• Title/Summary/Keyword: negative emission

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탄소 음이온 빔에 의해 증착된 DLC 필름의 특성 평가

  • 김인교;김용환;이덕연;최동준;한동원;백홍구
    • Proceedings of the Korean Vacuum Society Conference
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    • 1999.07a
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    • pp.59-59
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    • 1999
  • DLC(diamond-like carbon)필름은 다이아몬드와 유사한 강도, 낮은 마차계수, 높은 Optical band gap, NEA(negative electron affinity)등의 우수한 특성을 가지고 있어, 내마모 코팅이나 정보저장 매체의 윤활 코팅, FED(field emission display)의 전계방출소자등 다양한 분야에의 응용이 연구되고 있다. DLC 필름은 PECVD(plasma enhanced chemical vapor deposition), IBAD(ion beam assisted deposition), Laser ablation, Cathodic vacuum arc등의 process를 이용하여 증착되고 있다. 특히 이러한 필름의 물성은 입사되는 이온의 에너지에 의해 좌우되는데, Lifshitz 등의 연구에 의하여 hyperthermal species를 이용한 DLC 필름의 성장은 초기에 subsurface로의 shallow implantation이 일어난 후 높은 sp3 fraction을 갖는 필름이 연속적으로 성장한다는 subplantation model이 제시 되었다. 본 연구에서는 기판과 subplantation 영역이 이후 계속하여 증착되는 순수 DLC 필름의 특성 변호에 미치는 영향에 대하여 관심을 가지고 실험을 행하였다. 본 실험에서는 상기 제시되어 있는 방법보다도 더욱 정확하고도 독립적으로 탄소 음이온의 에너지와 flux를 조절할 수 있는 Cs+ ion beam sputtering system을 이용하여 탄소 음이온의 에너지를 40eV에서 200eV까지 변화시키며 필름을 증착하였다. Si(100) 웨이퍼를 기판으로 사용하였고 증착 압력은 5$\times$10-7torr 였으며 인위적인 기판의 가열은 하지 않았다. 또한 Ion beam deposited DLC film의 growth process를 연구하기 위하여 200eV의 탄소 음이온을 시간(증착두께)을 변수로 하여 증착하였고, 이 때에는 Kaufman type의 gas ion beam을 이용하여 500eV의 Ar+ ion으로 pre-sputering을 행하였다. 탄소 음이온의 에너지와 증착두께에 따라 증착된 film 내의 sp3/sp2 ratio 의 변화를 XPS plasmon loss 와 Raman spectra를 이용하여 분석하였다. 또한 증착두께에 따른 interlayer의 결합상태를 관찰하기 위하여 AES와 XPS 분석을 보조로 행하였다.

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Analysis of Carbonyl Compounds using DNPH Cartridge with LC-MS (DNPH cartridge/LC-MS 방법에 의한 카르보닐화합물 분석에 관한 연구)

  • Cho Deok-Hee;Song Il-Seok
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.2
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    • pp.201-208
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    • 2006
  • Several carbonyl compounds are important because of their irritant and toxic properties, mutagenicity and carcinogenicity. Therefore, they are regulated in korean odor emission standard. In this study, atmospheric pressure ionization-mass spectrometry(API-MS) is used for the analysis of carbonyl compounds after derivatization with 2, 4-dinitrophenylhydrazine (DNPH) and liquid chromatographic separation. In the negative ion mode, the $[M-H]^-$ pseudomolecular ions are most abundant for the carbonyls. Analytical parameters such as linearity, repeatability and minimum detection limit were evaluated. The linearities ($r^2$) for carbonyls were $0.9977{\sim}0.9999$ when analyte concentration ranges from $25\;to\;250{\mu}g/L$(n=6). The relative standard deviations (%RSD) for carbonyls were $0.55{\sim}3.51%$ for concentration of $100{\mu}g/L$(n=5). The minimum detection limit (MDL) was $1.88{\mu}g/L$(0.27 ppb) for i-valeraldehyde. It was shown that LC-MS method has a great potential for carbonyl compounds analysis.

Manufacturing of Wood Charcoal Cup by Using Carbonization Method and Its Water Repellency (목재를 이용한 무할렬 숯잔 제조 및 발수특성)

  • Park, Sang Bum;Lee, Min
    • Journal of the Korea Furniture Society
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    • v.25 no.3
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    • pp.207-212
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    • 2014
  • With increased interests in environmental issues, people are looking for new materials that serve special and bio-activated functions. One of interesting materials is charcoal which has excellent adsorption ability for harmful volatile organic compounds, fireproof performance, far-infrared ray emission, and electromagnetic shielding. Since non-crack carbonized board was developed from wood-based composite materials, carbonization method might be applied to woodcraft products such as wood cup and bamboo. In this study, manufacture of wood charcoal bowl was conducted with carbonization method developed in 2009 in order to activate wood products market. Ash tree(Fraxinus rhynchophylla) cup was carbonized at $600^{\circ}C$ with two pretreatments which were phenol resin and wood tar solution treatment. After carbonization of ash tree cup, non-crack charcoal cup were successfully manufactured. Phenol resin treatment affected on charcoal cup manufacturing both positively and negatively. For a positive way, it prevented shrinkage. For a negative way, it decreased water repellency. On the contrary, wood tar treatment accelerated shrinkage a bit and increased water repellency. Based on the results, wood tar can be used as pre-treatment solution for reducing post-treatment costs. We confirmed woodcraft products can be carbonized without deformation, so carbonization may provide a high value-added products from wood.

