• Title/Summary/Keyword: multifunctional materials

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Highly Efficient Red Phosphorescent OLEDs Employing a Multifunctional Oligofluorene Host

  • Tsai, Ming-Han;Su, Hai-Ching;Wu, Chung-Chih;Wong, Ken-Tsung;Li, Wen-Ren
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.663-666
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    • 2007
  • High-efficiency red phosphorescent OLEDs employing a novel red emitter and a multifunctional oligofluorene host are reported. With qazIr(acac) as the red phosphorescent dopant, a maximum external quantum efficiency of 19% and maximum power efficiency of 11 lm/W are achieved. In addition, single layer devices using such host and dopant materials have efficiencies up to 13%.

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Direct Growth of Graphene at Low Temperature for Future Device Applications

  • Kim, Bum Jun;Nasir, Tuqeer;Choi, Jae-Young
    • Journal of the Korean Ceramic Society
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    • v.55 no.3
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    • pp.203-223
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    • 2018
  • The development of two-dimensional graphene layers has recently attracted considerable attention because of its tremendous application in various research fields. Semi-metal materials have received significant attention because of their excellent biocompatibility as well as distinct physical, chemical, and mechanical properties. Taking into account the technical importance of graphene in various fields, such as complementary metal-oxide-semiconductor technology, energy-harvesting and -storage devices, biotechnology, electronics, light-emitting diodes, and wearable and flexible applications, it is considered to be a multifunctional component. In this regard, material scientists and researchers have primarily focused on two typical problems: i) direct growth and ii) low-temperature growth of graphene. In this review, we have considered only cold growth of graphene. The review is divided into five sections. Sections 1 and 2 explain the typical characteristics of graphene with a short history and the growth methods adopted, respectively. Graphene's direct growth at low temperatures on a required substrate with a well-established application is then precisely discussed in Sections 3 and 4. Finally, a summary of the review along with future challenges is described in Section 5.

Production of Functional Colloids and Fibers from Phase Separation During Electrohydrodynamic Process

  • Jeong, Un-Ryong
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.10a
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    • pp.1.2-1.2
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    • 2011
  • Electrohydrodynamics is a good approach to produce uniform-sized colloids and fibers in a continuous process. The dimension can be controlled from tens of nanometers to a few micrometers. The structure of the colloids and nanofibers from electrohydrodynamics has been diversified according to the uses. Especially, core-shell structure and hybridization with functional nanomaterials are fascinating due to their possible uses in drug-delivery systems, multifunctional scaffolds, organic/inorganic hybrids with new functions, and highly sensitive gas- or bio-sensors. This talk will present the structural variations in the colloids and fibers by simply employing phase separation during electrohydrodynamic process and demonstrate their possible applications.

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Research on the Replacement of Bed Material and Multifunctional Additives in Circulating Fluidized Bed Combustion Using Solid Fuels (고형연료사용 순환유동층 연소로에서의 유동사 대체 및 다기능성 첨가제에 관한 연구)

  • Park, In su;Nam, Jeong soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.11a
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    • pp.115-116
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    • 2023
  • In this study, it was confirmed whether kaolin can play a role as a bed materials and a role in reducing clinkers by using kaolin with a bed materials for the purpose of removing clinkers such as slagging and fouling generated in circulating fluidized bed combustion furnaces using solid fuel.

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Fabrication of Luminescent Hydroxyapatite Microspheres for Drug Loading and Release

