• Title/Summary/Keyword: mixing factors

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Source Identification and Trends in Atmospheric Particulate-bound Mercury at Seoul and Baengnyeong, South Korea (서울과 백령도의 대기 중 입자상 수은의 분포 특성 및 발생원 추정연구)

  • Noh, Seam;Park, Kwang-Su;Kim, Hyuk;Yu, Seok-Min;Lim, Yong-Jae;Lee, Min-Do;Seok, Kwang-Seol;Kim, Younghee
    • Journal of Environmental Analysis, Health and Toxicology
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    • v.21 no.4
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    • pp.220-228
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    • 2018
  • $PM_{2.5}$-bound mercury (PBM) was monitored at weekly intervals for three years (from 2014 to 2016) at an urban (Seoul) and rural site (Baengnyeong) in South Korea. The average PBM concentrations in $PM_{2.5}$ samples over the entire sampling period were $12{\pm}11pg/m^3$ and $36{\pm}34pg/m^3$ for Baengnyeong and Seoul, respectively. Seasonal differences were pronounced, with concentrations being highest in winter due to local meteorological conditions (high gas-particle coefficient due to low temperature and low mixing layer height in winter) as well as seasonal factors, such as coal combustion for heating purposes in China. In Baengnyeong, the significant positive correlation of PBM with $PM_{2.5}$, air pollutants, and heavy metals suggested that coal combustion in China might be the most important source of ambient mercury in Korea. In winter, no correlation of PBM with $PM_{2.5}$, air pollutants, and heavy metals was seen in Seoul. Furthermore, Seoul showed higher $PBM/PM_{2.5}$ and $Pb/PM_{2.5}$ ratios in winter due to the strong atmospheric oxidation-reduction reaction conditions as well as local and regional PBM sources. We conclude that immediate attention must be given to addressing PBM levels in Korea, including considering it as a key component of future air quality monitoring activities and mitigation measures.

A Study on the Influence of Blending Ratio of Powder and Oil on the Stability of Talc-Free Pressed Powder Formulation (파우더와 오일의 배합 비율이 탈크 프리 프레스드 파우더 제형의 안정성에 미치는 영향에 관한 연구)

  • Oh, Ji Won;Kim, Hyun Jee;Kwak, Byeong Mun;Jo, Hantae;Lee, Mi-Gi;Bin, Bum-Ho
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.47 no.1
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    • pp.31-40
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    • 2021
  • The main stability factors of the pressed powder include hardness and drop stability. In general, for pressed powder with talc, the hardness and drop stability are evenly met and the skin texture is excellent. Recently, more than ever customers are looking for a replacement due to asbestos issue of talc. Therefore, it is urgent to develop a pressed powder formulation without talc that maintains stability and does not lose its sense of use. In this study, experiments were conducted to find the optimal ingredients mixing ratio to make talc-free pressed powder. The characteristics of raw materials used mainly in powder were checked and the ratio was changed, and the lightness and hardness were measured and drop test was conducted. If the natural mica ratio was higher than the synthetic mica or non-coated silica was used instead of the coated silica, the hardness and drop stability were lower than the content containing talc, but the lightness was similar. Conversely, if the synthetic mica ratio was equal to or higher than the natural mica ratio and the coated silica ratio was equal to or higher than the non-coated silica ratio, the hardness and drop stability of the content containing talc were similar, but the lightness was low. It was found that the hardness was higher than the content containing talc, but the drop stability was lower. Therefore, further study of the correlation between hardness and fall stability is also thought to be necessary.

Evaluation of Hydration Heat Characteristics of Strontium Based Hydration Heat Reducer Addition on Concrete in Hot Weather Condition (서중환경에서 스트론튬계 수화열저감재를 사용한 콘크리트의 수화발열특성 평가)

  • Suh, Dong-Kyun;Kim, Gyu-Yong;Kil, Bae-Su;Koyama, Tomoyuki;Nam, Jeong-Soo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.6
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    • pp.189-196
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    • 2020
  • When concrete member become large like in high rise buildings, hydration heat makes temperature difference inside and outside and cause cracks. The method of using latent heat material as heat reducer could be more accessible, usable and efficient than other methods. Therefore, many studies using PCM as heat reducer are being conducted. Since heat reducer have different reacting temperature, they may be affected by environmental factors like ambient and concrete mixing temperature but studies issuing this are insignificant. Therefore, this paper attempt to evaluate the hydration heat characteristics and quality of concrete using strontium-based PCM under hot weather conditions. As a result, when the strontium-based hydration heat reducer was mixed 3wt.% and 5wt.% in hot weather condition, hydration heat speed and heating rate could be reduced by 8%, 21%, and 75, 85 minutes compared to OPC, respectively. This is considered to be the phase change reaction is relatively promoted when the temperature is high and cause improve performance than room condition result. Later, comparing the efficiency of other types of P.C.M in hot weather condition, and conduct detailed reviews on the strength development in long-term age.

