• Title/Summary/Keyword: neutral response

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The Potentiometric Studies on the Effects of Various Functional Groups in Disiloxane as an Anion-Selective Ionophore

  • Jung, Hyo-Jin;Lee, Myong-Euy;Lim, Chae-Yun;Paeng, Ki-Jung
    • Bulletin of the Korean Chemical Society
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    • v.26 no.1
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    • pp.57-62
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    • 2005
  • The potentiometric responses for various anions are investigated with membrane electrode (membrane 1) based on 1,3-diethyl-1,3-dihydroxy-1,3-bis(2-dimethylaminomethyl ferrocenyl) disiloxane. The nitrate ion-selective electrode based on compound 1 gave a good Nernstian response of 58.18 mV per decade for nitrate with the detection limit of −e5.66 of log [NO3−e]. Compound 1 has all those functional groups and the other two compounds have less functional group of ferrocenyl or ferrocenyl and hydroxide, respectively. Even though, potentiometric response to anions was excellent at pH 5, the selectivity pattern for all three membrane electrode based on series of disiloxane is almost like Hofmeister sequence at pH 5. However, the membrane electrode 1-3 exhibited very different response to anions at pH 7. In this pH, NH2 is not protonated and ionophore may act as neutral carrier. Hydrogen bond may enhance the responsibility to hydrogen acceptors and intramolecular electro-active site may increase the permeability of analyte to ionophore in membrane.

The Potentiometric Performance of Mercury (II) Ion-Selective Electrode Based on Tetracycline Antibiotics

  • Baek, Jong-Gyu;Rhee Paeng, In-Sook
    • Journal of the Korean Electrochemical Society
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    • v.11 no.1
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    • pp.59-63
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    • 2008
  • Poly (vinylchloride) (PVC) membrane electrodes based on neutral carrier, tetracycline was prepared as an active sensor for Hg(II) ion, and tested in different contents of the potassium tetrakis (4-chlorophenyl) borate (KTpClPB) as lipophilic salt. Bis (2-ethylhexyl) sebacate (DOS), bis(l-butylpentyl) adipate (BBPA), 2-nitrophenyl octyl ether (NPOE) and dibutyl phthalate (DBP) were used as diverse plasticizing solvent mediators. This electrode shows excellent potentiometric response characteristics and display good linearity with log $[Hg^{+2}]$ versus EMF response, over a range of concentrations between $10^{-7}$ and $10^{-3}M$. With 30.8mV/decade Nernstian slope, the detection limit was $6.9{\times}10^{-9}M$ and the response time was less than 20s. The proposed electrode yields very good selectivity for mercury (II) ion over many cations such as alkali, alkaline earth, transition and heavy metal ions. And it shows a very stable potential values in a wide pH range. This reliable electrode prepared was kept at least a month without considerable alteration in their response to Hg (II) ion.

A Scheme of EDTC Control using an Induction Motor Three-Level Voltage Source Inverter for Electric Vehicles

  • Zaimeddine, R.;Berkouk, E.M.;Refoufi, L.
    • Journal of Electrical Engineering and Technology
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    • v.2 no.4
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    • pp.505-512
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    • 2007
  • The object of this paper is to study a new control structure for sensorless induction machines dedicated to electrical drives using a three-level voltage source inverter VSI-NPC. The amplitude and the rotating speed of the flux vector can be controlled freely. The scheme investigated is an Enhanced direct torque control "EDTC" for electric vehicle propulsion. The considered application imposes some constraints which are achieved in EDTC control (fast torque response, optimal switching logic, torque control at zero speed, and large speed control. The results obtained for an induction motor indicate superior performance over the FOC type without need for any mechanical sensor.

