• Membrane Journal
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• v.29 no.1
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• pp.37-43
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• 2019

In this study, we investigated how the force-field, which is the most important factor to define atomic motion in molecular dynamics (MD), affects the motion of the polymer and gas molecules. The repeat units and the polymer structure were well simulated in all five force-fields, and the distribution of the polymer linear chain in the final polymer 3D model did not show any significant difference. However, the movement of actual gas molecules showed a very different tendency, which was also observed in COMPASS and pcff using the same functional form. Therefore, even if the same structure is used, it can be seen that the motion of the gas molecule moves under the influence of the force-field continuously over time, so that the effect is much larger than that of macromolecules such as a polymer linear chain. Accordingly, in case of using different force-fields, it is necessary to be very careful in comparison of those results.

• The Bulletin of The Korean Astronomical Society
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• v.46 no.2
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• pp.38.2-39
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• 2021

I will presents the analysis of the gas properties of the protoplanetary disk surrounding the young low-mass (about 1.2M_sun) triple star, GG Tau A. This work makes use of ALMA observations of rotational lines of CO (¹²CO, ¹³CO and C¹⁸O) together NOEMA observations of a few dozens of other molecules. While the CO emission gives information on the molecular layer close to the disk atmosphere, its less abundant isotopologues ¹³CO and C¹⁸O bring information much deeper in the molecular layer. I will present the analysis of the morphology and kinematics of the gas disk using the CO isotopologues. A radiative transfer model of the ring in CO isotopologues will also be presented. The subtraction of this model from the original data reveals the weak emission of the molecular gas lying inside the cavity. Thus, I am able to evaluate the properties of the gas inside the cavity, such as the gas dynamics, excitation conditions, and the amount of mass in the cavity. High angular resolution observations of CO reveals sprials induced by embedded planet(s) located near the 3:2:1 mean-motion resonance that help to explain the special morphology of the circumbinary disk. I also discuss some chemical properties of the GG Tau A disk. I report the first detection of H2S and C₂S in a protoplanetary disk. The molecule abundance relative to ¹³CO of about twenties other molecules will also be given. In GG Tau A, the detections of rare molecules such as H₂S and C₂S have been probably possible because the disk is more massive (a factor about 3-5) than other disks where the molecules was searched. Such a large disk mass makes the system suitable to detect rare molecules and to study cold-chemistry in protoplanetary disks.

• Membrane Journal
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• v.23 no.6
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• pp.393-408
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• 2013

Gas separation processes using polymeric membranes have been greatly developed during the last few decades due to high energy efficiency and economic advantages. To achieve optimum economic performance, gas separation membranes required high permeability and selectivity. So, a number of reports examining the various polymeric materials for gas separation membranes have been published. Among the studied materials, polyimide (PI), which exhibit high permselectivity for various gas pairs, high chemical resistance, thermal stability, and mechanical strength, have attracted much attention. This paper focuses on the basic principle of gas separation, preparation procedure of membrane along with the recent developments and research trends of PI based materials for gas separation.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.22 no.12
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• pp.1089-1094
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• 2009

Carbon nanotubes (CNTs) have excellent electrical, chemical stability, mechanical and thermal properties. In this paper, networks of Multi-walled carbon nanotube (MWCNT) materials were investigated as resistive gas sensors for ethanol ($C_2H_5OH$) detection. Sensor films were fabricated by air spray method for the multi-walled CNTs solution on glass substrates. Sensors were characterized by resistance measurements in the sensing system, in order to find the optimum detection properties for the ethanol gas molecular. The film that was sprayed with the MWCNT dispersion for 60 see, was 300 nm thick. And the electric resistivity is $2{\times}10^{-2}\;{\Omega\cdot}cm$. Also, the sensitivity and the linearity of MWVNT sensor for ethanol gas are 0.389 %/sec and 17.541 %/FS, respectively. The MWCNT film was excellent in the response for the ethanol gas molecules and its reaction speed was very fast, which could be using as ethanol gas sensor. The conductance of the fabricated sensors decreases when the sensors are exposed to ethanol gas.

• Advances in environmental research
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• v.6 no.3
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• pp.189-202
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• 2017

This study examines the concentrations of particulate-phase polycyclic aromatic hydrocarbons (PAHs) and gas-phase PAHs in sidestream cigarette smoke. Sixteen PAHs were determined for four brands of cigarettes. The volume of the experimental room is approximately $66m^3$. The air samples in the room were collected before and after smoking. The median total of particulate-phase and gas-phase PAH concentrations before smoking $3.13ng/m^3$and $48.0ng/m^3$, respectively. The median concentrations of them after smoking were $10.0ng/m^3$ and $79.6ng/m^3$. The median increases in the total of 16 PAH concentrations per cigarette during smoking were 271 ng for the particulate-phase PAHs and 1960 ng for the gas-phase PAHs. According to the relationship between particulate-phase and gas-phase PAHs after smoking, the two- to four-ring gas-phase PAHs and the higher molecular weight particulate-phase PAHs were probably formed from similar precursors. The relationship between the total suspended particulate (TSP) concentration and the increase in the total particulate-phase concentration of the 16 PAHs per cigarette during smoking were significantly positive. The increase in the total gas-phase concentration of the 16 PAHs tended to increase as the TSP concentration increased. This may indicates that decreasing the amount of TSP produced inhibit the production of PAHs during smoking.

