• 한국태양에너지학회 논문집
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• 제32권5호
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• pp.118-123
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• 2012

Water balance has a significant impact on the overall fuel cell performance. Maintenance of proper water management should provide an adequate membrane hydration and avoidance of water flooding in the catalyst layer and gas diffusion layer. Considering the important of advanced water management in PEM fuel cell, this study proposes a simple one dimensional water transportation model of PEM fuel cell for use in a dynamic condition. The model has been created by assumption that the output is the water liquid saturation difference. The liquid saturation change is the total difference between the additional water and the removal water on the system. The water addition is obtained from fuel cell reaction and the electro osmotic drag. The water removal is obtained from capillary transport and evaporation process. The result shows that the capillary water transport of low temperature fuel cell is high because the evaporation rate is low.

• 재무관리연구
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• 제25권2호
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• pp.69-101
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• 2008

본 연구는 결정적변동성 옵션가격결정모형보다 더 일반적인 조건에서도 성립되는 옵션의 레버리지효과와 기초자산을 일차원확산과정으로 제약할 경우에만 성립되는 여분가정의 성립여부를 실증적으로 검증하였다. 다음으로 여분가정이 기각될 경우 해당원인을 규명하기 위해, 기초자산과의 선형적인 관계하에서의 레버리지 이외에 KOSPI 200 지수옵션의 가격동학에 내재된 추가적인 체계적 위험요인들을 규명하였다. 분석결과 이론과 일치하는 레버리지패턴이 존재하였지만 여분 자산가정은 기각되었다. 여분가정이 기각되는 원인을 분석한 결과, 선형적인 레버리지하에서의 기초자산의 불확실성에 대한 프리미엄 이외에, 비선형적인 수익구조하에서의 체계적 고차적률에 대한 선호와 체계적 확률변동성위험에 대한 음의 프리미엄이 옵션의 시장가격에 반영되어 있는 것으로 나타났다. 그러나 점프위험에 대한 선호여부는 명확하지 않으며 이에 대한 추가적인 연구가 요구되었다.

• 대한금속재료학회지
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• 제50권3호
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• pp.256-262
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• 2012

This study investigated the hydrogen storage properties of Zr-Based $AB_{2-x}M_x$ metal hybride made by HCS (Hydriding Combustion Synthesis). The materials were prepared by HCS 80 wt% $AB_2$-15 wt% Mg-5 wt% Mm, HCS 80 wt% $AB_2$-20 wt% Mg and pure Zr-Based $AB_2$, These materials were activated at 298 K under 20 bar. Both HCS 80 wt% $AB_2$-20 wt% Mg and HCS 80 wt% $AB_2$-15 wt% Mg-5 wt% Mm were absorbed within 1 minute. In the case of the $AB_2$, it was perfectly absorbed within 6 minutes. Then, the materials were evaluated to obtain P-C-T (Pressure-Composition-Temperature) curves at 298K. As a result, the hydrogen storage capacity of HCS 80 wt% $AB_2$-20 wt% Mg, HCS 80 wt% $AB_2$-15 wt% Mg-5 wt% Mm and pure Zr-Based $AB_2$ were determined to be 1.2, 1.6 and 1.74 wt%, respectively. The activation energy and rate controlling step were calculated by the Johnson-Mehl Avrami equation. The activation energies of HCS 80 wt% $AB_2$-20 wt% Mg, HCS 80 wt% $AB_2$-15 wt% Mg-5 wt% Mm and pure Zr-Based $AB_2$ were 26.91, 20.45, and 60.41 kJ/mol, respectively. Also, the values of ${\eta}$ in the Johnson-Mehl Avrami equation for HCS 80 wt% $AB_2$-20 wt% Mg, HCS 80 wt% $AB_2$-15 wt% Mg-5 wt% Mm and pure Zr-Based $AB_2$ are 0.60, 0.51, and 0.44. So, the rate controlling steps which indicate hydrogen storage mechanism are an one dimensional diffusion process.