• Title/Summary/Keyword: nitrogen cycling

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Estimation of N-balance and Agronomical Approaches to Minimizing Nitrogen Pollution in Korea Agriculture (한국 국토의 질소부하화 질소오염 방지대책)

  • 류종원
    • Journal of Animal Environmental Science
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    • v.3 no.2
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    • pp.125-131
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    • 1997
  • This paper was discussed N-balance of the republic of Korea. About 397Kg N/ha was inputted into the chemical fertilizer, animal feed, precipitation and nitrogen fixation. About 15kg N/ha was outputted from the Korea. The amount of N surplus was 397kg N/ha and loaded into environment. This causes the problem of water, air and soil pollution. It should take measures to improve the situation, such as depending more on selfsufficient feed and using nutrient cycling functions of soils.

Combined effect of nitrogen- and oxygen functional groups on electrochemical performance of surface treated multi-walled carbon nanotubes (표면처리된 탄소나노튜브의 질소 및 산소관능기 도입에 따른 전기화학적 특성)

  • Kim, Ji-Il;Park, Soo-Jin
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.214.1-214.1
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    • 2011
  • In this work, the electrochemical properties of the surface treated multi-walled carbon nanotubes (MWNTs) are investigated for supercapacitors. Nitrogen- and oxygen functional groups containing MWNTs are prepared by nitrogen precursors and acidic treatment, respectively. The surface properties of the MWNTs are confirmed by X-ray photoelectron spectroscopy (XPS) and Zeta-potential measurements. The electrochemical properties of the MWNTs are investigated by cyclic voltammetry, impedance spectra, and charge-discharge cycling performance in 1 M $H_2SO_4$ at room temperature. As a result, these functionalized MWNTs lead to an increase in the specific capacitance as compared with the pristine MWNTs. It proposes that the pyridinic and pyridinic-N-oxides nitrogen species influence on the specific capacitance due to their positive charges, and thus an improved electron transfer at high current loads, since they are the most important functional groups affecting capacitive behaviors.

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Carbon and Nitrogen Responses of Litterfall Components by NPK and PK Fertilizers in a Red Pine (Pinus densiflora S. et Z.) Stand

  • Park, Seong-Wan;Baek, Gyeongwon;Kim, Seongjun;Yang, A-Ram;Kim, Choonsig
    • Journal of Korean Society of Forest Science
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    • v.108 no.1
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    • pp.21-28
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    • 2019
  • This study was conducted to determine the carbon (C) and nitrogen (N) response of litterfall components as affected by N addition in compound fertilizer in a Korean red pine (Pinus densiflora S. et Z.) stand in southern Korea. Litterfall in a mature red pine stand was collected for two years following compound fertilizer application ($N_3P_4K_1$; $P_4K_1$) and no fertilization (control). The C concentration of litterfall components was not significantly (P > 0.05) different between the $N_3P_4K_1$ and the control plots, whereas the N concentration of the litterfall components was significantly higher in the $N_3P_4K_1$ plot than in the control plot. The $N_3P_4K_1$ and $P_4K_1$ additions induced a lower C/N ratio of litterfall components compared with the control plot. Annual C and N fluxes via litterfall components were not affected by the $N_3P_4K_1$ addition over the study period, except for reproduction litter. Annual N fluxes via reproduction litter were significantly higher in the $N_3P_4K_1$ plot than in the control plot. Thus, the $N_3P_4K_1$ and $P_4K_1$ additions could modify differently nutrient distribution of the forest floor and mineral soils in a red pine stand. These results indicate that N concentration and C/N ratio in litterfall components are more susceptible to fertilizer application than the C response in litterfall components.

A Study on the Biological Organic, Nitrogen and Phosphorus Removal in Sequencing Batch Biofilm Reactor (연속회분식 생물막 반응기(Sequencing Batch Biofilm Reactor)를 이용한 수중의 유기물, 질소 및 인의 동시 제거에 관한 연구)

  • 박민정;김동석
    • Journal of Environmental Health Sciences
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    • v.30 no.2
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    • pp.84-91
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    • 2004
  • Biological nutrient removal(BNR) from wastewater was performed by adopting various process configurations. The simultaneous biological organics, phosphorus and nitrogen removal of synthetic wastewater was investigated in a sequencing batch biofilm reactor (SBBR). The other reactor was operating as a reference, without biofilm being added. The cycling time in SBR and SBBR was adjusted at 12 hours and then certainly included anaerobic and aerobic conditions. Both systems has been operated with a stable total organic carbon(TOC), nitrogen and phosphorus removal performance for over 90 days. Average removal efficiencies of TOC and total nitrogen were 83% and 95%, respectively. The nitrification rate in SBR was higher than that in SBBR. On the contrary, the denitrification rate in SBBR was higher than that in SBR. The phosphorus release was occurred in SBBR, however, not in SBR because of the inhibition effect of NO$_3$$^{[-10]}$ .

