• Title/Summary/Keyword: nitrogen biodegradability

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Evaluation of biodegradability according to bait type for crab pots (꽃게 통발용 미끼의 형태에 대한 생분해도 평가)

  • Jeong, Byung-Gon;Chang, Ho-Young;Koo, Jae-Geun
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.44 no.1
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    • pp.20-30
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    • 2008
  • In order to evaluate the biodegradability of bait used in the pot for swimming crab, water tank experiments were conducted. Mackerel is the most commonly used natural form of bait to catch the swimming crabs, and therefore was used in this experiment for the biodegradability according to the manufacturing process of the bait. From the biodegradability test on chemical oxygen demand(COD), total nitrogen(T - N), total phosphorus(T - P), ammoniac nitrogen, nitrite nitrogen and nitrate nitrogen per unit weight of the bait based on the production rate and the accumulated amount of pollutants, it was concluded that the smaller the size of the mackerel pieces, the higher the production rate and accumulated amount of organic matter and nutrients which was unfavorable to water pollution. The amount of pollutants released from the intestine of the tuna was similar with that from the whole mackerel. For the operation period of 111 days, the accumulated concentrations of tested pollutants from the tuna which were 67.3 mgCOD/g d, 86.4 mgT N/g d, 3.1 mgT - P/g d, were almost half comparing with those from the mackerel which were 65.7 - 94.4 mgCOD/g d, 83.8 - 109.4 mgT - N/g d, 3.1 - 5.2 mgT - P/g d. The amount of pollutants released from the intestine of the tuna was slightly less than that from the mackerel that was cut into 8 pieces. but more than that from the mackerel which was not cut into pieces. Therefore, it can be concluded that the key factor in determining water pollution potential is not the kind of bait, but the processing or preparation method used.

Estimation of Nitrifiable Nitrogen Compounds in Municipal Wastewater by Respirometry (호흡률법에 의한 하수의 질산화성 질소화합물 추정)

  • Kim, Dong Han
    • Journal of Korean Society of Water and Wastewater
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    • v.21 no.3
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    • pp.295-303
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    • 2007
  • Nitrogen compounds in municipal wastewater can be divided into biodegradable and nonbiodegradable fractions with biodegradability. Biodegradable nitrogen compounds can be removed through biological nitrification and denitrification processes, and nonbiodegradable nitrogen compounds affect the effluent quality of biological nutrient removal processes. The amount of nitrifiable nitrogen compounds, which are the sum of ammonia and biodegradable organic nitrogen, has been estimated by respirometry. Respirometry shows good estimation of the concentration of nitrifiable nitrogen when a synthetic sample of ammonium chloride is dosed. The estimated concentration of nitrifiable nitrogen compounds in municipal wastewater is close to ammonia concentration in municipal wastewater, but it is lower than that for the synthetic sample. If nitrogen assimilated into cell synthesis of nitrifiers and heterotrophs is considered, the total amounts of nitrifiable nitrogen compounds, which are nitrified and assimilated, could be more accurately estimated. The concentration of nitrifiable nitrogen compounds, which are biodegradable, is about 31 mg N/l, and this is 119% of ammonia and 94% of total nitrogen. Ammonia, nitrate, biodegradable organic nitrogen, and nonbiodegradable nitrogen are about 79%, 1%, 15%, and 5% of the total nitrogen in municipal wastewater, respectively.

