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High Thermal Conductive Natural Rubber Composites Using Aluminum Nitride and Boron Nitride Hybrid Fillers

  • Chung, June-Young;Lee, Bumhee;Park, In-Kyung;Park, Hyun Ho;Jung, Heon Seob;Park, Joon Chul;Cho, Hyun Chul;Nam, Jae-Do
    • Elastomers and Composites
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    • v.55 no.1
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    • pp.59-66
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    • 2020
  • Herein, we investigated the thermal conductivity and thermal stability of natural rubber composite systems containing hybrid fillers of boron nitride (BN) and aluminum nitride (AlN). In the hybrid system, the bimodal distribution of polygonal AlN and planar BN particles provided excellent filler-packing efficiency and desired energy path for phonon transfer, resulting in high thermal conductivity of 1.29 W/mK, which could not be achieved by single filler composites. Further, polyethylene glycol (PEG) was compounded with a commonly used naphthenic oil, which substantially increased thermal conductivity to 3.51 W/mK with an excellent thermal stability due to facilitated energy transfer across the filler-filler interface. The resulting PEG-incorporated hybrid composite showed a high thermal degradation temperature (T2) of 290℃, a low coefficient of thermal expansion of 26.4 ppm/℃, and a low thermal distortion parameter of 7.53 m/K, which is well over the naphthenic oil compound. Finally, using the Fourier's law of conduction, we suggested a modeling methodology to evaluate the cooling performance in thermal management system.

Finite element based dynamic analysis of multilayer fibre composite sandwich plates with interlayer delaminations

  • Jayatilake, Indunil N.;Karunasena, Warna;Lokuge, Weena
    • Advances in aircraft and spacecraft science
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    • v.3 no.1
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    • pp.15-28
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    • 2016
  • Although the aircraft industry was the first to use fibre composites, now they are increasingly used in a range of structural applications such as flooring, decking, platforms and roofs. Interlayer delamination is a major failure mode which threatens the reliability of composite structures. Delamination can grow in size under increasing loads with time and hence leads to severe loss of structural integrity and stiffness reduction. Delamination reduces the natural frequency and as a consequence may result in resonance. Hence, the study of the effects of delamination on the free vibration behaviour of multilayer composite structures is imperative. The focus of this paper is to develop a 3D FE model and investigate the free vibration behaviour of fibre composite multilayer sandwich panels with interlayer delaminations. A series of parametric studies are conducted to assess the influence of various parameters of concern, using a commercially available finite element package. Additionally, selected points in the delaminated region are connected appropriately to simulate bolting as a remedial measure to fasten the delamination region in the aim of reducing the effects of delamination. First order shear deformation theory based plate elements have been used to model each sandwich layer. The findings suggest that the delamination size and the end fixity of the plate are the most important factors responsible for stiffness reduction due to delamination damage in composite laminates. It is also revealed that bolting the delaminated region can significantly reduce the natural frequency variation due to delamination thereby improving the dynamic performance.

Adhesion Performance of Natural Rubber-based Pressure-Sensitive Adhesives for Protecting of Opto-functionalized Sheet (광기능성시트 보호용 천연고무계 점착제의 점착 물성)

  • Park, Young-Jun;Lim, Dong-Hyuk;Kim, Hyun-Joong;Song, Hyun-Suk;Kwon, Hyuk-Jin
    • Journal of Adhesion and Interface
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    • v.8 no.2
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    • pp.15-21
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    • 2007
  • To prepare a natural rubber-based pressure-sensitive adhesive (PSA) for protection film of opto- functionalized sheet, natural rubber (NR) was blended with a DCPD type tackifier and three types of aliphatic hydrocarbon resins, respectively. Also, to supply low cohesion strength of NR, in the fixed ratio of tackifier, synthetic rubber, styrene-isoprene-styrene (SIS) block copolymer was blended with NR as a function of SIS contents. PSA performance of prepared PSAs was evaluated using probe tack and peel strength. Probe tack of NR/tackifier blends was increased with increasing tackifier contents, and showed maximum peak. In addition, probe tack of NR/tackifier blends slightly increased with increasing softening point of aliphatic hydrocarbon resins. Their peel strength increased up to 50 wt% of tackifier contents, but in the over contents of tackifier, they showed stick-slip failure mode. Finally, probe tack of NR/SIS/tackifier blends showed the maximum values at 20~40 wt% of tackifier contents, but at 20 wt% of tackifier contents, they showed fibrillation. For this reason, peel strength showed maximum values at 40 wt% of tackifier contents.

