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Properties of Plywood Bonded with Adhesive Resins Formulated with Enzymatically-Hydrolyzed Rapeseed Flour (유채박의 효소 가수분해물로 조제한 접착제를 사용한 합판의 접착특성)

  • Yang, In;Han, Gyu-Seong;Choi, In-Gyu;Kim, Yong-Hyun;Ahn, Sye-Hee;Oh, Sei-Chang
    • Journal of the Korean Wood Science and Technology
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    • v.40 no.3
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    • pp.164-176
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    • 2012
  • In the present study, rapeseed flour (RSF), which is a by-product from the production of edible oil and biodiesel extracted from rapeseed, was used to develop alternative adhesives for the production of plywood panels. To examine the effects of the enzyme on the adhesive properties and formaldehyde emission of the RSF-based adhesive resins, three enzymes, such as cellulase (CEL), pectinase (PEC) and protease (ALC), were used either separately or together. As a crosslinking agent, PF prepolymers, which were prepared with 1.5, 1.8 and 2.1 mole formaldehyde and 1 mol phenol (1.8-, 2.1- and 2.4-PF), were added into the RSF hydrolyzates. The adhesive resins formulated with CEL- or CEL-PEC-RSF hydrolyzates and 1.8-F/P PF prepolymers exhibited excellent adhesive strengths and formaldehyde emission. The tensile shear strength and formaldehyde emission of the plywood panels bonded with the formulate resins were satisfied with the minimum requirement of the KS standard for ordinary plywood panels (0.6 N/$mm^2$). In addition, formaldehyde emissions of the plywood panels approached to that of E0 specified in the KS standard (0.5 mg/${\ell}$), and even had much better than those of commercial UF glue mixes. Overall, the use of RSF-based adhesive resins for the production of plywood panels might provide durable adhesive properties and an environmentally friendly substitute for petroleum-based adhesive resins. However, further researches - the increase of solid content of RSF-based adhesives for reducing press time and the microscopic observation of plywood specimen for identifying the relationship between tensile shear strength and the penetration of adhesives into wood structure - are required to commercialize the RSF-based adhesives.

Fungicide Resistance of Fusarium fujikuroi Isolates Isolated In Korea (우리나라에서 분리한 벼 키다리병균(Fusarium fujikuroi)의 살균제 저항성)

  • Lee, Yong-Hwan;Kim, So-Yeon;Choi, Hyo-Won;Lee, Myeong-Ji;Ra, Dong-Soo;Kim, In-Seon;Park, Jin-Woo;Lee, Se-Weon
    • The Korean Journal of Pesticide Science
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    • v.14 no.4
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    • pp.427-432
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    • 2010
  • Rice bakanae disease caused by Fusarium fujikuroi is one of the most serious rice diseases in Korea. From 2006 to 2009, 118 F. fujikuroi isolates were collected from various regions of rice fields in Korea. Resistance assay of 118 F. fujikuroi isolates to prochloraz, tebuconazole, and benomyl, were performed using agar dilution method. To investigate inhibitory effects of the fungicides, minimum inhibitory concentration of mycelial growth (MIC) and effective concentration inhibiting mycelial growth by 50% ($EC_{50}$) for 118 isolates were calculated using Sigmaplot 8.02 (Antro, SPSS UK, Ltd). Based on the means of $EC_{50}$ values, baseline resistance values were determined as $0.5{\mu}g{\cdot}mL^{-1}$ for prochloraz, $5.0{\mu}g{\cdot}mL^{-1}$ for tebuconazole and $2.5{\mu}g{\cdot}mL^{-1}$ for benomyl. Number of resistant isolates to each fungicide was 17, 19 and 43 for prochloraz, tebuconazole and benomyl, respectively. Furthermore, 4 isolates showed the double resistance to both prochloraz and tebuconazole, 6 isolates to prochloraz and benomyl, and 11 isolates to tebuconazole and benomyl. Isolates CF366 and LF335 isolated from Gyeongbuk province were resistant to the three fungicides tested, prochloraz, tebuconazole and benomyl.