Low-k Polymer Composite Ink Applied to Transmission Line (전송선로에 적용한 Low-k 고분자 복합 잉크 개발)

  • Nam, Hyun Jin;Jung, Jae-Woong;Seo, Deokjin;Kim, Jisoo;Ryu, Jong-In;Park, Se-Hoon
    • Journal of the Microelectronics and Packaging Society
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    • v.29 no.2
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    • pp.99-105
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    • 2022
  • As the chip size gets smaller, the width of the electrode line is also fine, and the density of interconnections is increasing. As a result, RC delay is becoming a problem due to the difference in resistance between the capacitor layer and the electrical conductivity layer. To solve this problem, the development of electrodes with high electrical conductivity and dielectric materials with low dielectric constant is required. In this study, we developed low dielectric ink by mixing commercial PSR which protect PCB's circuits from external factors and PI with excellent thermal property and low-k characteristics. As a result, the ink mixture of PSR and PI 10:3 showed the best results, with a dielectric constant of about 2.6 and 2.37 at 20 GHz and 28 GHz, respectively, and dielectric dissipation was measured at about 0.022 and 0.016. In order to verify the applicability of future applications, various line-width transmission lines produced on Teflon were evaluated, and as a result, the loss of transmission lines using low dielectric ink mixed with PI was 0.12 dB less on average in S21 than when only PSR was used.

Environmental Impact Evaluation of Mechanical Seal Manufacturing Process by Utilizing Recycled Silicon from End-of-Life PV Module (태양광 폐모듈 실리콘을 재활용한 메커니컬 실 제조공정의 환경성평가)

  • Shin, Byung-Chul;Shin, Ji-Won;Kwon, Woo-Teck;Choi, Joon-Chul;Sun, Ju-Hyeong;Jang, Geun-Yong
    • Clean Technology
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    • v.28 no.3
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    • pp.203-209
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    • 2022
  • An environmental evaluation was conducted by employing LCA methodology for a mechanical seal manufacturing process that uses recycled silicon recovered from end-of-cycle PV modules. The recycled silicon was purified and reacted with carbon to synthesize β-SiC particles. Then the particles underwent compression molding, calcination and heat treatment to produce a product. Field data were collected and the potential environmental impacts of each stage were calculated using the LCI DB of the Ministry of Environment. The assessment was based on 6 categories, which were abiotic resource depletion, acidification, eutrophication, global warming, ozone depletion and photochemical oxidant creation. The environmental impacts by category were 45 kg CO2 for global warming and 2.23 kg C2H4 for photochemical oxide creation, and the overall environmental impact by photochemical oxide creation, resource depletion and global warming had a high contribution of 98.7% based on weighted analysis. The wet process of fine grinding and mixing the raw silicon and carbon, and SiC granulation were major factors that caused the environmental impacts. These impacts need to be reduced by converting to a dry process and using a system to recover and reuse the solvent emitted to the atmosphere. It was analyzed that the environmental impacts of resource depletion and global warming decreased by 53.9% and 60.7%, respectively, by recycling silicon from end-of-cycle PV modules. Weighted analysis showed that the overall environmental impact decreased by 27%, and the LCA analysis confirmed that recycling waste modules could be a major means of resource saving and realizing carbon neutrality.

