• Bulletin of the Korean Chemical Society
• /
• 제32권6호
• /
• pp.1993-1996
• /
• 2011

The vibronically well-resolved emission spectrum was recorded from the corona discharge of precursor 2,3,4-trifluorotoluene in a corona excited supersonic expansion with a pinhole-type glass nozzle using a long-path monochromator in the visible region. From the analysis of the observed spectrum, we found the evidence of the presence of the difluorobenzyl radicals in the corona discharge of the precursor. A possible mechanism is proposed for the formation of difluorobenzyl radicals in the gas phase on the basis of the observed emission intensity of the difluorobenzyl radicals produced.

• 대한화장품학회:학술대회논문집
• /
• 대한화장품학회 2003년도 IFSCC Conference Proceeding Book I
• /
• pp.203-224
• /
• 2003

In recent years, a miniature spectrometer has been extensively developed due to the combination of fiber optics and semiconductor detector arrays. This type of miniature spectrometer has advantages of low price and robustness because of the capability of mass production and no moving parts are required such as lenses, mirrors and scanning monochromator. In this study, for skin diagnostics, a portable near infrared (NIR) system has been developed using a LlGA microspectrometer, which is photo-diode arrays-type.(omitted)

• Bulletin of the Korean Chemical Society
• /
• 제34권12호
• /
• pp.3565-3569
• /
• 2013

A home-made pinhole-type glass nozzle was employed to generate vibronically excited but jet-cooled benzyl-type radicals from precursor 2-fluoro-4-chlorotoluene with a large amount of carrier gas He, from which the visible vibronic emission spectrum was recorded with a long-path monochromator. From an analysis of the spectrum observed, it was found that two benzyl-type radicals, 2-fluorobenzyl and 2-fluoro-4-chlorobenzyl radicals, were formed from the precursor in corona discharge. The possible pathway for the production of benzyl-type radicals that can explain the spectroscopic observation is herein proposed. In addition, the electronic energy of the $D_1{\rightarrow}D_0$ transition and the vibrational mode frequencies in the $D_0$ state of the 2-fluoro-4-chlorobenzyl radical were determined for the first time.

• Bulletin of the Korean Chemical Society
• /
• 제32권9호
• /
• pp.3389-3394
• /
• 2011

Isomeric trimethylbenzyl radicals were generated and vibronically excited from precursor 1,2,3,5-tetramethylbenzene, isodurene, with a large amount inert carrier gas helium in a corona excited supersonic expansion (CESE) using a pinhole-type glass nozzle. A long-path monochromator was used to record the visible vibronic emission spectra of the jet-cooled benzyl-type radicals in the $D_1{\rightarrow}D_0$ electronic transition. From the analysis of the spectra, we identified the evidence of the presence of three isomeric trimethylbenzyl radicals in the corona discharge, and obtained the electronic energy and a few vibrational mode frequencies in the ground electronic state for each isomer.

• 한국세라믹학회지
• /
• 제23권2호
• /
• pp.64-70
• /
• 1986

In this investigation x-ray diffraction method was mainly studied for quantitative analysis of clinker mineral composition. And also optical microscopic observation and Bogue calculation method were applied to compare with the x-ray diffraction method. In the procedure of x-ray diffraction analysis graphite monochromator automatic divergence slit and spinner for sample holder were used for minimizing the error due to the operation of the equipment. Especially the separation of overlapped peaks were proceeded by micro-processor automatically. The results of x-ray diffraction method for synthesized clinker were consistent with the Bogue value and the results of optical microscopic observation. However the results of quantitative analysis of mineral composition or commercial clinker containing solid solution of minor component were different from the Bogue value. On the other hand they agreed reasonably well with results of the optical mic-roscopic observation.

• Bulletin of the Korean Chemical Society
• /
• 제31권9호
• /
• pp.2479-2482
• /
• 2010

Using a pinhole-type glass nozzle equipped for a corona-excited supersonic expansion (CESE), precursor 2,6-dichlorotoluene seeded in a large amount of inert carrier gas helium was discharged to produce jet-cooled but electronically excited benzyl-type radicals. The visible vibronic emission spectrum was recorded with a long-path monochromator to observe vibronic bands in the $D_1{\rightarrow}D_0$ electronic transition of benzyl-type radicals. The spectral analysis revealed the generation of not only the 2,6-dichlorobenzyl radical as a typical product, but also the o-chlorobenzyl radical as an unexpected species, which indicates the possible molecular rearrangement in eliminating a chlorine atom from the benzene ring. A possible mechanism is proposed for the formation of the o-chlorobenzyl radical from the precurs or in the gas phase.

