• Title/Summary/Keyword: molecular gas

Search Result 868, Processing Time 0.041 seconds

High Performance InAIAs/InGaAs Metal-Semiconductor-Metal Photodetectors Grown by Gas Source Molecular Beam Epitaxy

  • Zhang, Y.G.;Chen, J.X.;Li, A.Z.
    • Journal of the Korean Vacuum Society
    • /
    • v.4 no.S2
    • /
    • pp.75-78
    • /
    • 1995
  • Gas source molecular beam epitaxy have been used in the growth of InAlAsAnGaAs MSM-PD structure, in which InAlAs ultra thin layer was used as Schottky barrier enhancement material. High performance MSM-PDs have been constructed on the grown wafer. High breakdown voltage of >30V, low dark current density of $3pA/\mu \textrm{cm}^2$ at 10V bias and fast transient response of <20ps rise time / <40ps FWHM have been measured, which confirm the results that GSMBE is a superior method for the growth of materials with high layer and interfacial quality, especially for InP based InAIAdInGaAs system.

  • PDF

Dehydration of Methanol to Dimethyl Ether over ZSM-5 Zeolite

  • Jiang, Shan;Hwang, Jin-Soo;Jin, Tai-Huan;Cai, Tianxi;Cho, Wonihl;Baek, Young-Soon;Park, Sang-Eon
    • Bulletin of the Korean Chemical Society
    • /
    • v.25 no.2
    • /
    • pp.185-189
    • /
    • 2004
  • Methanol dehydration to dimethyl ether (DME) has been investigated over ZSM-5 zeolites and compared with that of ${\gamma}-Al_2O_3$. Although the catalytic activity was decreased with an increase in silica/alumina ratio, the DME selectivity increased. H-ZSM-5 and NaH-ZSM-5 zeolites were more active for conversion of methanol to DME than ${\gamma}-Al_2O_3$. $Na^+$ ion-exchanged H-ZSM-5 (NaH-ZSM-5) shows higher DME selectivity than H-ZSM-5 due to the selective removal of strong acid sites.

Molecular Dynamics Simulation of a Small Drop of Liquid Argon

  • Lee, Song Hi
    • Bulletin of the Korean Chemical Society
    • /
    • v.33 no.11
    • /
    • pp.3805-3809
    • /
    • 2012
  • Results for molecular dynamics simulation method of small liquid drops of argon (N = 1200-14400 molecules) at 94.4 K through a Lennard-Jones intermolecular potential are presented in this paper as a preliminary study of drop systems. We have calculated the density profiles ${\rho}(r)$, and from which the liquid and gas densities ${\rho}_l$ and ${\rho}_g$, the position of the Gibbs' dividing surface $R_o$, the thickness of the interface d, and the radius of equimolar surface $R_e$ can be obtained. Next we have calculated the normal and transverse pressure tensor ${\rho}_N(r)$ and ${\rho}_T(r)$ using Irving-Kirkwood method, and from which the liquid and gas pressures ${\rho}_l$ and ${\rho}_g$, the surface tension ${\gamma}_s$, the surface of tension $R_s$, and Tolman's length ${\delta}$ can be obtained. The variation of these properties with N is applied for the validity of Laplace's equation for the pressure change and Tolman's equation for the effect of curvature on surface tension through two routes, thermodynamic and mechanical.

Comparison of the Fatty Acid Composition and Small Molecular Metabolites between Yanjin Blackbone Chicken and Piao Chicken Meat

  • Rong Jia;Wen Xun;Guozhou Liao;Yuan Yang;Guiying Wang
    • Food Science of Animal Resources
    • /
    • v.43 no.6
    • /
    • pp.975-988
    • /
    • 2023
  • The fatty acid composition and small molecular metabolites in breast and leg meat of Yanjin blackbone chickens (YBC) and Piao chickens (PC) were detected by gas chromatography-mass spectrometry and liquid chromatography-quadrupole static field orbital trap mass spectrometry. Thirty-two fatty acids were detected, and the total fatty acid content of PC was significantly higher than that of YBC (p<0.05). Oleic acid, linoleic acid, palmitic acid, stearic acid, and arachidonic acid were the main fatty acids in the two chicken varieties, and the composition of fatty acids in the two varieties were mainly unsaturated fatty acids, being more than 61.10% of the total fatty acids. Meanwhile, 12 and 16 compounds were screened out from chicken legs and chicken breasts of YBC and PC, respectively, which had important contributions to the differences between groups.

Sensing and Identification of Health Hazardous Molecular Components using Surface-Enhanced Raman Spectroscopy: A Mini Review

  • Pratiksha P. Mandrekar;Moonjin Lee;Tae-Sung Kim;Daejong Yang
    • Journal of Sensor Science and Technology
    • /
    • v.32 no.5
    • /
    • pp.259-266
    • /
    • 2023
  • The use of various adulterants and harmful chemicals is rapidly increasing in various sectors such as agriculture, food, and pharmaceuticals, and they are also present in our surroundings in the form of pollutants. The regular and repeated intake of harmful chemicals often adversely affects human health. The prolonged exposure of living beings to such adverse components can lead to severe health complications. To avoid the unlimited utilization of these chemical components, a sensing technology that is sensitive and reliable for low-concentration detection is beneficial. Surface-enhanced Raman spectroscopy (SERS) is a powerful method for identifying low-range concentrations of analytes, leading to great applications in molecular identification, including various diagnostic biomarkers. SERS in chemical, gas, and biological sensors can be an excellent approach in the sensing world to achieve rapid and multiple-analyte detection, leading to a new and efficient approach in healthcare monitoring.