Strength Analysis of 3D Concrete Printed Mortar Prism Samples (3D 콘크리트 프린팅된 모르타르 프리즘 시편의 강도 분석)

  • Kim, Sung-Jo;Bang, Gun-Woong;Han, Tong-Seok
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.35 no.4
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    • pp.227-233
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    • 2022
  • The 3D-printing technique is used for manufacturing objects by adding multiple layers, and it is relatively easy to manufacture objects with complex shapes. The 3D concrete printing technique, which incorporates 3D printing into the construction industry, does not use a formwork when placing concrete, and it requires less workload and labor, so economical construction is possible. However, 3D-printed concrete is expected to have a lower strength than that of molded concrete. In this study, the properties of 3D-printed concrete were analyzed. To fabricate the 3D-printed concrete samples, the extrusion path and shape of the samples were designed with Ultimaker Cura. Based on this, G-codes were generated to control the 3D printer. The optimal concrete mixing proportion was selected considering such factors as extrudability and buildability. Molded samples with the same dimensions were also fabricated for comparative analysis. The properties of each sample were measured through a three-point bending test and uniaxial compression test, and a comparative analysis was performed.

Two-dimensional Spatial Distribution Analysis Using Water Quality Measurement Results at River Junctions (하천 합류부에서의 수질계측결과를 활용한 2차원 공간분포 해석)

  • Lee, Chang Hyun;Park, Jae Gon;Kim, Kyung Dong;Ryu, Si Wan;Kim, Dong Su;Kim, Young Do
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.42 no.3
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    • pp.343-350
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    • 2022
  • High-resolution data are needed to understand water body mixing patterns at river junctions. In particular, in river analysis, hydrological and water quality characteristics are used as basic data for aquatic ecological health, so observation through continuous monitoring is necessary. In addition, since measurement is carried out through a one-dimensional and fixed measurement method in existing monitoring systems, a hydrological and water quality characteristics investigation of an entire river, except for in the immediate vicinity of the measurement point, is not undertaken. In order to obtain high-resolution measurement data, a measurer has to consider multiple factors, and the area or time that can be measured is limited. Although the resolution might be lowered, an appropriate interpolation method must be selected in order to acquire a wide range of data. Therefore, in this study, a high-elevation measurement method at a river junction was introduced, and the interpolation method according to the measurement results was compared. The overall hydraulic and water quality information of the river was indicated through the visualization of the prediction and interpolation method in the low-resolution measurement result. By comparing each interpolation method, Inverse Distance Weighting, Natural Neighbor, and Kriging techniques were applied in river mapping to improve the precision of river mapping through visualized data and quantitative evaluation. It is thought that this study will offer a new method for measuring rivers through spatial interpolation.

Measurement and Prediction of Combustion Characteristics of DEC(Diethyl Carbonate) + DMMP(Dimethyl Methylphosphonate) for Secondary Battery Solutions (2차전지 용액인 DEC(Diethyl Carbonate) + DMMP(Dimethyl Methylphosphonate)계의 연소특성치 측정 및 예측)

  • Y. S. Jang;Y. R. Jang;J. J. Choi;D. J. Jeon;Y. G. Kim;D. M. Ha
    • Journal of the Korean Society of Safety
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    • v.38 no.5
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    • pp.8-14
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    • 2023
  • Lithium ions can induce the thermal runaway phenomenon and lead to reignition due to electrical, mechanical, and environmental factors such as high temperature, smoke generation, explosions, or flames, which is extremely likely to create safety concerns. Therefore, one of the ways to improve the flame retardancy of the electrolyte is to use a flame-retardant additive. Comparing the associated characteristic value of existing substances with the required experimental value, it was found that these values were either considerably different or were not documented. It is vital to know a substance's combustion characteristic values, flash point, explosion limit, and autoignition temperature (AIT) as well as its combustion characteristics before using it. In this research, the flash point and AIT of materials were measured by mixing a highly volatile and flammable substance, diethyl carbonate (DEC), with flame-retardant dimethyl methylphosphonate (DMMP). The flash point of DEC, which is a pure substance, was 29℃, and that for DMMP was 65℃. Further, the lower explosion limit calculated using the measured flash point of DEC was 1.79 Vol.%, while that for DMMP was 0.79 Vol.%. The AIT was 410℃ and 390℃ for DEC and DMMP, respectively. In particular, since the AIT of DMMP has not been discussed in any previous study, it is necessary to ensure safety through experimental values. In this study, the experimental and regression analysis revealed that the average absolute deviation (ADD) for the flash point of the DEC+DMMP DEC+DMMP system is 0.58 sec and that the flash point tends to increase according to changes in the composition employed. It also revealed that the AAD for the AIT of the mixture was 3.17 sec and that the AIT tended to decrease and then increase based on changes in the composition.

