• Title/Summary/Keyword: mixed-phase

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Characterization of FePtN Nano-particles Synthesized by Thermal Decomposition and Mixed-gas Nitrification (열분해법과 혼합가스 질화법으로 합성한 FePtN 나노 입자의 특성)

  • Oh, Young Woo
    • Journal of the Korean Magnetics Society
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    • v.26 no.4
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    • pp.129-132
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    • 2016
  • The effect of thermal-nitrification on L1o transfomation in nano-sized FePt particles was studied. As-synthesized FePt nanoparticles by thermal decomposition method have fcc structured phase and their Hc and Ms were 247.34 Oe and 27.308 emu/g, respectively. According to the XRD analysis, phase transformation from fcc (face centered cubic) to fct (face centered tetragonal) structure was revealed by heating under $NH_3+H_2$ mixed-gas atmosphere. Also a slight shift of each (111) peak indicated phase transformation from fcc to fct structure. Hc and Ms of fct FePtN were 1058.2 Oe and 32.718 emu/g, respectively. The nano-sized FePtN magnetic particles synthesized by thermal decomposition method and mixed-gas nitrification are expected for advanced applications such as high density magnetic recording media and biomedical materials.

Mixed Micellization of Anionic Ammonium Dodecyl Sulfate and

  • Gang, Gye Hong;Kim, Hong Un;Im, Gyeong Hui;Jeong, No Hui
    • Bulletin of the Korean Chemical Society
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    • v.22 no.9
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    • pp.1009-1014
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    • 2001
  • In aqueous mixtures of cationic OTAC (octadecyl trimethyl ammonium chloride) and anionic ADS (ammonium dodecyl sulfate) surfactants, mixed micelles were formed at low (< 0.2 wt %) total surfactant concentrations. For these mixtures mixed micelliza tion and interaction of surfactant molecules were examined. Mixed critical micelle concentration (CMC), thermodynamic potentials of micellization, and minimum area per surfactant molecule at the interface were obtained from surface tensiometry and electrical conductometry. The mixed micellar compositions and the estimation of interacting forces were determined on the basis of a regular solution model. The CMCs were reduced, although not substantial, and synergistic behavior of the ADS and OTAC in the mixed micelles was observed. The CMC reductions in this anionic/cationic system were comparable to those in nonionic/anionic surfactant systems. The interaction parameter $\beta$ of the regular solution model was estimated to be -5 and this negative value of $\beta$ indicated an overall attractive force in the mixed state.

Synthesis and Photocatalytic Properties of SnO2-Mixed and Sn-Doped TiO2 Nanoparticles

  • Choi, Hong-Goo;Yong, Seok-Min;Kim, Do-Kyung
    • Korean Journal of Materials Research
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    • v.22 no.7
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    • pp.352-357
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    • 2012
  • $SnO_2$-mixed and Sn-doped $TiO_2$ nanoparticles were synthesized via a hydrothermal process. $SnO_2$-mixed $TiO_2$ nanoparticles prepared in a neutral condition consisted of anatase $TiO_2$ nanoparticles(diamond shape, ~25 nm) and cassiterite $SnO_2$ nanoparticles(spherical shape, ~10 nm). On the other hand, Sn-doped $TiO_2$ nanoparticles obtained under a high acidic condition showed a crystalline phase corresponding to rutile $TiO_2$. As the Sn content increased, the particle shape changed from rod-like(d~40 nm, 1~200 nm) to spherical(18 nm) with a decrease in the particle size. The peak shift in the XRD results and a change of the c-axis lattice parameter with the Sn content demonstrate that the $TiO_2$ in the rutile phase was doped with Sn. The photocatalytic activity of the $SnO_2$-mixed $TiO_2$ nanoparticles dramatically increased and then decreased when the $SnO_2$ content exceeded 4%. The increased photocatalytic activity is mainly attributed to the improved charge separation of the $TiO_2$ nanoparticles with the $SnO_2$. In the case of Sn-doped $TiO_2$ nanoparticles, the photocatalytic activity increased slightly with the Sn content due most likely to the larger energy bandgap caused by Sn-doping and the decrease in the particle size. The $SnO_2$-mixed $TiO_2$ nanoparticles generally exhibited higher photocatalytic activity than the Sn-doped $TiO_2$ nanoparticles. This was caused by the phase difference of $TiO_2$.