A Study on the Modeling of Transient Response in Automated Manual Transmission for Hybrid Trucks

  • Park, Kyung-Min;Ko, Young-Jin
    • Journal of Power System Engineering
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    • v.17 no.5
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    • pp.128-137
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    • 2013
  • Modern transmission technologies such as automated manual transmission(AMT) and dual clutch transmission(DCT) are interested to all manufactures due to their fuel efficiency and driver's convenience, especially in a hybrid system. AMT has advantages in that they have a high efficiency of manual transmissions(MT) and offer operation convenience similar to automatic transmissions(AT), but it has some disadvantages in that they have torque gap during gear shift and shift time. To reduce disadvantages, it is necessary to evaluate errors and characteristics as a developing simulation model before experimental verification. The purpose of this study is to develop virtual components and simulate the transient response of AMT. A dynamic AMT model and a control logic for an integrated vehicle model have been developed using Matlab/Simulink as a simulation platform. In this paper, the clutch model to describe the stick-slip transition mode and the transmission model to describe the neutral gear shifting is introduced and compared with each other.

Control Strategy of Improved Transient Response for a Doubly Fed Induction Generator in Medium Voltage Wind Power System under Grid Unbalance

  • Han, Daesu;Park, Yonggyun;Suh, Yongsug
    • Proceedings of the KIPE Conference
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    • 2013.07a
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    • pp.246-247
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    • 2013
  • This paper investigates control algorithms for a doubly fed induction generator with a back-to-back three-level neutral-point clamped voltage source converter in medium voltage wind power system under unbalanced grid conditions. Control algorithms to compensate for unbalanced conditions have been investigated with respect to four performance factors; fault ride-through capability, instantaneous active power pulsation, harmonic distortions, and torque pulsation. The control algorithm having zero amplitude of torque ripple shows the most cost-effective performance concerning torque pulsation. The least active power pulsation is produced by control algorithm that nullifies the oscillating component of the instantaneous stator active and reactive power. Combination of these two control algorithms depending on the operating requirements and depth of grid unbalance presents most optimized performance factors under the generalized unbalanced operating conditions leading to high performance DFIG wind turbine system. The proposed control algorithms are verified through transient response in the simulation.

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A Study on Development of Over-load Fault Prevention Apparatus using Distribution Line Voltage (배전선로 선로전압을 이용한 과부하 사고 예방장치 개발에 관한 연구)

  • Kwak, D.K.;Park, D.H.;Park, Y.J.;Jung, D.Y.;Kim, D.K.
    • Proceedings of the KIPE Conference
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    • 2012.07a
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    • pp.617-618
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    • 2012
  • Recently as the inactive response characteristics of the existing RCD(Residual Current protective Device) used on low voltage power distribution system, so control of overload and electric short circuit faults, major causes of electrical fires, are not enough. Therefore, this paper is proposed a prevention apparatus using neutral line voltage and semiconductor switching devices for the prevention of electrical disasters in low voltage power distribution system caused by overload or electric short circuit faults. The proposed prevention apparatus confirms the excellent characteristics in response velocity and accuracy in comparison with the conventional circuit breaker(RCD) through various operation performance analysis.

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Development of HST electronic control system for combine (II)- Outdoor tests for control Characteristics - (콤바인 HST 전자제어시스템 개발- 제어특성 실외시험 -)

  • Seo, Sin-Won;Huh, Yun-Kun;Lee, Je-Yong;Lee, Chang-Kyu;Bae, Keun-Soo
    • Korean Journal of Agricultural Science
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    • v.38 no.1
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    • pp.121-128
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    • 2011
  • I/An electro-hydraulic transmission having advantages of convenience, safety, simple linking and high power, and an electronic control system were designed and fabricated. In this study, characteristics of the control system were investigated through outdoor tests for evaluation of installation of the system on a combine. Major findings were as followings. 1. Experiment for performance evaluation of the control system was conducted on concrete road. With steering lever in neutral position, driving HST swash plate and left/right wheel speed increased in proportion to driving lever angle. In case of steering control, steering swash plate angle changed in proportion to steering lever angle. This should cause increase in outer wheel speed, but it was observed that HST swash plate was controlled toward neutral to maintain the speed before steering. As a result, speed before steering was maintained despite the change in outer wheel speed by steering HST swash plate angle change. 2. It was observed that the HST system enabled steering with outer wheel maintained at constant speeds while inner wheel speed decreased, which was more stable than conventional mechanical links. In addition, for the selected 5 criteria, experiment showed satisfactory results and it was judged that installation on real vehicle would be feasible. 3. The control system showed response property of appropriate forward/reverse movement and lift/right steering, without causing any problems during experiment on concrete. Result of response property experiment on field operation also showed appropriate control over forward/reverse movement and left/right steering.