A Comparison of Nitrogen Cycling among Young Pinus koraiensis Plantations of Different Ages (잣나무 유림의 수령에 따른 질소순환의 비교)

  • Cho, Kang-Hyun;Kim, Joon-Ho
    • The Korean Journal of Ecology
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    • v.12 no.4
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    • pp.245-256
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    • 1989
  • Nitrogen cycling was in vestigated in Piuns koraiensis plantations with different ages, 1, 2, 3, 6, 9 and 11 years, which were reforested after clear-cutting. Annual N input by bulk precipitation was 10kg., and output by runoff decreased as the plantation aged, especially in-N. The standing N content of the whole vegetation increased approximately 5 times through 11 years. Understory surpassed P. koraiensis plants in the distribution of standing N content for the initial 9 years, but reversed thereafter. Annual N uptake of P. koraiensis plants increased greatly through 11 years, but that of understory increased somewhat until 9 years and decreased thereafter. The maximum N uptake of the whole vegetation was made in the 9-yr-old plantation. In the 1-yr-old one, 59% of the maximum was already absorbed by understory which mainly consisted to herbs. The recycling coefficient, ratio of annual return to rptake, of the whole vegetation decreased as the plantation aged and the value of understory was greater than that of P koraiensis plants. On the contrary, the N use efficiency, ratio of the net primary production to N uptake, of the whole vegetation increased as the plantation aged and the value of understory was less than that of P. koraiensis plants. Consequently, it is emphasized that understory played an important role in such plantation reforesred after clear-cutting for the initial 9 years.

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EFFECT OF ADDITIONS OF POTASSIUM AND NITROGEN INTO PRESS CAKE ON MAGNESIUM UTILIZATION OF GOATS WITH RELATION TO WATER INTAKE

  • Kim, S.A.;Ohshima, M.;Kayama, R.
    • Asian-Australasian Journal of Animal Sciences
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    • v.1 no.1
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    • pp.33-41
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    • 1988
  • In a study about minerals cycling in grassland agro-ecosystem, investigation on relations among two minerals, potassium(K) and magnesium(Mg), and nitrogen(N) was performed. Four kinds of diets different in K and N levels were fed to four goats with a Latin-square method and $2{\times}2$ factorial design. As the basal diet, press cake silage prepared from Italian ryegrass was used because of its uniformity and comparatively low mineral concentrations. Supplementation of K and N were made using potassium bicarbonate and urea. In the experiment, it was clearly shown that high K concentration in the forage crops is the main reason of the low utilization of Mg in ruminant animals. However, high nitrogen intake resulted in the increase of magnesium retention, urinary potassium excretion, water intake and volume of urine and in the decreases of potassium intake minus urinary potassium excretion. The results of high nitrogen intake seemed to be produced in the following order;increase of urine, increase of water intake, increase of urinary potassium excretion, and decrease of intake minus urinary potassium excretion. The amount of potassium intake minus urinary potassium excretion had significantly close relationships with magnesium utilization and serum magnesium concentration. As a conclusion, higher nitrogen intake by ruminants seemed to be preferable for magnesium utilization through increased water intake and urinary potassium excretion, if the sufficient drinking water could be supplied to ruminants.

Difference of Nutrients Budgets in the Bohai Sea between 1982 and 1992 related to the Decrease of the Yellow River Discharge

  • Hayashi, Mitsuru;Yanagi, Tetsuo;Xinyu, Guo
    • Journal of the korean society of oceanography
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    • v.39 no.1
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    • pp.14-19
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    • 2004
  • Difference of Dissolved Inorganic Phosphorus (DIP), Dissolved Inorganic Nitrogen (DIN) and Dissolved Silicate (DSi) budgets in the Bohai Sea between 1982 and 1992 related the decrease of the Yellow River discharge is discussed on the basis of observed data. The estuarine circulation in the Bohai Sea had been weakened from 1982 to 1992 due to the decrease of the Yellow River discharge and the average residence time of fresh water had become longer. DIN concentration increased but DIP and DSi concentrations decreased from 1982 to 1992 in the Bohai Sea. Primary production was regulated mainly by water temperature and DIN concentration in 1982 but it was regulated mainly by DIP concentration in 1992. Primary production was larger than decomposition plus bottom release and nitrogen fixation was larger than denitrification in 1982. However, decomposition plus bottom release was larger than primary production and denitrification was larger than nitrogen fixation in 1992 in the Bohai Sea.