• Journal of The Korean Astronomical Society
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• v.35 no.2
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• pp.97-103
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• 2002

We have mapped 1 $deg^2$ region toward a high latitude cloud MBM 40 in the J = 1 - 0 transition of $^{12}CO$ and $^{13}CO$, using the 3 mm SIS receiver on the 14 m telescope at Taeduk Radio Astronomy Observatory. We used a high resolution autocorrelator to resolve extremely narrow CO linewidths of the molecular gas. Though the linewidth of the molecular gas is very narrow (FWHP < 1 km $s^{-1}$ ), it is found that there is an evident velocity difference between the middle upper part and the lower part of the cloud. Their spectra for both of $^{12}CO$ and $^{13}CO$ show blue wings, and the position-velocity map shows clear velocity difference of 0.4 km $s^{-1}$ between two parts. The mean velocity of the cloud is 3.1 km $s^{-1}$. It is also found that the linewidths at the blueshifted region are broader than those of the rest of the cloud. We confirmed that the visual extinction is less than 3 magnitude, and the molecular gas is translucent. We discussed three mass estimates, and took a mass of 17 solar masses from CO integrated intensity using a conversion factor $2.3 {\times} 10^{20} cm^{-2} (K\;km s^{-1})^{-1}$. Spatial coincidence and close morphological similarity is found between the CO emission and dust far-infrared (FIR) emission. The ratio between the 100 f.Lm intensity and CO integrated intensity of MBM 40 is 0.7 (MJy/sr)/(K km $s^{-1}$), which is larger than those of dark clouds, but much smaller than those of GMCs. The low ratio found for MBM 40 probably results from the absence of internal heating sources, or significant nearby external heating sources.

• Journal of Microbiology and Biotechnology
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• v.18 no.11
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• pp.1809-1818
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• 2008

Biotechnological treatment of sulfate- and metal-ions-containing acidic wastewaters from mining and metallurgical activities utilizes sulfate-reducing bacteria to produce sulfide that can subsequently precipitate metal ions. Reducing sulfate at a low pH has several advantages above neutrophilic sulfate reduction. This study describes the effect of sulfide removal on the reactor performance and microbial community in a high-rate sulfidogenic gas-lift bioreactor fed with hydrogen at a controlled internal pH of 5. Under sulfide removal conditions, 99% of the sulfate was converted at a hydraulic retention time of 24 h, reaching a volumetric activity as high as 51 mmol sulfate/l/d. Under nonsulfide removal conditions, <25% of the sulfate was converted at a hydraulic retention time of 24 h reaching volumetric activities of <13 mmol sulfate/l/d. The absence of sulfide removal at a hydraulic retention time of 24 h resulted in an average $H_2S$ concentration of 18.2 mM (584 mg S/I). The incomplete sulfate removal was probably due to sulfide inhibition. Molecular phylogenetic analysis identified 11 separate 16S rRNA bands under sulfide stripping conditions, whereas under nonsulfide removal conditions only 4 separate 16S rRNA bands were found. This shows that a less diverse population was found in the presence of a high sulfide concentration.

• Journal of the Korean Society of Marine Environment & Safety
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• v.27 no.6
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• pp.890-897
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• 2021

Since the enforcement of strict regulations on marine fuel oil sulfur content, demand for Low Sulfur Fuel Oil (LSFO) has been increasing. However, as LSFO properties vary greatly depending on the supply timing, region, and supplier, LSFOs can experience problems with sludge formation, blending compatibility, and stability once mixed into storage tanks. This study investigates using ultrasound cavitation effects to improve the quality of LSFOs in storage tanks. For marine gas oil (MGO), the results showed that the relative ratio of high molecular weight compounds to those of low molecular weight decreased after ultrasonic irradiation, due to cavitation-induced cracking of chemical bonds. For marine diesel oil (MDO) and blended oil, a small increase in the relative abundance of low weight molecular compounds was observed after treatment. However, no correlation between time and relative abundance was observed.

• 한국신재생에너지학회:학술대회논문집
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• 2005.06a
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• pp.553-556
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• 2005

Pyrolysis of polyethylene was carried out in the stainless steel reactor of internal volume of $40cm^3$. Pyrolysis reactions were performed at temperature $390-450^{\circ}C$ and the pyrolysis product were collected separately as reaction products and gas products. The molecular weight distributions(MWDs) of each liquid product were determined by GC-SIMDIS. Molecular weight of each product were decreased wi th increase of react ion temperature and time.

• Journal of the Korean Graphic Arts Communication Society
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• v.12 no.1
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• pp.159-168
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• 1994

The Aggregation State of thin vapor deposite Film made by Cyanine Dye were changed into Monomeric molecular state(M) and Dimeric Aggregation(D) at the acidic treatment, into reversible H-Aggregation (H) at alkalic gas or heat treatment. Photo-electric properties were higher H than D and M, this stats were effective in enhancing Photoelectric-conversion characteristic. Substitute group of Meso-Position being stronger electronic Donors, Electronic density is higher and Electric conductivity is enhanced, we confirmed Oscillator Strength calculated by PPP-Molecular Orbital Calculation and Absorption Spectra at solvent stats were agreed good.