  • Park, So Yeon;Kwon, Seung Lee;Baek, Mi Yeon;Yoo, Jin Sun;Kim, Min-Cheol;Jung, Hyun Suk
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.360.1-360.1
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    • 2016
  • Hydroxyapatite (Ca10(PO4)6(OH)2, HAP) particles have attracted a great deal of attention in biomedical fields due to their good biocompatibility, bioactivity and fairly broad applications as drug delivery, dental implant, bone cement, and etc. Thus, many researchers have made an effort to add new functionalities such as luminescence, drug delivery, and bone regeneration properties up to HAP powders by controlling their nanostructure as well as composition. In this research, the mesoporous strontium substituted HAP (Sr-HAP) microspheres were synthesized using a hydrothermal method. In this synthesis, aspartic acid monomers were utilized to form microsphere by controlling surface energy of HAP particles and Sr ions were substituted into Ca ion sites, which induced luminescence property in HAP powders. Moreover, the change in the amount of Sr substitution was found to influence the particle size, morphology, and concurrently surface area, which led to changing drug loading as well as drug release property. The amount of Sr influences the morphology, luminescent properties, particle size, surface area cell viability and drug loading property, which are investigated by SEM, TEM, XRD, FTIR, BET, XPS and in vitro test such as MTT assay and drug release test. In particular, the multifunctional Sr-HAP with molar ratios of 0.25 (Sr/(Ca+Sr)) possessed the strongest luminescent property as well as the superior drug loading and sustained release properties that were correspondent with large surface area and pore size. Our study indicates that the fabricated multifunctional Sr-HAP microspheres are quite useful for bone regeneration and drug delivery.

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Preparation of Silica Films by Surface Tension Control (표면장력 제어를 이용한 실리카 박막의 제조)

  • Lee, Jae-Jun;Kim, Yeong-Ung;Jo, Un-Jo;Kim, In-Tae;Je, Hae-Jun;Park, Jae-Gwan
    • Korean Journal of Materials Research
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    • v.9 no.8
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    • pp.804-809
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    • 1999
  • Silica films were prepared on Si single crystal substrates by a sol-gel process without DMF using TEOS as a starting material. Films were fabricated by spin coating technique. For films having a composition of TEOS : HCI(1:0.05mol), gelation time, the thickness of films, the formation of cracks and the microstructure of the films were investigated as a function of the molar ratio of $CH_3OH and H_2O$. With 8mol $CH_3OH$, the longest gelation time was measured to be 640hr. The thickness of the coated films was decreased with increasing content of $CH_3OH$. The films were sintered at $500^{\circ}C$ for 1hr with a heating rate of $0.6^{\circ}C$/min. The coated films showed worm-like grains and partially cracked microstructures at an amount of $CH_3OH$ 2mol and 4mol. The addition of more than 8 mole of $CH_2OH$ resulted in crack-free silica films. This suggests that crack-free films can be fabricated by controlling the surface tension energy of the sol solutions without DMF.

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Low-temperature Sintering and Dielectric Properties of $CaZrO_3-CaTiO_3$ Ceramics for Middle- Permittivity LTCC Substrate (중유전율 LTCC 기판용 $CaZrO_3-CaTiO_3$계 세라믹스의 저온소결 및 유전특성)

  • Park Jeong-Hyun;Choi Young-Jin;Ko Won-Jun;Park Jae-Hwan;Park Jae-Gwan
    • Journal of the Microelectronics and Packaging Society
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    • v.11 no.3 s.32
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    • pp.17-22
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    • 2004
  • The microwave dielectric properties of $CaZrO_3$ ceramics with addition of $CaTiO_3$ were studied. The effect of glass addition on the low-temperature sintering and microwave dielectric properties of $CaZrO_3-CaTiO_3$ ceramics were also evaluated to develop the materials for functional substrates of low-temperature co-fired ceramics. When $10-20 wt\%$ of lithium borosilicate glass was added, the sintering temperature of the $CaZrO_3-CaTiO_3$ ceramics decreased from $1450^{\circ}C$ to below $900^{\circ}C$. As the $T_f$ of glass frits and $CaZrO_3$ are slightly negative and that of $CaTiO_3$ is significantly positive, zero $T_f$ could be realized by mixing an appropriate amount of $CaTiO_3$ with $CaZrO_3$. The $CaZrO_3-CaTiO_3$ ceramics sintered at $875^{\circ}C$ with $15wt\%$ glass frits showed the relative density of $98\%$, permittivity of 23, quality factor of 2500 GHz, and temperature coefficient of resonant frequency of $ -3 ppm/^{\circ}C$.