Property of tow Shrinkage High Performance Concrete depending on Mixture Proportions and Material Characteristics (배합 및 재료요인에 따른 저수축 고성능 콘크리트의 품질 특성)

  • Han Cheon-Goo;Kim Sung-Wook;Koh Kyoung-Taek;Han Mu-Cheol
    • Journal of the Korea Concrete Institute
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    • v.16 no.6 s.84
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    • pp.805-811
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    • 2004
  • In this paper, effects of mixture proportion and material condition on both fundamental properties, drying and autogenous shrinkage of high performance concrete are discussed. According to the results, for the effect of mixture proportion on the fundamental properties, decrease in W/B and unit water content results in reduction of fluidity, while air content has no variation. Compressive strength exhibits an decreasing tendency with an increase in W/B and unit water content do not remarkable affect the compressive strength. For the effect of materials on the fluidity, the fluidity of low heat portland cement(LPC) is smaller than that of ordinary portland cement(OPC). The use of Polycarbonic acid based superplasticizer(PS) has more favorable effect on enhancing fluidity than Naphtalene based superplasticlzer(NS) and Melamine based superplasticizer(MS). Air content of concrete using LPC is larger than that using OPC. The effects of superplasticizer type on the air content is larger in order of MS, PS and NS. The use of LPC exhibited lower strength development at early age than OPC, whereas after 91days, similar level of compressive strength is achieved regardless of cement type. Compressive strength of concrete is not affected by SP type. For the effect of mixture proportion and materials on drying and autogenous shrinkage, an increase in W/B results in reduction of drying shrinkage and an decrease in water content leads to reduce drying shrinkage. Autogenous shrinkage is not observed until 49 days with the concrete mixture with $35\%$ of W/B and $145 kg/m^3$ of water content. This is due to the combination effects of expansion admixture and shrinkage reducing admixture, which causes an offset of autogenous shrinkage. The use of LPC results in a reduction in autogenous shrinkage compared with OPC. SP type has little influence on the autogenous shrinkage. It is found from the results that mixture proportioning of high performance concrete incorporating fly ash, silica fume, expansion admixture and shrinkage reducing admixture is need to focus on the increase in W/B and the reduction in water content and the use of LPC and MS is also required to use to secure the stability against shrinkage properties.

Spatio-Temporal Distribution of Nutrients in the Surface Waters of Deukryang Bay 1. Seasonal Variation of Nutrients and Limiting Factors for Primary Production (득량만 표층수중 영양염류의 시공간적 분포특성 -1. 영양염류의 계절변화와 기초생산 제한인자-)

  • YANG Han-Soeb;KIM Soung-Soo;KIM Guebuem
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.28 no.4
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    • pp.475-488
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    • 1995
  • In order to see the seasonal variation of nutrients and the limiting factors to the primary production in Deukryang Bay, both dissolved inorganic nutrients and salinity were measured in the surface waters during the periods from July 1992 to March 1993. The mean value of salinity was the lowest in ?all and the highest in early spring. Dissolved inorganic nitrogen (DIN) was the highest in winter and the lowest in summer. However, both phosphate and silicate were the highest in summer and the lowest in fall. Salinity was generally higher in the outer region than in the inner region of the bay.DIN content was nearly depleted (less than $2{\mu}M$) in summer. From fall to spring, DIN content was nearly depleted in the inner region and relatively high in the outer region of the Day. Phosphate was the highest in summer showing an opposite distribution pattern to salinity, and it was nearly depleted (less than $0.1{\mu}M$) in fall and winter. In spring, however, phosphate content was slightly high in the outer region. Silicate content showed an opposite distribution pattern to salinity in summer. in other seasons, However, the distribution pattern of silicate was similar to the salinity. DIN seemed to be a limiting factor for the primary production at all area of the bay in summer and at the inner region in other season. However, phosphate seemed to be a limiting factor at all area of the bay in fall and winter and at the inner region in spring. Silicate may limit the production of diatoms at the inner region of the bay in winter and spying. Both phosphate and silicate showed a good inverse relationship with salinity in summer, which indicates inputs of these nutrients from the freshwater runoff. In the other seasons, both nitrate and silicate showed a positive linear relationship with salinity in the outer region of the bay, suggesting that these two nutrients were mainly supplied by the inflow of the offshore costal water which had high nitrate content associated with vertical mixing.

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