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Submicrometer Particle Size Distribution of Emissions from Diesel Engines (디젤엔진에서 배출되는 미세 입자의 크기 분포)

  • 김민철;권순박;이규원;김종춘;류정훈;엄명도
    • Journal of Korean Society for Atmospheric Environment
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    • v.15 no.5
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    • pp.657-665
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    • 1999
  • Particulate matter produced by diesel engines is of concern to cngine manufactures because of its environmental impact. The majority of diesel particles are in the range of smaller than 1 ${\mu}{\textrm}{m}$. Because of their tiny volume, ultrafine diesel particles contribute very little to the total mass concentration which is currently regulated for automobile emissions. Ultrafinc particles are known to have deleterious effects upon human health cspecially because they penetrate deeply human respiratory tract and have negative effects on the health. In this study, the engine exhaust gas was diluted in a dilution tunnel and the particle size distribution was measured using the scanning mobility particel sizer system. Measurements of the number and the mass concentrations of the diesel exhaust were made under different engine ooperating conditions. The dilution sampling system provided a common basis for collection of the exhaust by cooling and diluting the source emission prior to the measurement. The measurement results showed that the particle size distributions of the exhaust from the diesel vehicles equipment with either heavy-duty or lignt-duty diesel engines, were similar in the particle size range of 0.08~0.2${\mu}{\textrm}{m}$.

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Changes in air pollutant emissions from road vehicles due to autonomous driving technology: A conceptual modeling approach

  • Hwang, Ha;Song, Chang-Keun
    • Environmental Engineering Research
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    • v.25 no.3
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    • pp.366-373
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    • 2020
  • The autonomous vehicles (AVs) could make a positive or negative impact on reducing mobile emissions. This study investigated the changes of mobile emissions that could be caused by large-scale adoption of AVs. The factors of road capacity increase and speed limit increase impacts were simulated using a conceptual modeling approach that combines a hypothetical speed-emission function and a traffic demand model using a virtual transportation network. The simulation results show that road capacity increase impact is significant in decreasing mobile emissions until the market share of AVs is less than 80%. If the road capacity increases by 100%, the mobile emissions will decrease by about 30%. On the other hand, driving speed limit increase impact is significant in increasing mobile emissions, and the environmentally desirable speed limit was found at around 95 km/h. If the speed limit increases to 140 km/h, the mobile emissions will increase by about 25%. This is because some vehicles begin to bypass the congested routes at high speeds as speed limit increases. Based on the simulation results, it is clear that the vehicle platooning technology implemented at reasonable speed limit is one of the AV technologies that are encouraging from the environmental point of view.

Pulsar observation with KVN

  • Kim, Chunglee;Dodson, Richard;Jung, Taehyun;Sohn, Bong Won
    • The Bulletin of The Korean Astronomical Society
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    • v.39 no.1
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    • pp.52.1-52.1
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    • 2014
  • Radio pulsars are highly magnetized, rapidly rotating neutron stars that emit synchrotron radiation along the magnetic axes at their spin frequencies. Traditionally, pulsar observations have been done at low frequencies (MHz up to a few GHz), since radio pulsar spectrum is known to a power-law with a steep negative spectral index. More recently, high-frequency pulsar observations (several GHz and above) have been made as a broadband spectrometer and fast computers became available. High-frequency pulsar observations will provide information on radio emission mechanism of pulsars in the vicinity of the neutron star surface. There is also huge interest from gravitational-wave and astrophysics community to find a pulsar in the center of our Galaxy. The Korean VLBI Network has three 21-m single dishes in the Korean peninsula. Using KVN's lowest observational frequency of 22-GHz, we performed test observations with the KVN targeting a few selected known, bright pulsars. In addition, we have been developing pulsar pipelines that can be utilized with a VLBI facility using Mark-V. We present a brief introduction of radio pulsars and show data obtained with the KVN.