Hydrophilicity and Biodegradability of Polyesteramides (폴리에스테르아미드의 친수성과 생분해성)

  • 김은영;박정희
    • Journal of the Korean Society of Clothing and Textiles
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    • v.25 no.7
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    • pp.1270-1280
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    • 2001
  • In this research of biodegradable polymers, it is essential to investigate the relation between biodegradability and molecular structure such as chemical constitution, hydrophilicity, molecular weight, crystallinity, chain orientation, and so on. It is also expected that hydrophilicity of polymer can affect biodegradability because biodegradation occurs with the help of enzymes and microorganisms. This study is to investigate the effect of hydrophilicity on biodegradability of polyesters. Hydrophilicity was varied by adding 5~30 mol% of amide groups, since amide groups are hydrophilic and used for improving thermal and mechanical properties. Surface energies and nitrogen contents by ESCA were measured to determine their hydrophilicity. The biodegradation was examined in activated sludge, enzyme and natural soil by $CO_2$evolution, TOC, weight loss, and observation through microscopy. The results showed that hydrophilicity of polyesteramide films increased with the addition of amide, PBAD series of shorter methylene units showed maximum hydrophilicity at 15~20 mol% of amide contents, but PBSE exhibited maximum values at 5~15 mol% of amide contents. The biodegradability increased as the hydrophilicty on surface increased. The biodegradation rate of PBAD series was higher than that of PBSE series. Therefore, it can be concluded that the addition of appropriate contents of hydrophile enhanced the biodegradability of aliphatic polyesters as well as their physical properties. Also, the experimental results revealed the relation between hydrophilicity and biodegradability of polyesteramides.

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The Biodegradation Characteristics of the Mixtures of Bunker-A, B Oils with Dispersants in the Seawater

  • BAEK Joong-Soo;KIM Gwang-Su;CHO Eun-il
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.29 no.6
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    • pp.787-796
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    • 1996
  • The biodegradation experiment, the TOD analysis and the element analysis for dispersant, Bunker-A oil and Bunker-B oil were conducted to study the biodegradation characteristics of a mixture of Bunker-A oil with dispersant and a mixture of Bunker-B oil with dispersant in the seawater. The results of biodegradation experiment showed 1mg of dispersant to be equivalent to 0.26 mg of $BOD_5$ and to 0.60 mg of $BOD_{20}$ in the natural seawater. The results of TOD analysis showed each 1 mg of dispersant, Bunker-A oil and Bunker-B oil to be equivalent to 2.37 mg, 2.94 mg and 2.74 mg of TOD, respectively. The results of element analysis showed carbon, hydrogen, nitrogen and phosphorus contents of dispersant to be $82.1\%,\;13.8\%,\;1.8\%\;and\;2.2\%$, respectively. Carbon and hydrogen contents of Bunker-A oil were found to be $73.3\%\;and\;13.5\%$, respectively, and carbon, hydrogen and nitrogen contents of Bunker-B oil to be $80.4\%,\;12.3\%\;and\;0.7\%$, respectively. Accordingly, the detection of nitrogen and phosphorus in dispersant shows that dispersants should be used with caution in coastal waters, with relation to eutrophication. The biodegradability of dispersant expressed as the ratio of $BOD_5/TOD$ was found to be $11.0\%$. As the mix ratios of dispersant to Bunker-A oil (3 mg/l) and a mixture of Bunker-B oil (3mg/l) were changed from 1 : 10 to 5 : 10, the biodegradabilities of a mixture of Bunker-A oil with dispersant and Bunker-B oil with dispersant increased from $2.1\%\;to\;7.2\%$ and from $1.0\%\;to\;4.4\%$, respectively. Accordingly, the dispersant belongs to the organic matter group of middle-biodegradability while mixtures in the mix ratio range of $1:10\~5:10$ belong to the organic matter group of low-biodegradability. The deoxygenation rate constant $(K_1)$ and ultimate biochemical oxygen demand $(L_0)$ obtained from the biodegradation experiment and Thomas slope method were found to be 0.125/day and 2.487 mg/l for dispersant (4 mg/l), respectively. $K_1\;and\;L_0$, were found to be $0.079\~0.131/day$ and $0.318\~2.052\;mg/l$ for a mixture of Bunker-A oil with dispersant and to be $0.106\~0.371/day$ and $0.262\~1.106\;mg/l$ for a mixture of Bunker-B oil with dispersant, respectively, having $1:10\~5:10$ mix ratios of dispersant to Bunker-A oil and Bunker-B oil. The ultimate biochemical oxygen demands of the mixtures increased as the mix ratio of dispersant to Bunker-A, B oils changed from 1 : 10 to 5 : 10. This suggests that the more dispersants are applied to the sea for the cleanup of Bunker-A oil or Bunker-B oil, the more decreases the dissolved oxygen level in the seawater.

