were prepared by decalcomania method using synthesized anode powder. The Ni-Fe/YSZ core-shell anode exhibited better electrical conductivity than a commercially available Ni-YSZ cermet anode. Also power output increased by 1.3 times with a higher open circuit voltage. These results can be attributed to the uniformly distributed Ni particles in the YSZ framework. The impedance spectra of a Ni-Fe/YSZ core-shell anode showed comparable reduced ohmic resistance similar to those of the commercially available Ni-YSZ cermet anodes.

Development of Macro-Porous Silicon Based Dye-Sensitized Solar Cells with Improved Light Trapping

  • Aliaghayee, Mehdi;Fard, Hassan Ghafoori;Zandi, Ashkan
    • Journal of Electrochemical Science and Technology
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    • 제7권3호
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    • pp.218-227
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    • 2016
  • The light harvesting efficiency is counted as an important factor in the power conversion efficiency of DSSCs. There are two measures to improve this parameter, including enhancing the dye-loading capacity and increasing the light trapping in the photoanode structure. In this paper, these tasks are addressed by introducing a macro-porous silicon (PSi) substrate as photoanode. The effects of the novel photoanode structure on the DSSC performance have been investigated by using energy dispersive X-ray spectroscopy, photocurrent-voltage, UV-visible spectroscopy, reflectance spectroscopy, and electrochemical impedance spectroscopy measurements. The results indicated that bigger porosity percentage of the PSi structure improved the both anti-reflective/light-trapping and dye-loading capacity properties. PSi based DSSCs own higher power conversion efficiency due to its remarkable higher photocurrent, open circuit voltage, and fill factor. Percent porosity of 64%, PSi(III), resulted in nearly 50 percent increment in power conversion efficiency compared with conventional DSSC. This paper showed that PSi can be a good candidate for the improvement of light harvesting efficiency in DSSCs. Furthermore, this study can be considered a valuable reference for more investigations in the design of multifunctional devices which will profit from integrated on-chip solar power.

EMB용 전동발전기 선정을 위한 슬롯형과 슬롯리스 Ring-wound형 영구자석 브러시리스 기기의 특성 비교 (Comparison of Slotted and Slotless Ring-wound PM Brushless Machines for Electro-Mechanical Battery)

  • 장석명;정상섭;류동완;최상규
    • 대한전기학회논문지:전기기기및에너지변환시스템부문B
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    • 제50권3호
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    • pp.107-114
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    • 2001
  • Electro-mechanical battery (EMB) consists of a high-speed fly wheel with an integral motor/ generator suspended on magnetic bearings and in an evacuated housing. Permanent magnet (PM) machines as the EMB motor/ generator are a popular choice, since there are no excitation losses which means substantial increase in the efficiency. In this paper we present the comparison of conventional slotted and slotless ring-wound types, aimed at EMB and other high-speed drives. We firstly discuss the topology of each machine for this particular application. these machines are primarily designed as 1kW two-pole PM generator with the rated speed of 40000 rpm. the motoring torque of 0.51 Nm has to be enough to accelerate the flywheel to the rated speed. We then present the comparison of the open-circuit field, the armature reaction field and winding inductance. next we analyze the induced voltage and the developed torque per unit stack length and unit weight of different machines. Finally, we estimate and compare the losses and the efficiency at motoring and generating modes.

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