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Electron Injection Mechanisms Varied by Conjugated Polyelectrolyte Electron Transporting Layers in Polymer Light-Emitting Diodes (고분자 발광다이오드에서 공액고분자 전해질 전자수송층에 의해 변화되는 전자주입 메카니즘)

  • Um, Seung-Soo;Park, Ju-Hyun
    • Polymer(Korea)
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    • v.36 no.4
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    • pp.519-524
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    • 2012
  • Capacitance measurements of the polymer light-emitting diodes (PLEDs) with conjugated polyelectrolyte (CPE) electron transporting layers (ETLs) provide important information of device physics for understanding the function of CPEs as ETLs, together with current density-voltage-luminescence measurements. We investigated the counterion-dependent capacitance behaviors that present a highly negative or positive capacitance at the low frequency, and suggested different carrier injection mechanisms. Capacitance model study reveals that the electron injection mechanism can be described either by the dipole alignment scheme or by electronic charge carrier accumulation at the cathode/ETL/emission layer interfaces.

Extraction of the shape feature according to the risk area of the segmented tumor region based on the small-animal PET (소동물 PET기반 종양분할영역 위험구간변화에 따른 형태특성추출)

  • Lee Joung-Min;Kim Hyeong-Min;Kim Myoung-Hee
    • Proceedings of the Korean Information Science Society Conference
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    • 2006.06b
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    • pp.376-378
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    • 2006
  • 본 논문에서는 소동물 양전자방출단층촬영 영상(Positron Emission Tomography, PET) 내 종양영역을 자동분할하고 분할된 윤곽선주변의 기하학적 위험구간에 따른 종양의 형태특성을 분석하기 위한 방법을 제시한다. PET 영상내 검출된 종양영역의 신뢰성을 위해 위음성(False negative, FN) 및 위양성(False positive, FP)의 위험구간을 같이 제공하는 것이 필요하다. 따라서, 방사선 특이적 특성이 반영된 명암값을 기반으로 Fuzzy C-Means(FCM) 클러스터링을 수행하여 종양영역을 자동 분할한다. 분활된 종양영역의 위험구간은 클러스터 간 공유되는 영역의 소속값을 이용하여 위음성, 위양성을 계산한다. 또한, 임의의 소속값 임계치 변화를 통해 위험구간의 변화에 따른 종양의 형태적 특성변화를 관측한다. 이러한 지역적 변화의 관측을 통해 위험구간의 형태학적 위치를 판단할 수 있어 위험구간에 따른 추가적인 잔여 암의 위치 및 형태 파악을 용이하게 한다.

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The discharge characteristics for various electrode shapes under negative high-voltagein in Liquid $SF_6$ ((-)전압 인가시 액체 $SF_6$의 전극형상에 따른 절연파괴특성)

  • Choi, Eun-Hyuck;Park, Kwang-Seo;Kim, Lee-Kook;Lee, Kwang-Sik;Do, Dae-Ho;Kim, Jong-Whan
    • Proceedings of the KIEE Conference
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    • 2005.07c
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    • pp.2085-2087
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    • 2005
  • In this paper the experiments of insulation characteristics by temperature change of $SF_6$ gas and liquid $SF_6$ in model GIS(Gas Insulated Switchgear) were described. From this results, the breakdown voltage was increased with a drop of temperature and an increase of the inner pressure in model GIS. The ability of insulation in liquid $SF_6$ was higher than that of the highly pressurized $SF_6$ gas. A liquid $SF_6$ discharge characteristics was caused by bubble formed evaporation of liquid $SF_6$ and bubble caused by high electric emission. It is considered that these result are fundamental data for electric insulation design of superconductor and cryogenic application machinery which will be studied and developed in the future.

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Clinical Experience of Basosquamous Cell Carcinoma (기저편평세포암의 치험례)

  • Kim, Hyun-Sung;Kim, Chul-Han
    • Archives of Plastic Surgery
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    • v.38 no.4
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    • pp.490-493
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    • 2011
  • Purpose: Basosquamous carcinoma is a rare malignancy, with features of both basal cell carcinoma and squamous cell carcinoma. It is considered as aggressive tumor with a high risk of recurrence and metastases. Authors report a case of basosquamous cell carcinoma. Methods: A 72 year-old man, who had an erythematous ulcer on his left auricle, described a slow growing lesion, starting at the posterior surface of the superior helix with a steady increase in size during the past 10 years. At operation, auricular cartilage was grossly invaded by the tumor and was, therefore, amputated with tumor-free margins. Results: Histopathologic examination was revealed a basosquamous cell carcinoma. On positron emission tomography/computed tomography (PET/CT) and neck CT were negative for signs of further nodal involvement or metastases to other organs. At follow-up 6 months later, his wounds were noted to be well healed, with no evidence of local recurrence or identifiable metastases. Conclusion: Because basosquamous cell carcinoma has a significant potential to recur and metastasize, surgical excision for this type of carcinoma should be more extensive than that performed for conventional basal cell carcinoma or squamous cell carcinoma. In addition, regional lymph nodes should be monitored and close follow-up should be carried out.