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Effect of Zinc on the Suspended Growth Biological Wastewater Treatment (부유 성장식 생물학적 폐수처리에 미치는 아연의 영향)

  • Seo, Jeong-Beom;Hwang, Chang-Min
    • Journal of Korean Society of Environmental Engineers
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    • v.37 no.4
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    • pp.228-233
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    • 2015
  • This study was performed to examine the effect of zinc on the biodegradability, nitrification, denitrification and oxygen uptake rate (OUR) using batch reactor and continuous flow stirred tank reactor (CSTR) of anaerobic/anoxic/oxic ($A^2/O$). The results of this study can be summarized as follows. In the case of the effect of zinc on organic treatment, zinc had no effect up to 12 mg/L with batch reactor but biodegradability was lowered when it was above 3.0 mg/L with CSTR. Concerning the case on nitrification and removal of nitrogen, nitrification rate was lowered when zinc was above 6.0 mg/L with batch reactor and removal rate of nitrogen was lowered when zinc was above 3.0 mg/L with CSTR. Removal rate of phosphorus was lowered when it was above 6.0 mg/L zinc with batch reactor and above 3.0 mg/L zinc with CSTR. In the case of OUR, it decreased as microbial activity was affected when zinc concentration was above 3.0 mg/L in CSTR.

Effects of ultrasound coupled with potassium permanganate pre-treatment of sludge on aerobic digestion

  • Demir, Ozlem
    • Advances in environmental research
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    • v.5 no.4
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    • pp.251-262
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    • 2016
  • The biodegradability and decomposition efficiencies increase with the pre-treatment of sludge in a digestion process. In this study, the feasibility of ultrasound coupled with potassium permanganate oxidation as a disintegration method and digestibility of aerobic reactor fed with disintegrated sludge with ultrasound coupled potassium permanganate were investigated. The first stage of the study focused on determining the optimum condition for ultrasonic pre-treatment for achieving better destruction efficiency of sludge. The second part of the study, the aerobic digestibility of sludge disintegrated with ultrasound and potassium permanganate oxidation alone and combined were examined comparatively. The results showed that when 20 min of ultrasonic pre-treatment applied, the specific energy output was 49384 kJ/kgTS with disintegration degree of 58.84%. During the operation of aerobic digester, VS/TS ratios of digesters fed with disintegrated sludge decreased indicating that disintegration methods could obviously enhance aerobic digestion performance. The highest reduction in volatile solids was 75% in the digester fed with ultrasound+potassium permanganate disintegrated sludge at the end of the operation compared to digester fed with raw sludge. Total Nitrogen (TN) and Total Phosphorus (TP) levels in sludge supernatant increased with this combined method significantly. Besides, it promoted the production of ${\bullet}OH$, thus enhancing the release of Carbon (C), Nitrogen (N) and Phosphorus (P) from the sludge. Disintegration with all methods used in this study could not improve Capillary Suction Time (CST) reduction in disintegrated digesters during the operation. The results demonstrated that the combined ultrasound treatment and potassium permanganate oxidation method improves the biodegradability compared to control reactor or their single application.

