• Membrane Journal
• /
• 제24권1호
• /
• pp.69-77
• /
• 2014

To prepare the hollow fiber nanofiltration composite membranes, the poly(vinylidene fluoride) (PVDF) membrane was hydrophilized with $K_2Cr_2OH$ and $KMnO_4$ aqueous solutions. And then the composite membrane was synthesized on that membrane surfaces using interfacial polymerization with piperazine (PIP) and trimesoyl chloride (TMC). The resulting membranes were characterized in terms of the rejection and flux for NaCl, $CaSO_4$, $MgCl_2$ 100 ppm solution and 300 ppm of NaCl and $CaSO_4$ mixed solution by varying the coating time, drying time, and the concentration of the coating materials. As a result, the higher rejections were shown for $K_2Cr_2OH$ solutionas a hydrophilization material, and the flux was enhanced while the rejection reduced as the hydrophilization time is longer. Also, the rejection increased and the flux reduced as the concentrations of triethyl amine (TEA) and sodium lauryl sulfate (SLS) were higher. Typically, the rejection 50% and flux 40 LMH for NaCl 100 ppm solution, and the rejection 55% and flux 48 LMH for $CaSO_4$ 100 ppm solution were obtained for the PVDF hollow fiber composite membrane prepared with the conditions of PIP 2 wt% (Triethyl amine (TEA) 7 wt%, SLS 20 wt% mixed solution against PIP concentration) and TMC 0.1 wt%.

• Applied Chemistry for Engineering
• /
• 제24권5호
• /
• pp.456-470
• /
• 2013

Hollow-fiber membranes, is one of the new technologies that is growing rapidly in the past few decades. In addition, separation membranes using polymer materials, have attracted attentions in various fields including gas separation, fuel cells, water treatment, wastewater treatment, and organic separation. Nanofiltration (NF) membranes having the separation characteristics in the intermediate range between ultrafiltration and reverse osmosis (RO) membranes for liquid separation, with relatively low investment cost and operating pressure lower than that of RO membranes, have high permeance and rejection performance of multivalent ions as well as organic compounds of molecular weight between $200{\sim}1000gmol^{-1}$. In this paper, we would like to review the research trends on the various structure control and characterization of NF hollow fiber membranes with respect to materials and the methods of preparation (phase inversion method and interfacial polymerization method). Currently, most of NF membranes have been manufactured by plate and frame types or spiral wound types. But hollow fiber types have delayed in commercial products, because of the weak strength when to produce on the basis of the existing materials, therefore the development of new materials or improvement of existing materials will be needed. If improving manufacturing technology is available, hollow fiber types will replace spiral wound types and gradually show a higher market share.

• Journal of Korean Society of Environmental Engineers
• /
• 제27권2호
• /
• pp.158-162
• /
• 2005

The objective of this study was to assess the assimilable organic carbon (AOC) in processing water, a measurement of biostability, at several stages of a full-scale nanofiltration (NF) water treatment plant. The NF membrane plant investigated was a $45,400\;m^3$/day (12 mgd) water softening facility at Plantation City in southern Florida, which utilized an organic rich groundwater (dissolved organic carbon (DOC) = 17.6 mg/L) originated from a surficial aquifer. The average AOC concentration of raw feed water was estimated at 158 g/L acetate-C. After pretreatment(acid and antiscalant addition), AOC levels increased by 12.7%, suggesting that pretreatment chemicals used to control scaling may deteriorate feed water biostability. The results also demonstrated that nanofiltration was capable of effectively removing 63.4% of AOC and 94.8% of DOC from the raw water. AOC rejection in stage 1 (${\approx}\;68%$) was slightly higher than that of stage 2 (${\approx}\;58%$) indicating that AOC was removed less at the solution environment (i.e. low pH, high ionic strength and high hardness), which was often created in the $2^{nd}$ stage of full-scale membrane plants due to pretreatment (acid addition) and high recovery operation.

