• 한국환경과학회지
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• 제6권2호
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• pp.183-187
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• 1997

유기인제 농약을 70% acetone으로 추출한 다음 dlchloromethane 층으로 옮겨 추출물을 florisil로 충진된 open-column에서 chromatography를 행하였다. 마지막 추출물을 nitrogen-phosphorus detector(GC/NPD)을 가진 GC로 분석하였다. Narrow-bore capillary GC(Ultra-2)에 대해 18 가지의 유기인제 농약의 회수율이 88.7%에서 100.0%에 달하였다. 본 분석 방법의 최소 검출 준위는 0.019 - 0.035 mg/kg 이었으며 sample throughput(추출, open-column chro-matography 및 GC 분석)도 상당히 개선되었다.(sample당 8시간)

• 한국해양환경ㆍ에너지학회지
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• 제20권2호
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• pp.63-75
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• 2017

해양환경에서 파랑-구조물 상호작용의 정확한 예측은 극한 환경조건에 노출 된 고정식 및 부유식 해양구조물의 안전성과 설계비용 효율성에 있어서 중요하다. 본 연구에서는 규칙파 와 원형 기둥의 파랑-구조물 상호작용을 해석하였다. 3차원 이상유동(two-phase flow)을 해석하기 위해 오픈소스 전산유체역학 라이브러리인 OpenFOAM을 사용하였다. 수치파랑수조에서 파를 생성 및 흡수하기 위해 소스항을 이용한 relaxation method를 적용하였다. 수치기법을 검증하기 위해 심해조건에서 생성된 2차 stokes 파형은 이론적인 해와 비교하였다. 검증과정을 통해 파장과 진폭에 대한 길이 및 높이 방향의 격자크기를 정하였다. 원형 기둥에 작용하는 파랑 하중과 wave run-up을 계산하고 기존의 실험 데이터와 비교하였다.

• 한국철도학회:학술대회논문집
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• 한국철도학회 2011년도 정기총회 및 추계학술대회 논문집
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• pp.2409-2421
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• 2011

본 논문에서는 지진하중에 의한 1경간 1층 강재골조구조에 대한 하이브리드 실험을 수행하였다. 오른쪽 기둥 1개소와 상부의 트러스요소 또는 보요소는 수치해석모형으로, 왼쪽기둥 1개소는 물리적 부분구조모형으로 선택하여 요소의 성능 및 거동을 평가하였다. 실험은 1자유도 또는 3자유도만을 고려하여 실시간으로 하이브리드 실험을 수행하였으며, 이를 위한 제어 알고리즘은 MATLAB/Simulink를 이용한 방법과 OpenSees, OpenFresco와 xPCTarget를 이용하는 방법으로 나누어 수행하였다. 그리고 수치해석모형과 물리적 부분구조모형의 실시간 데이터 통신을 위하여 SCRAMNet을 사용하였다. 파이버단면을 이용한 구조해석이 가능한 OpenSees를 사용하여 수치해석을 실시하였으며, 실시간 하이브리드 실험결과를 이와 비교하였다. 단순한 구조모형을 이용하여 제어시스템의 유효성을 검증하고자 실시간 하이브리드 실험이 실시되었으며, 추후 심각한 비선형성을 갖거나 복잡한 구조물의 하이브리드 실험으로 확장할 예정이다.

• Structural Engineering and Mechanics
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• 제47권6호
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• pp.791-818
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• 2013

The seismic performance of reinforced concrete (RC) frame structures with irregularities leading to soft first floor is studied using capacity assessment procedures. The soft first story effect is investigated for the cases: (i) slab-column connections without beams at the first floor, (ii) tall first story height and (iii) pilotis type building (open ground story). The effects of the first floor irregularity on the RC frame structure performance stages at global and local level (limit states) are investigated. Assessment based on the Capacity Spectrum Method (ATC-40) and on the Coefficient Method (FEMA 356) is also examined. Results in terms of failure modes, capacity curves, interstory drifts, ductility requirements and infills behaviour are presented. From the results it can be deduced that the global capacity of the structures is decreased due to the considered first floor morphology irregularities in comparison to the capacities of the regular structure. An increase of the demands for interstory drift is observed at the first floor level due to the considered irregularities while the open ground floor structure (pilotis type) led to even higher values of interstory drift demands at the first story. In the cases of tall first story and slab-column connections without beams soft-story mechanisms have also been observed at the first floor. Rotational criteria (EC8-part3) showed that the structure with slab-column connections without beams exhibited the most critical response.