Biodegradation of Poly (3-hydroxybutyrate) by Penicillium pinophilum (Penicillium pinophilum에 의한 Poly (3-hydroxybutyrate)의 생분해)

  • Kim, Mal-Nam;Kang, Eun-Jung
    • The Korean Journal of Mycology
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    • v.23 no.4 s.75
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    • pp.348-353
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    • 1995
  • Biodegradability of poly (3-hydroxybutyrate) (PHB) by Penicillium pinophilum was investigated by the modified Sturm Test. The biodegradability measurement by this method was more reproducible than other conventional activated sludge methods. Optimum inoculum size for the PHB biodegradation was 1% (v/v). The degradation appeared to occur not only on the sample surface but also inside the sample because the biodegradation did not increase quite proportionally with the sample surface area. The biodegradation rate increased to an asymptotic value as the nitrogen content in the test medium increased, indicating the nitrogen source was needed for the synthesis of the PHB depolymerase.

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Effect of Surface Roughness on Biodegradability of Poly (3-hydroxybutyrate) (Poly(3-hydroxybutyrate) 표면 형태가 생분해에 미치는 영향)

  • Kim, Mal-Nam;Lee, Ae-Ri
    • Korean Journal of Environmental Biology
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    • v.17 no.3
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    • pp.249-255
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    • 1999
  • The effect of surface roughness on biodegradability of poly (3-hydroxybutyrate) was investigated. The PHB film prepared by cooling the molten polymer slowly ($-0.5^{\circ}C$/min) had higher crystallinity and melting temperature than that prepared by quenching into liquid nitrogen followed by annealing at $90^{\circ}C$ for 2 hours. However, the former sample was found to degrade faster than the latter due to presence of microscopic crack. Roughening the surface of a PHB film by hot pressing under a coarse surfaced plate accelerated the bioerosion considerably of the sample in comparison with the sample having the same thermal history but smooth surface.

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The Effect of Nutrient Amendments on Biodegradability of Kerosene and Growth of Kerosene-degrading Microorganisms (영양원 변화가 Kerosene 분해율 및 분해균주 성장에 미치는 영향)

  • Chung, Kyu-Hyuck
    • Journal of Environmental Health Sciences
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    • v.25 no.3
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    • pp.7-12
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    • 1999
  • Bioremediation is the technology to harness nature's biodegradative capabilities to remove or detoxify pollutions that threaten public health as environmental contaminants. Composting may become one of major bioremediation technologies for treating soils contaminated with petroleum if the fate of contaminants during composting is better understood Most composting research of petroleum was primarily focused on removing contaminant by optimizing composting conditions. Accordingly, laboratory feasibility studies may be useful to establish a realistic basis in co-composting complex substrate such as petroleum hydrocarbons. The purpose of this study was to assess the optimal conditions of kerosene biodegradation following supplementation with nutrient amendments under simulated composting conditions. Although it increased the growth of bacterial consortium, addition of co-substrates 0.5%(w/v) such as acetic acid, citric acid, glucose, and malic acid was not beneficial. Combination of nitrogen and phosphorous source enhanced kerosene biodegradation and reduced VOC evolution. These results showed that kerosene was able to utilize in bioremediation technology.

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Effects of media weight and pre-ozonation on the biodegradability enhancement in biological fluidized bed (생물활성탄 유동상법에서 충전량과 전오존처리가 생물처리효율에 미치는 영향)

  • 우달식;곽필재;남상호
    • Journal of environmental and Sanitary engineering
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    • v.12 no.1
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    • pp.69-75
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    • 1997
  • Biological drinking water treatment is widely used in Europe for the removal of ammonia nitrogen and organics. During the last 16 years, the deterioration of the quality of surface waters used to produce drinking water has resulted in the widespread use of ozone-biological treatment in Korea. This study were conducted to determine the effect of media weight and preozonation on the biodegradability enhancement in biological fluidized bed(BFB) using Han river water. When the carbon weight was increased, $NH_{3}-N$ and DOC removal increased, but turbidity and SS removal decreased. To remove turbidity and SS, the bed depth in 40% expansion rate/total bed depth was very important. Preozonation of raw water was not effective in $NH_{3}-N$, but increased in biodegradable organic fraction about 10-30% with 0.425-0.85 mg $O_{3}/mg$ DOC.

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