An experimental study on thermal performance evaluation of PCM mixed coating material constructed in and out of the wall (벽체 내·외부에 시공한 PCM혼입 도료의 열적성능 평가에 관한 실험적 연구)

  • Ju, Dong-Uk;Shin, Sang-Heon;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2014.05a
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    • pp.216-217
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    • 2014
  • Optimum finishing position, thickness and phase change temperature of winter and summer season were selected and suitability of finishing materials was evaluated based on temperature measurement of specimens applying the coating material mixed phase change materials(PCM). As a result, when finishing position was interior and finishing thickness of coating material mixed n-Octadecane(28℃ PCM) was 4mm, thermal performance was effective. n-Octadecane in summer season and n-Hexadecane(18℃ PCM) in winter season are indicated effective on energy savings, respectively.

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Smart Solid State Syntheses of Well-Crystallized Phase Pure Mixed Oxides for Electroceramics

  • Sennat, Mamoru
    • Journal of the Korean Ceramic Society
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    • v.43 no.11 s.294
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    • pp.680-687
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    • 2006
  • An overview is given to optimize the solid state processes toward phase pure and well-crystallized fine particulates of mixed oxides, serving as electroceramic materials in various genres. Elevation of the reactivity and preservation of stoichiometry of the starting mixture are of universal importance. Mechanical activation is versatile for these purposes, particularly when an oxygen atom as a hinge promotes formation of hetero-bridging bonds between dissimilar cationic species prior to calcination. Case studies carried out recently in the author's laboratory are displayed and compared for ferroelectric materials, i.e. $PbMg_{1/3}Nb_{2/3}O_3$ $xPbTiO_3$(PMN-PT), $(1-y)Pb(Zn_xMg{1-x})_{1/3}$ $yNb_{2/3}O_3$ (PZN-PMN), $BaBi_2Ta_2O_9$ (BBT), $Ba(Mg_{1/3}Ta_{2/3})O_3$ (BMT), and ferromagnetics, i.e. M-, Y-, and Z-phases of Ba-hexaferrites.

Relationship Between Mechanical Properties and Damping Capacity in Stainless Steel with Two Phases of Reversed Austenite and Deformation Induced Martensite (역변태 오스테나이트와 가공유기 마르텐사이트의 2상 혼합조직을 갖는 스테인리스강의 기계적 성질과 감쇠능)

  • Namgung, Won;Jung, Mok-Hwan;Lee, Hyang-Beak;Kim, Jae-Nam;Kang, Chang-Young
    • Journal of Power System Engineering
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    • v.17 no.2
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    • pp.114-120
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    • 2013
  • This study was carried out to investigate the relationship between mechanical properties and damping capacity in high manganese austenitic stainless steel with two phase mixed structure of reversed austenite and deformation induced martensite. Reversed austenite of ultra-fine grain size less than $0.3{\mu}m$ was obtained by reversion treatment. Two phase structure of deformation induced martensite and reversed austenite was obtained by annealing treatment at range of $500^{\circ}C{\sim}700^{\circ}C$ for various time in cold rolled high manganese austenite stainless steel. In stainless steel with two phase mixed structure of martensite and austenite, damping capacity decreased rapidly with the increasing hardness and strength. With the increasing elongation, damping capacity was increased rapidly and then, slowly increased.