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Mechanical Properties of Cellulose-filled Epoxy Hybrid Composites Reinforced with Alkali-treated Hemp Fiber (염기 처리 대마 섬유로 강화된 셀룰로오스 충전 에폭시 하이브리드 복합재의 기계적 물성)

  • Anand, P.;Anbumalar, V.
    • Polymer(Korea)
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    • v.39 no.1
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    • pp.46-55
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    • 2015
  • There is a limit for deforestation in order to keep the environmental cycle undisturbed. The heart of the paper is to replace the wood to a maximum extent to obtain a sustainable environment. This research aims at new natural composites in which treated hemp fiber used as reinforcement, synthetic cellulose used as particulate to improve the adhesion between matrix - fiber interface and Epoxy LY556 acted as matrix fabricated by hand layup technique. The density, water absorption, tensile properties, impact strength, hardness, flexural properties and compressive properties have been evaluated under ASTM standards and compare the results with existing materials such as wood, aluminium, etc., The composite hemp fiber reinforced polymer (HFRP) could be exploited as an effective replacement for wood and it would be suitable for automotive applications by comparing results.

COMPOSITES IN CONSTRUCTION : Size/scale Effects in Failure Theory (건설에서의 복합재료 : 파괴강도에 대한 치수효과)

  • Kim, Duk-Hyun;Kim, Du-Hwan;Oh, Sang-Sub;Lim, Tae-Ho
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2003.10a
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    • pp.187-189
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    • 2003
  • Almost all building/infrastructures made of composite materials are fabricated without proper design. Unlike airplane or automobile parts, prototype test is impossible. One cannot destroy 10 story buildings or 100-meter long bridges. People try to build 100-story buildings or several thousand meter long bridges. In order to realize "composites in construction", the following subjects must be studied in detail, for his design: Concept optimization, Simple method of analysis, Folded plate theory, Size effects in failure, and Critical frequency. Unlike the design procedure with conventional materials, his design should include material design, selection of manufacturing methods, and quality control methods, in addition to the fabrication method.on method.

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Algae Based Energy Materials (해조류를 이용한 친환경 에너지소재)

  • Han, Seong-Ok
    • New & Renewable Energy
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    • v.4 no.4
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    • pp.50-55
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    • 2008
  • Recently, sea algae cultivation as carbon sink and carbon dioxide fixation have been considered. Also, various researches on bioenergy derived from sea algae and the utilization of fibers, saccharide, and lipid of sea algae have been performing. Till now, algae fibers has been used for manufacturing of paper and reinforcing of polymer composites and the extracts of sea algae are used for cosmetics, pharmaceutical materials and food such as agar. Especially, algae fiber has so similar properties to cellulose in terms of crystallinity and functional groups that it can be utilized as reinforcements of biocomposites. Biocomposites as alternatives of glass fiber reinforced polymer composites are environmentally friendly polymer composites reinforced with natural fibers and are actively applying to the automobiles and construction industries. In this paper, characteristics of algae fiber and biocomposites reinforced with algae fiber as environmentally friendly energy materials have been introduced.

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COMPOSITES IN CONSTRUCTION - CONSTRUCTION WITH DESIGNED STRUCTURES II - (건설에서의 복합재료 -설계된 구조물을 사용한 건설 II-)

  • Kim, Duk-Hyun;Kim, Du-Hwan;Oh, Sang-Sub;Lim, Tae-Ho
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2003.04a
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    • pp.165-168
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    • 2003
  • Almost all buildings/infrastructures made of composite materials are fabricated without proper design. Unlike airplane or automobile parts, prototype test is impossible. One cannot destroy 10 story buildings or 100-meter long bridges. People try to build 100-story buildings or several thousand meter long bridges. In order to realize "composites in construction", the following subjects must be studied in detail, for his design: Concept optimization, Simple method of analysis, Folded plate theory, Size effects in failure, and Critical frequency. Unlike the design procedure with conventional materials, his design should include material design, selection of manufacturing methods, and quality control methods, in addition to the fabrication method.on method.