• 한국진공학회:학술대회논문집
• /
• 한국진공학회 1999년도 제17회 학술발표회 논문개요집
• /
• pp.233-233
• /
• 1999

본 연구에서는 2성분계 gas(Ne+Xe)를 사용하여 기체압력(p), 진동수(f)에 따라 VUV(Vacuum Ultra Violet) spectrum 147, 173nm 파장과 IR(Infrared) spectrum 823nm, 828nm을 Vacuum Monochromator(Acton-VM 507)를 통해 측정하였다. 휘도(Luminance)와 전력(Power)측면에서 Ne+ Xe 최적의 가스 조성비를 찾기 위해서 Xe의 혼합비에 따른 IR영역인 823nm, 828nm을 측정결과, Xe 4%일 때 좋은 효율을 나타냈다. 기체압력이 200Torr에서는 Xe(3P1)에 기인하는 147nm가 주요한 파장이며, 기체압력이 400Torr, 600Torr일때는 Xe(3P2)에 기인하는 173nm 파장이 주요함을 알 수 있었다. 또한 공간 방전 이미지를 전압 pulse 인가후 ICCD Camera(V-Tek)의 Ready time, On Time을 조절하면서 50ns delay로 관측하였다. 향후 실험계획은 실제 상용화되고 있는 혼합가스 He+Ne+Xe의 조성비에 따른 자세한 실험을 할 것이다.

• Macromolecular Research
• /
• 제14권4호
• /
• pp.473-477
• /
• 2006

The above described semi-transparent monochromators have been operational since 1997. Four units are permanently operating at the ESRF beam line ID14. Two units are in continuous operation at ID 10 and one unit is installed at the APS beamline 8-ID in USA. The water cooling of the crystals is currently being revised and above we showed that improvements most likely are possible by using micro fluidics techniques. Further tests will be performed in collaboration with the CEA-France and tested at ESRF. Parallel developments including nanofluids as coolants are under evaluation. Combination of nanofluidics and microfluidics cooling devices are under study. The authors are grateful to C. Gillot and J-A. Gruss for useful discussions and advices, and to S.Mcheik for his work on the thermal model.

• 대한전기학회:학술대회논문집
• /
• 대한전기학회 2002년도 하계학술대회 논문집 C
• /
• pp.1779-1781
• /
• 2002

본 연구에서는 대기압 교류방전시 비열플라즈마를 이용하였을 때 NO입자의 분광스펙트럼과 전극재질과 전극두께에 따른 신호강도를 측정하였다. 분광기를 이용하여 측정된 NO입자의 분광스펙트럼 분포를 바탕으로 측정된 파장대역 중에서 비교적 신호강도가 큰 파장대역인 226[nm], 236[nm], 247[nm], 259[nm]에서 전극의 재질을 스테인레스, 구리, 알루미늄으로 변화시켰을 때의 신호강도와 전극의 두께를 4[mm], 5[mm], 6[mm]로 변화시켰을 때의 신호강도를 분광기(Monochromator)를 이용하여 측정하였다. 또한, 측정대상 중 전극재질은 구리일때가 가장 신호강도가 높음을 확인할 수 있었으며 전극두께는 갭 간격이 작을수록 신호강도가 강한 것을 확인함으로써 NO입자의 방전 메카니즘을 보다 명확하게 규명하고 또한 방전 리액터 제작에도 좋은 자료를 제공할 수 있을 것으로 생각된다.

• 한국결정학회지
• /
• 제11권2호
• /
• pp.84-88
• /
• 2000

The crystal of cholesteryl crotylcarbonate was investigated by X-ray diffraction method. Crystallographic data for the title compound: P21, a=13.510(2)Å, b=11.843(2)Å, c=19.882(2)Å, β=106.88(1)°, Z=4. Reflections were collected with an Enraf-Nonius CAD-4 diffractometer equipped with a graphite monochromator. The structure was solved by direct methods and refined by least-squares analyses. The final R value was 0.125 for 2607 reflections. The cholesterol fragment of the title compound were in good agreement with those for related cholesterol derivatives. The molecules were stacked in clearly separated layers. At the center of the layers, there were cholesteryl-cholesteryl interactions between the symmetry-related B molecules and the cholesteryl-C(17) side chain of A molecules. There were also interactions between the C(17) side chain of B molecules and the crotylcarbonate chain in the interface region between layers. The crystal structure of the title compound turned out to be isostructural with those of cholesteryl ethylcarbonate and cholesteryl propylcarbonate.