Strength and Deformation Characteristic of Two-Phase Mixture Soil (폐기물을 포함한 이종혼합토의 강도·변형특성)

  • Lee, Ki-Ho
    • Journal of the Korean GEO-environmental Society
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    • v.2 no.2
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    • pp.33-39
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    • 2001
  • In order to utilize mass of oyster shells for a partial substitute material for reclamation, the shear characteristics of two-phase mixture soil with oyster shells were investigated with $\overline{CU}$ test. From various experiments, it was found that the increase of mixed ratio of oyster shells causes the shear strength of mixed soil. And this phenomenon not only depends on friction due to confining pressure such as pure clay but also is influenced by shaping skeleton of oyster shells. Also, it was discovered that there were many influences by clay-oyster shell mixture from the study of the secant modulus and dilatancy characteristics of mixed soil. In addition, variation of oyster shell skeleton during shearing stage is examined applying modifying coefficient concept.

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A study on Properties of YbBaCuO Superconductor with various calcination conditions (하소 조건 변화에 따른 YbBaCuO 초전도체 의 특성 연구)

  • 이영매;박정철;소대화
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.68-72
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    • 1997
  • In this paper, to obtain the YbB $a_2$C $u_3$ $O_{x}$ superconductor, the mixed Powders of Y $b_2$ $O_3$, BaC $O_3$, CuO and Y $b_2$BaCu $O_{5}$, BaCu $O_2$ were used and the various calcining conditions were applied for the 123 phase of YbB $a_2$C $u_3$ $O_{x}$. Samples were prepared by the mixed oxide method and calcined with various temperatures of 88$0^{\circ}C$ ~91$0^{\circ}C$ . It was observed that the distribution of YbB $a_2$C $u_3$ $O_{x}$ phase which was calcined at 90$0^{\circ}C$ for 12 hours and 99 hours. But the result of long time calcination(99 hrs), the 123 phase of YbB $a_2$C $u_3$ $O_{x}$ was existed between 89$0^{\circ}C$ and 91$0^{\circ}C$ . And the best case could be obtained at the calcination temp. of 90$0^{\circ}C$ from the mixed Powder of YbB $a_2$C $u_3$ $O_{5}$ and Bacu $O_2$ which were prepared individually.idually.

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Mixed Dual-rail Data Encoding Method Proposal and Verification for Low Power Asynchronous System Design (저전력 비동기식 시스템 설계를 위한 혼합형 dual-rail data encoding 방식 제안 및 검증)

  • Chi, Huajun;Kim, Sangman;Park, Jusung
    • Journal of the Institute of Electronics and Information Engineers
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    • v.51 no.7
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    • pp.96-102
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    • 2014
  • In this paper, we proposed new dual-rail data encoding that mixed 4-phase handshaking protocol and 2-phase handshaking protocol for asynchronous system design to reduce signal activities and power consumption. The dual-rail data encoding 4-phase handshaking protocol should leat to much signal activities and power consumption by return to space state. Ideally, the dual-rail data encoding 2-phase handshaking protocol should lead to faster circuits and lower power consumption than the dual-rail 4-phase handshaking protocol, but can not designed using standard library. We use a benchmark circuit that contains a multiplier block, an adder block, and latches to evaluate the proposed dual-rail data encoding. The benchmark circuit using the proposed dual-rail data encoding shows an over 35% reduction in power consumption with 4-phase dual-rail data encoding.

A Mixed Nonlinear Filter for Image Restoration under AWGN and Impulse Noise Environment

  • Gao, Yinyu;Kim, Nam-Ho
    • Journal of information and communication convergence engineering
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    • v.9 no.5
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    • pp.591-596
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    • 2011
  • Image denoising is a key issue in all image processing researches. Generally, the quality of an image could be corrupted by a lot of noise due to the undesired conditions of image acquisition phase or during the transmission. Many approaches to image restoration are aimed at removing either Gaussian or impulse noise. Nevertheless, it is possible to find them operating on the same image, which is called mixed noise and it produces a hard damage. In this paper, we proposed noise type classification method and a mixed nonlinear filter for mixed noise suppression. The proposed filtering scheme applies a modified adaptive switching median filter to impulse noise suppression and an efficient nonlinear filer was carried out to remove Gaussian noise. The simulation results based on Matlab show that the proposed method can remove mixed Gaussian and impulse noise efficiently and it can preserve the integrity of edge and keep the detailed information.