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Manufacturing and Properties of Bi-Sn Impregnated Wood Composites of Juglans nigra (북미산 흑호두나무 Bi-Sn 용융합금 복합체의 제조와 특성)

  • Kang, Seog-Goo;Park, Kye-Shin;Lee, Ho;Seo, In-Soo;Lee, Jong-Shin;Lee, Hwa-Hyoung
    • Journal of the Korea Furniture Society
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    • v.22 no.1
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    • pp.54-62
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    • 2011
  • The metalized wood composites with natural grain of imported Juglans nigra, which was impregnated with low melting alloy were manufactured and evaluated in this study. And the proper manufacturing conditions was also investigated in this study. The low melting alloy with bismuth (Bi) and tin (Sn) which are harmless to humans, was applied to this new composites. The composites showed not only no defects of discoloration, delamination, swelling, and cracking, because of high dimensional stability and low thickness swelling, but also much improved performance such as high bending strength, high hardness, abrasion resistance, high thermal conductivity as floor materials. This study also suggested the proper impregnating condition, such as 10 minutes of the preliminary vacuum time, $186^{\circ}C$ of the heating temperature and 10 minutes of the maintaining pressure time at the pressure of $30kgf/cm^2$. This metalized wood composites showed 7 times higher density than control, great increase in bending strength from $131.8N/mm^2$ to $192.3N/mm^2$, and great increase in hardness from $18.2N/mm^2$ to $90.4N/mm^2$. The composites demonstrated not only high emissivity of 91%, high shilding effectiveness of 92.59∼99.99%, high fire resistance but also great decrease in abrasion depth, water absorption and thickness swelling.

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A Study on Fire Resistance of Abaca/Vinyl-ester Composites (마닐라 삼/비닐에스터 복합재료의 내화성 연구)

  • Lee, Dong-Woo;Park, Byung-Jin;Song, Jung-Il
    • Composites Research
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    • v.30 no.1
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    • pp.59-64
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    • 2017
  • Eco-convivial composites with improved properties are essential to present polymer scenario and can be made easily by replacing partially/completely renewable materials either matrix or reinforcement along with few % of additives. In these investigations, Abaca fabric have been used as reinforcement for manufacturing of Vinyl ester composites through VARTM technique and study the effect of alkali surface treatment of abaca fabric and flame retardant additives i.e., ammonium polyphosphate (APP) with halloysite nano-clay (HNT) on mechanical and flame retardant properties. The results concluded that, surface treatment deceased the hydrophilic nature of fabric and enhanced the interfacial bonding with hydrophobic matrix and eventually increased mechanical properties slightly of developed composites. Similarly, the flame retardancy of the composites improved significantly and increases the burning time by varying the wt% of filler concentration.

Influence of the Vulcanization on the Dielectric Proper ties of the Ageing Natural Nubber (노화된 천연고무의 유전특성에 미치는 가황의 영향)

  • Kim, Bong-Heup;Kim, Wang-Kon;Lee, Joon-Ung
    • Elastomers and Composites
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    • v.21 no.3
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    • pp.205-212
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    • 1986
  • The dielectric properties of natural rubber are very important to investigate the molecular structure. The charcteristics of the dielectric absorption in aging natural rubber were studied in the range of frequency from $1{\times}10^3Hz\;to\;3.2{\times}10^7Hz$ at the temperature of $23^{\circ}C$. As the results, it has been confirmed that in the case of aged NR vulcanized specimen with contained sulfur 2 phr above the specimens exhibit two kind of dielectic losses due to the the dipole polarization by impurities and sulfurs, and of raw rubber exhibit the kind of losses due the to dipole polarization. Particularly, it has been affirmed that the dielectric loss spectrum of the aging natural rubber is larger than that the natural rubber, and the dielectric strength of the aging natural rubber drop depreciate respctively.

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