• Journal of Korean Society of Water and Wastewater
• /
• 제34권6호
• /
• pp.473-480
• /
• 2020

High-pressure membrane system like nanofiltration(NF) and reverse osmosis(RO) was investigated as a part of water treatment processes to produce high quality potable water with low organic matter concentration through membrane module tests and design simulation. River water and sand filtration permeate in Busan D water treatment plant were selected as feed water, and NE4040-90 and RE4040-Fen(Toray Chemical Korea) were used as NF and RO membranes, respectively. Total organic carbon(TOC) concentrations of NF and RO permeates were mostly below 0.5 mg/l and the average TOC removal rates of NF and RO membranes were 93.99% and 94.28%, respectively, which means NF used in this study is competitive with RO in terms of organic matter removal ability. Different from ions rejection tendency, the TOC removal rate increases at higher recovery rates, which is because the portion of higher molecular weight materials in the concentrated raw water with increasing recovery rate increases. Discharge of NF/RO concentrates to rivers may not be acceptable because the increased TDS concentration of the concentrates can harm the river eco-system. Thus, the idea of using NF/RO concentrate as the raw water for industrial water production was introduced. The design simulation results with feed water and membranes used in this work reveal that the raw water guideline can be satisfied if the recovery rate of NF/RO system is designed below 80%.

• Membrane and Water Treatment
• /
• 제8권1호
• /
• pp.89-112
• /
• 2017

Dyeing wastewaters are the most problematic wastewater in textile industries and also, growing amounts of waste fibers in carpet industries have concerned environmental specialists. Among different treatment methods, membrane filtration processes as energy-efficient and compatible way, were utilized for several individual problems. In this research, novel hybrid membranes were prepared by waste fibers of mechanical carpets as useful resource of membrane matrix and industrial graphite powder as filler to eliminate Chrysophenine GX from dyeing wastewater. These membranes were expected to be utilized for first stage of hybrid membrane filtration process including (adsorption-ultrafiltration) and nanofiltration in Kashan Textile Company. For scaling of membrane filtration process, fouling mechanism of these membranes were recognized and explained by the use of genetic algorithm, as well. The graphite increased rejection and diminished permeate flux at low concentration but in high concentration, the performance was significantly worsened. Among all hybrid membranes, 18% wt. waste fibers-1% wt. graphite membrane had the best performance and minimum fouling. The maximum pore size of this optimum membrane was ranged from 16.10 to 18.72 nm.

• Korean Membrane Journal
• /
• 제10권1호
• /
• pp.13-19
• /
• 2008

Water softening is a very promising field for membranes and especially ultra low pressure membranes. Nanofiltration membranes based on pore-filling technology was prepared by using a new technique: the in-situ cross-linking. This route involves introducing a pre-formed polymer into the pores of a host membrane and then locking the polymer in the pores by in-situ cross-linking with an appropriate reagent. By this way, it is possible to make robust and competitive, pore-filled, anion-exchange membranes with excellent control over the properties of the incorporated gel without affecting the host membrane. In this paper, the possibilities of tuning such membranes for ultra low pressure water softening was examined by altering pore-filling chemistry (by changing cross-linking and aminating reagents). The results showed that tuning the chemistry of the pore-filling has important effects. In particularly, it had been shown that the correct selection of cross-linking reagent was not only essential to get pore-filled membranes but it could control their properties. Moreover, the aminating reagent could improve membrane performance. It was found that an increase in hydrophobicity could improve the Darcy permeability.