Comparison of a Microbiological Model Simulation with Microcosm Data

  • Lee, Jae-Young;Tett, Paul;Jones, Ken
    • Journal of the korean society of oceanography
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    • v.39 no.4
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    • pp.222-233
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    • 2004
  • Using nitrogen as the limiting nutrient, the default version of a microplankton-detritus model linked chlorophyll concentration to the autotroph nitrogen. However, phosphorus dynamics were added to simulate the results of a microcosm experiment. Using standard parameter values with a single value of microheterotroph fraction in the microplankton taken from the observed range, the best simulation successfully captured the main features of the time-courses of chlorophyll and particulate organic carbon, nitrogen and phosphorus, with root-mean-square error equivalent to 29% of particulate concentration. A standard version of microbiological model assumes complete internal cycling of nutrient elements; adding a term for ammonium and phosphate excretion by microheterotrophs did not significantly improve predictions. Relaxing the requirement for constant microheterotroph fraction resulted in an autotroph-heterotroph model AH, with dynamics resembling those of a Lotka-Volterra predator-prey system. AH fitted the microcosm data worse than did MP, justifying the suppression of Lotka-Volterra dynamics in MP. The paper concludes with a discussion of possible reasons for the success of the simple bulk dynamics of MP in simulating microplankton behaviour.

Durability of Photocatalytic Cement after Nitric Oxide-Wet-Dry Cycling

  • Lee, Bo Yeon;Kurtis, Kimberly E.
    • Journal of the Korea Institute of Building Construction
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    • v.14 no.4
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    • pp.359-368
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    • 2014
  • Photocatalytic cement has been receiving attention due to its high oxidation power that reduces nitrogen oxide, thus contributing to a clean atmospheric environment. However, there has not yet been a thorough investigation on the effect of photocatalytic reactions on the durability of cementitious material, the parent material. In this study, photocatalytic cement samples were exposed to nitric oxide gas and UV along with cycles of wetting and drying to simulate environmental conditions. The surface of samples was characterized mechanically, chemically, and visually during the cycling. The results indicate that that the photocatalytic efficiency decreased with continued NO oxidation. The pits found from SEM indicated that chemical deterioration, such as acid attack or leaching, did occur. However, this was not confirmed by X-ray diffraction. The hardness was not affected, probably due to the formation of CSH as evidenced by the XRD pattern. In conclusion, it was found that photocatalysis could alter cementitious materials both chemically and mechanically, which could further affect long-term durability.

Seasonal Variation of Nitrogen Loads and Nitrogen Cycling at Tidal Flat Sediments in Nakdong River Estuary (낙동강 하구 갯벌 퇴적물에서 강을 통한 질산염 유입에 따른 질소순환의 계절 변화)

  • Lee, Ji-Young;Kwon, Ji-Nam;An, Soon-Mo
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.17 no.2
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    • pp.120-129
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    • 2012
  • We investigated seasonal variation of sediment-water oxygen and inorganic nitrogen fluxes, and denitrification at tidal flat sediments located in the Nakdong River Estuary from July 2005 to September 2006. Net oxygen fluxes, measured with sediment incubations at in situ temperature, varied from -37.0 to $0.5mmol\;O_2\;m^{-2}\;d^{-1}$. Oxygen fluxes into the sediments from the overlying water increased due to the increased water temperature. Denitrification rate ($4{\sim}2732{\mu}mol\;N\;m^{-2}\;d^{-1}$) in this study was higher compared to the other Korean coast measured with the same method. Denitrification showed the same seasonal variation as oxygen fluxes. Denitrification rate based on $^{15}N$-nitrate showed a strong correlation with nitrate flux into the sediments from the overlying water. Denitrification via "water column supplied nitrate ($D_w$)", calculated from Isotope pairing technique, also correlated well with nitrate flux into the sediments. Nitrate from water column seems to account for seasonal variation of denitrification in Nakdong River Estuary. To understand general patterns and trends of biogeochemical processes of sediments in the Nakdong River Estuary, we categorized biogeochemical fluxes measured in this study according to direction and sizes of fluxes. Type 1(high oxygen and inorganic nitrogen fluxes into the sediments and high denitrification) occurred in summer, whereas Type 2(low oxygen and inorganic nitrogen fluxes into the sediments and low denitrification) occurred in rest of the season. Intertidal flat sediments seem to react sensitively to influence of freshwater from the Nakdong River.