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Functional LTCC Substrate with Near Zero Temperature Coefficient of the Resonant Frequency (Near Zero TCF 특성을 가지는 기능성 LTCC 기판)

  • Choi, Young-Jin;Park, Jeong-Hyun;Ko, Won-Jun;Park, Jae-Hwan;Park, Jae-Gwan;Nahm, Sahn
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.635-638
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    • 2004
  • 페로브스카이트 구조를 가지는 $CaZrO_3$ 유전체 세라믹스에 $CaTiO_3$를 부피 비율로 첨가하여 첨가량 변동에 따른 마이크로파 유전 특성을 조사하였다. 또한 저온 동시소성 기능성 LTCC 기판용 유전체 소재로서 활용하기 위하여 저융점의 borosilicate계 유리 프리트를 첨가하여 $CaZrO_3-CaTiO_3$ 복합 유전체 세라믹스의 저온 소결 거동과 마이크로파 유전 특성을 평가하였다. 알칼리가 첨가된 저융점의 borosilicate계 유리 프리트를 $10\sim30$ wt% 범위로 첨가함으로서 $CaZrO_3-CaTiO_3$ 복합 유전체 세라믹스의 소결온도를 $1450^{\circ}C$에서 $900^{\circ}C$이하로 낮출 수 있었으며, 유리 프리트의 첨가량으로 공진 주파수 온도계수 특성을 조절할 수 있었다. 유리 프리트의 첨가량이 15 wt% 첨가시 $875^{\circ}C$에서 충분한 소결이 이루어졌으며, 이 경우 $CaZrO_3-CaTiO_3$ 복합 유전체 세라믹스는 유전율(k) 23, 품질계수(Qxf) 2500, 공진 주파수 온도계수 ($\tau_{cf}$) -3 ppm/$^{\circ}C$의 매우 양호한 마이크로파 유전 특성을 나타내었다. 유리 프리트의 첨가에 의하여 소결 과정에서 주상인 $CaZrO_3$$CaZr_4O_9$ 상으로의 변화가 뚜렷이 나타났는데, 이러한 상전이 현상과 함께 미세구조의 변화에 대해서도 고찰하였다.

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Low Temperature Sintering and Dielectric Properties of Low Dielectric Constant/Loss for LTCC Wiring Substrate (저유전율/저손실 LTCC 배선 기판의 저온소결 및 유전특성)

  • Choi, Young-Jin;Park, Jeong-Hyun;Ko, Won-Jun;Park, Jae-Hwan;Park, Jae-Gwan;Nahm, Sahn
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.714-717
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    • 2004
  • 알루미노 보로실리케이트계 유리 기본조성 중 알칼리 토류 산화물의 종류 및 함량 변화에 따른 저유전율/저 LTCC 배선 기판의 저온 소성 거동 및 유전 특성을 조사하였다 알칼리 토류 산화물의 종류 및 함량 변화를 통해서 LTCC의 적정 소성온도인 $875^{\circ}C$ 부근을 포함하는 넓은 대역으로 소성수축이 시작되는 온도를 제어할 수 있었으며 유리 프리트와 알루미나 필러의 배합 비율의 변화에 따른 소성거동 및 유전특성의 변화 거동을 조사하였다. 알칼리 토류 산화물 중 유리 조성내의 CaO의 함량이 증가할수록 유리전이점 및 연화점을 증가하는 경향을 보였으며, 알루미나 필러의 첨가량이 증가할수록 소성수축이 시작되는 온도영역은 상향되고 유전율 및 품질계수는 증가하였다. 알칼리 토류 산화물의 조성과 필러인 알루미나의 함량을 제어함으로서 $875^{\circ}C$에서 18% 이상의 선수축율과 유전율 $5.1\sim5.5$ 및 유전손실 0.1% 이하의 우수한 특성을 갖는 저온소결용 LTCC 배선 기판을 얻을 수 있었다.

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