• Membrane and Water Treatment
• /
• 제3권4호
• /
• pp.221-230
• /
• 2012

This study employed the modified fouling index (MFI) to determine the performance of a two-step recycling system - a membrane filtration integrated laminar flow water storage (LFWS) tank followed by an ion exchange process to reclaim ultrapure water (UPW) from the wastewater generated from semiconductor wafer backgrinding and sawing processes. The first step consisted of the utilization of either ultrafiltration (UF) or nanofiltration (NF) membranes to remove solids in the wastewater where the second step consisted of an ion exchanger to further purify the filtrate. The system was able to produce high purity water in a continuous operating mode. However, higher recycling cost could be incurred due to membrane fouling. The feed wastewater used for this study contained high concentration of fine particles with low organic and ionic contents, hence membrane fouling was mainly attributed to particulate deposition and cake formation. Based on the MFI results, a LFWS tank that was equipped with a turbulence reducer with a pair of auto-valves was developed and found effective in minimizing fouling by discharging concentrated wastewater prior to any membrane filtration. By comparing flux behaviors of the improved system with the conventional system, the former maintained a high flux than the latter at the end of the experiment.

• Proceedings of the Membrane Society of Korea Conference
• /
• 한국막학회 1994년도 추계 총회 및 학술발표회
• /
• pp.60-61
• /
• 1994

복합막은 기존의 비대칭막에 비해서 극히 얇은 표면층을 형성할 수 있다. 이러한 복합막은 배제율도 우수할 뿐만아니라 투과속도 또한 매우 큰 특징을 가지고 있으며, 해수의 담수화를 비롯하여 초순수 제조 등 각종 산업분야에서 많이 응용되고 있다. 우수한 분리막을 제조하기 위해서는 막의 표면층을 보다 더 치밀하고 얇게 형성할 수 있어야 한다. 이렇게 하기 위해서는 지지막 또한 매우 중요한 요인으로 작용한다. 표면층이 치밀하고, 가능한 한 porosity가 큰 지지막을 제조해야한다. 따라서 본 연구에서는 고분자 물질로 Polyethersulfone을 사용하여 지지막을 만들었다. 이 지지막위에 계면중합법으로 NF/RO용 복합막을 제조하였다. 높은 투과 속도 및 염의 배제율이 우수한 복합막을 제조하기 위해서 먼저 Polymer 농도, 첨가제 종류및 농도 등에 의한 각종 제막조건에 따른 지지막의 성능을 조사하였다. 여기에 Monomer 농도를 변화시켜서 계면중합으로 복합막을 제조하여 그 성능 변화를 측정하였다.

• Proceedings of the Membrane Society of Korea Conference
• /
• 한국막학회 1998년도 추계 총회 및 학술발표회
• /
• pp.143-145
• /
• 1998

식품공업 분야에서 특정 성분의 분리, 정제, 농축은 매우 중요한 단위공정으로써 추출(Extraction), 여과(Filtration), 증류(Distillation), 증발(Evaporation)등의 조작을 통하여 실시되고 있다. 최근 들어 화학공업, 기계공업, 식품공업의 지속적인 발전에 힘입어 단위조작을 효율적으로 실시할 수 있는 기술로써 국내의 산업화되고 있는 것이 분리막 기술이다. 현재 식품공업 분야에서 활용되고 있는 분리막공정의 종류는 정밀여과(Microfiltration), 한외여과(Ultrafiltration), 초정밀여과(Nanofiltration), 역삼투(Reverse Osmosis) 시스템으로 유제품, 조미료, 음료공업, 장유산업, 기능성 인자의 분리 등에 공업적으로 점차 그 도입 가능성이 증가하고 있다.

• Membrane Journal
• /
• 제33권6호
• /
• pp.409-415
• /
• 2023

Apart from developing better membranes, a clever reconfiguration of membrane cascade process can improve the solute selectivity and minimize solvent consumption. In this work, solvent resistant cellulose nanofiltration membranes were fabricated and the solute rejection performance in various organic solvents were tested. Interestingly, cellulose membranes exhibited unique negative rejection profile in non-polar solvents. Such trend could be exploited to yield reverse selectivity, which showed that low molecular weight solute could be concentrated in the retentate. It was found that more than 3-fold solvent saving could be achieved at the same final purity.