Study on the Properties of Molecular Sieve Made from Carbonized Material with Modifiers (변형제를 이용한 탄화 시료의 분자체 특성 효과에 관한 연구)

  • Kim, Kweon-Ill;Kim, Tae-Hwan;Park, Jong-Gi;Cho, Sung-Chul;Jin, Myeng-Jong
    • Applied Chemistry for Engineering
    • /
    • v.7 no.2
    • /
    • pp.334-340
    • /
    • 1996
  • Carbon adsorbents, having the properties of molecular sieve, were prepared based on coat materials. A couple of modifiers were used to prepare carbon molecular sieve. The effects of modifier concentrations on the characteristics of carbon molecular sieve were investigated. In order to verify the characteristics of carbon molecular sieve, the adsorption rates of oxygen and nitrogen gases on the carbon molecular sieve were measured using Cahn microbalance(model # : D-200). The experimental data were fitted to an adsorption rate equation and gas diffusivities were calculated. The effects of modifier molecular weight and concentration on the characteristics of carbon molecular sieve were shown.

  • PDF

Analysis of Gases in Nuclear Fuel Rod by Quadrupole Mass Spectrometry (Quadrupole Mass Spectrometry를 이용한 핵연료봉내 기체분석)

  • Kim, Seung-Soo;Kang, Moon-Ja;Park, Soon-Dal;Park, Yong-Joon;Joe, Kih-Soo
    • Analytical Science and Technology
    • /
    • v.12 no.2
    • /
    • pp.94-98
    • /
    • 1999
  • An analysis method of components and isotopic compositions of low pressure gases from nuclear fuel rod using quadrupole mass spectrometer was studied. The calibration curves of each gas in pure and mixtures of He, $N_2$, $O_2$, Ar, Kr and Xe were obtained as a function of pressure and concentration, respectively. Effect of molecular leak, located between sample chamber and analyser chamber, on the sensitivites was also studied. The results suggested that samples could be analysed accurately at the same analytical condition as that of synthetic gas mixture. The difference of sensitivities among isotopes of Kr and Xe was not observed in the range of measured pressure.

  • PDF

The effects of primary gas physical properties on the performance of annular injection type supersonic ejector (주유동 기체의 물리적 특성이 환형 분사 초음속 이젝터의 성능에 미치는 영향)

  • Jin, Jung-Kun;Kim, Se-Hoon;Park, Geun-Hong;Kwon, Se-Jin
    • Journal of the Korean Society for Aeronautical & Space Sciences
    • /
    • v.33 no.12
    • /
    • pp.68-75
    • /
    • 2005
  • The effects of the physical properties of primary flow on the performance of a supersonic ejector were investigated. Axisymmetric annular injection type supersonic ejector was used for the study of the effects of molecular weight and the specific heat at constant pressure on the ejection performance. Test gases include; air, $CO_{2}$, Ar, $C_{3}H_{8}$, and $CCl_{2}F_{2}$ for different values of gas properties. As the molecular weight and CP of the primary gas increase, the secondary flow pressure increases at the same primary stagnation pressure and this behavior results from the combined effects of molar specific heat or specific heat ratio.

CO gas properties of a H2O detected star forming region in IC 10

  • Kim, Seongjoong;Lee, Bumhyun;Oh, Se-Heon;Chung, Aeree;Rey, Soo-Chang;Jung, Teahyun;Kang, Miju
    • The Bulletin of The Korean Astronomical Society
    • /
    • v.39 no.2
    • /
    • pp.61.1-61.1
    • /
    • 2014
  • IC 10 is one of the most well-known irregular starburst dwarf galaxies in the Local Group. Its low metal and oxygen abundance together with proximity make it an excellent laboratory to test star formation models, especially in low-metallicity systems like galaxies in the early Universe as well as many other local dwarfs. Among a number of active star forming regions, we have detected H2O kilo-maser emission in the south-east region of IC 10(IC 10 SE) using the Korean VLBI Network(KVN). This maser line is likely to be associated with a giant molecular cloud identified in IC 10 SE by former CO studies. Using the HI and CO data from the VLA and SMA archive, we probe the atomic and molecular gas properties of IC 10 SE. We discuss how the cool gas morphology and kinematics are related with maser and star formation activity in IC 10 SE.

  • PDF

Growth of InGaN on sapphire by GSMBE(gas source molecular beam epitaxy) using $DMH_y$(dimethylhydrazine) as nitrogen source at low temperature (Nitrogen source로 암모니아, $DMH_y$(dimethylhydrazine)을 사용해 Gas-Source MBE로 성장된 InGaN 박막특성)

  • Cho, Hae-Jong;Han, Kyo-Yong;Suh, Young-Suk;Park, Kang-Sa;Misawa, Yusuke
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2004.07b
    • /
    • pp.1010-1014
    • /
    • 2004
  • High quality GaN layer and $In_xGa_{1-x}N$ alloy were obtained on (0001)sapphire substrate using ammonia$(NH_3)$ and dimethylhydrazine$(DMH_y)$ as a nitrogen source by gas source molecular hem epitaxy(GSMBE) respectively. As a result, RHEED is used to investigate the relaxation processes which take place during the growth of GaN and $In_xGa_{1-x}N$. The full Width at half maximum of the x-ray diffraction(FWHM) rocking curve measured from Plane of GaN has exhibitted as narrow as 8 arcmin. Photoluminescence measurement of GaN and $In_xGa_{1-x}N$ were investigated at room temperature, where the intensity of the band edge emission is much stronger than that of deep level emission. In content of $In_xGa_{1-x}N$ epitaxial layer according to growth condition was investigated.

  • PDF