• Clinics in Shoulder and Elbow
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• 제22권1호
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• pp.29-36
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• 2019

Background: The execution of fibular allograft augmentation in unstable proximal humerus fractures (PHFs) was technically demanding. In this study, the authors evaluated the clinical and radiographic outcomes after tricortical iliac allograft (TIA) augmentation in PHFs. Methods: We retrospectively assessed 38 PHF patients treated with locking-plate fixation and TIA augmentation. Insertion of a TIA was indicated when an unstable PHF showed a large cavitary defect and poor medial column support after open reduction, regardless of the presence of medial cortical comminution in preoperative images. Radiographic imaging parameters (humeral head height, HHH; humeral neck-shaft angle, HNSA; head mediolateral offset, HMLO; and status of the union), Constant score, and range of motion were evaluated. Patients were grouped according to whether the medial column support after open reduction was poor or not (groups A and B, respectively); clinical outcomes were compared for all parameters. Results: All fractures healed radiologically (average duration to complete union, 5.8 months). At final evaluation, the average Constant score was 73 points and the mean active forward flexion was $148^{\circ}$. Based on the Paavolainen assessment method, 33 patients had good results and 5 patients showed fair results. The mean loss of reduction was 1.32 mm in HHH and 5.02% in HMLO. None of the parameters evaluated showed a statistically significant difference between the two groups (poor and not poor medial column support). Conclusions: In unstable PHFs, TIA augmentation can provide good clinical and radiological results when there are poor medial column support and a large cavitary defect after open reduction.

• 한국물환경학회지
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• 제23권5호
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• pp.723-730
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• 2007

This study was conducted to develop a combined method for remediating a Chlorinated Aliphatic Hydrocarbons (CAHs) mixtures-contaminated aquifer. The process is consist of two processes. A chemical process (1st) using natural zinc ores for reducing higher concentrations of CAH mixtures to the level at which biological process is feasible; and A biological process (2nd) using aerobic cometabolism for treating lower concentration of CAH mixtures (less than 1 mg/L). Natural zinc ore showed relatively high transformation capacity, average dehalogenation percentage, and the best economic efficiency in previously our study. To evaluate the feasibility of the process, we operated two columns in series (that is, chemical and biological columns). In the first column filled with natural zinc ore and sand, CAH mixtures were effectively transformed with more than 95% efficiency, the efficiency depends on the Empty Bed Contact Time (EBCT) and the mass of zinc ore packed. Scanning Electron Microscope (SEM), X-Ray Diffraction (XRD) analysis were performed to make sure whether natural zinc ore played an key role in the dechlorination of the CAH mixtures. The characteristics of zinc metal surface changed after exposure to CAHs due to oxidation of $Zn^0$ to $Zn^{2+}$. In the biological column injecting propane, DO and effluent of the chemical column, only 1,1,1-TCA was cometabolically transformed. Consequently, the combined process would be effective to remediate an aquifer contaminated with high concentrations of CAH mixtures.

• 분석과학
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• 제12권1호
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• pp.84-88
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• 1999

A method to analyze additives in a polyester resin has been studied by utilizing a centrifuge and a thin layer chromatography. Identification of the separated organic and inorganic compounds were carried out by spectrophotometers, such as NMR, UV-VIS, IR and XRD. For the polyester resin studied in this research contained organic and inorganic compounds which were found to be a dimer form of 2-phenylbenzoazole and an anatase form of $TiO_2$, respectively.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2004년도 춘계학술대회논문집
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• pp.957-962
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• 2004

This paper deals with the free vibration analysis of beam-columns resting on Pasternak foundation by the Differential Quadrature Method. Based on the differential equation subjected to the boundary conditions, adopted from the open literature, which governs the free vibrations of such member, this equation is applied to the Differential Quadrature Method. For computing natural frequencies, the numerical procedures are developed by QR Algorithm, in which the Chebyshev-Gauss-Lobatto method is used for choosing the grid points. The numerical methods developed herein for computing natural frequencies are programmed in FORTRAN code, and all solutions obtained in this study are quite agreed with those in the open literature.

• 한국환경과학회지
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• 제12권4호
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• pp.477-480
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• 2003

Pesticides were extracted from samples with 70% acetone and methylene chloride in order, and then cleaned up via open-column chromatography apparatus packed with florisil, and finally analyzed simultaneously the organochlorine and pyrethroid pesticides using GC(ECD). An ultra-2 fused silica capillary column was used to separate and identify the products. The resolution between the last isomeric peak of cypermethrin(59.987min) and the first isomeric peak of flucythrinate(60.043min) was not satisfactory. The last isomeric peak of fenvalerate(62.344min) and the first isomeric peak of fluvalinate(62.397min) were overlapped. Recoveries of soybean sample fer the most pesticides were 73.3% to 102.4%. Detection limits were between 0.004 and 0.063 ${\mu}$g/mg when this method was used.

• 한국환경보건학회지
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• 제27권1호
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• pp.88-92
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• 2001

The simultaneous analytical method for 37 residual pesticides was developed by a gas chromatography with $^{63}$ Ni electron capture detector. Pesticides added in soybean sample were extracted with 70% acetone in water and methylene chloride in oder, and then cleaned up via open-column apparatus packed with florisil and alumina N. The Ultra-2 fused capillary column was used to separate the products. The resolution between the last isomeric peak of cypermethrin (56.398 min) and the first isomeric peak of flucythrinate (56.421 min) was not satisfactory and the last isomeric peak of fenvalerate(58.783 min) and the first isomeric peak of fluvalinate(58.835 min) was overlapped. Except for $\alpha$-BHC, dichlofluanid, captan, and captafol, most recoveries were showed over 70%.