A hydrogen ion-selective membrane electrode based on N,N,N,N-Tetrabenzylethylenediamine as neutral carrier (N,N,N,N-Tetrabenzylethylenediamine 중성운반체를 이용한 수소 이온 선택성 막전극)

  • Jeong, Seong-Suk;Park, Myon-Yong;Chung, Koo-Chun;Cho, Dong-Hoe;Lee, Kyeong-Jae;Kim, Jae-Woo
    • Analytical Science and Technology
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    • v.8 no.2
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    • pp.187-193
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    • 1995
  • A PVC membrane ion-selective electrodes based on N,N,N,N-tetrabenzylethylenediamine as neutral carrier has been prepared by addition of plasticizers such as phthalates and sebacate and liphophillic additives such as NaTPB. The membrane electrodes were investigated to the electric resistance, response range to hydrogen ion and the interfering effect of alkali and alkline earth metals. A electric resistance hardly had on effect of plasticizers. In case of 0.7% NaTPB added to membrane, response of the electrodes were shown the values near to theoretical Nernstian slope and interferences by alkali and alkaline earth metal were few influenced. The performances of pH-selective electrodes were shown linerality to hydrogen ion between pH 2 and 10 in the presense of alkali and alkaline earth ions. Reproducibility and stability tests were shown good results in the same pH range.

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Legitimacy of the wartime maritime blockade of the Korean Peninsula : Focusing on the response to ships in neutral countries (전시 한반도 근해 해상봉쇄의 합법성: 중립국 선박에 대한 대응을 중심으로)

  • Park, Hyun-rok
    • Maritime Security
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    • v.5 no.1
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    • pp.85-112
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    • 2022
  • The maritime blockade has long been used as a means of war in that it serves as a bridge for economic warfare by paralyzing enemy maritime transport, although it is not a decisive battle, and in the Korean War, U.N. forces have achieved significant results in the war with limited maritime blockade through the Clark Line. However, with China emerging as a maritime powers based on its strong naval power, there is a lack of consideration on how to set up a blockade to block maritime activities and how to respond neutral ships or carrying wartime contraband products if war breaks out again on the Korean Peninsula, In addition, since maritime blockade should be used as a sensitive and flexible naval force projection in that it has interests with neutral countries, it should be carefully reviewed in that it can be used only through careful and reasonable judgment considering the principle of ensuring the legality of maritime blockade Therefore, in this study, Reexamine the process of change in the application of the International Law of Blockade, and through this, Derive the basic principle of ensuring the legitimacy of maritime blockade. In addition, by reviewing the application of these basic principles in the waters off the Korean Peninsula at wartime, we presented answers to research questions by reviewing what needs to be done to neutral ships and ships carrying wartime contraband products, and considered the implications for us

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Potentiometric Determination of Postssium Ion Using 15-Crown-5 Derivatives with Anthracene for the Selective Material (안트라센을 포함하는 15-Crown-5 유도체를 이온선택성 물질로 이용한 칼륨이온의 전위차법 정량)

  • Bae, Zun-Ung;Lee, Sang-Bong;Chang, Seung-Hyun;Kim, Ui-Rak
    • Journal of the Korean Chemical Society
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    • v.45 no.1
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    • pp.31-39
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    • 2001
  • Newly synthesized 15-Crown-5 derivatives including anthracene were used as neutral carriers for ion selective electrodes to determine potassium ion by potentiometry. Among the five neutral carriers studied in this work, N-(4'-benzo-15-crown-5-ether)-anthracene-9-imine was found to be the best in terms of selectivity and stability. The optimal composition of ion selective membrane was 1.0, 33.0 and 66.0 wt% for neutral carrier, PVC and plasticizer, resperctively. Addition of KTpCIPB used as a lipophilic additive improved the Nernst slope and the selectivity of potassium ion over alkali and alkaline earth metals. Especially, the selectivity of potassium ion over ammonium ion was remarkably good ($logK^{pot}_(K^+,NH_4^+}$=-2.59). The response time was also excellent ($t_{100}$=5sec) and continuous use of this electrode for three weeks has not changed the selectivity and analytical characteristics.

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