Assessment of Soil and Water Quality in some Catchments of Different Agricultural Practices in Nakdong River Basin (낙동강 유역 농업지대에서 영농형태별 토양과 수질 평가)

  • Kim, Min-Kyeong;Seo, Myung-Chul;Lee, Nam-Jong;Chung, Jong-Bae;Kim, Bok-Jin
    • Korean Journal of Soil Science and Fertilizer
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    • v.36 no.1
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    • pp.16-23
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    • 2003
  • Soil and water quality was monitored in the Nakdong River basin to assess the impact of different agricultural practices. From five catchments, soil samples were collected at three times during 1996 to 1998, and water samples were collected at twelve times on July during 1995 to 1999. The major agricultural practices were paddy and upland farming in three areas surveyed: Youngju, Goryung, and Milyang. Apple orchards were located along in the Imgo-Cheon catchment. Intensive vegetable farming in plastic fIlm house was practiced in the Habin-Cheon catchment. Total N contents, 0.04-0.32%, of paddy soils were low in comparison with those of upland, orchard, and plastic film house soils. Available phosphate($P_2O_5$) contents, $2-421mg\;kg^{-1}$, in plastic film house soils were higher than those in paddy soils. In plastic film house and upland soils, CEC of soils were high. The N concentrations in most of the streams were higher than $1.0mg^{-1}$, the standard of agricultural irrigation water. The P concentrations were above $1.0mg^{-1}$, the standard of agricultural irrigation water and were higher than the minimum level for eutrophication, $0.01-0.05mg\;L^{-1}$ in most of the streams. In conclusion, nutrients by agricultural activity could affect water quality of streams near the agricultural fields. Good water quality in streams can be maintained by proper management of agricultural fields and by decreasing application amount of fertilizers in agricultural fields.

Stable Liquid Paraffin-in-Water Nanoemulsions Prepared by Phase Inversion Composition Method (조성 상전이 방법으로 제조된 안정한 액상 파라핀-물 나노에멀젼)

  • Kim, Eun Hee;Cho, Wan Goo
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.40 no.2
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    • pp.133-139
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    • 2014
  • Oil-in-water nanoemulsions were prepared in the system of water/Span 80-Tween 80/long-chain paraffin oil via the PIC (phase inversion composition) method. With the increase of preparation temperature from $30^{\circ}C$ to $80^{\circ}C$, the diameter of emulsion droplets decreased from 120 nm to 40 nm, proving the formation of nanoemulsions. By varying the HLB (hydrophilic lipophilic balance) of mixed surfactants, we found that there was an optimum HLB around 12.0 ~ 13.0 corresponding to the minimum droplet size. The viscosity of nanoemulsions clearly increased with droplet volume fraction, f, but the droplet size slightly increased. Significantly, at ${\phi}{\leq}0.3$, the size distribution of nanoemulsions kept constant more than 2 months. These results proved that the viscous paraffin oil can hardly be dispersed by the PIC method at $30^{\circ}C$, but the increase in preparation temperature makes it possible for producing monodisperse nanoemulsions. Once the nanoemulsion is produced, the stability against Ostwald ripening is outstanding due to the extremely low solubility of the liquid paraffin oil in the continuous phase. The highly stable nanoemulsions are of great importance in cosmetic applications.

Fabrication and characterization of the 0.25 ${\mu}m$ T-shaped gate P-HEMT and its application for MMIC low noise amplifier (0.25 ${\mu}m$ T형 게이트 P-HEMT 제작 및 특성 평가와 MMIC 저잡음 증폭기에 응용)

  • Kim, Byung-Gyu;Kim, Young-Jin;Jeong, Yoon-Ha
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.36D no.1
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    • pp.38-46
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    • 1999
  • o.25${\mu}m$ T-shaped gate P-HEMT is fabricated and used for design of X0band three stage monolithic microwave integrated circuit(MMIC) low noise amplifier(LNA). The fabricated P-HEMT exhibits an extrinsis transconductance of 400mS/mm and a drain current of 400mA/mm. The RF and noise characteristics show that the current gain cut off frequency is 65GHz and minimum noise figure(NFmin) of 0.7dB with an associated gain of 14.8dB at 9GHz. In the design of the three stage LNA, we have used the inductive series feedback circuit topology with the short stub. The effects of series feedback to the noise figure, the gain, and the stability have been investigated to find the optimal short stub length. The designed three staage LNA showed a gain of above 33dB, a noise figure of under 1.2dB, and ainput/output return loss of under 15dB and 14dB, respectively. The results show that the fabricated P-HEMT is very suitable for a X-band LNA with high gain.

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Characterization of quality changes of whole super sweet corn (Zea mays saccharata Sturt.) during thermal sterilization for shelf-stable products (상온유통을 위한 가열살균 중의 통 초당옥수수의 품질변화 연구)

  • Lee, Yun Ju;Yoon, Won Byong
    • Journal of Applied Biological Chemistry
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    • v.62 no.1
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    • pp.25-30
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    • 2019
  • This study investigated the quality changes in whole super sweet corn during thermal processing to extend its shelf-life. To minimize the reduction of unique texture of whole sweet corn after the sterilization, the alcohol sanitation applied and the cold point of a whole corn ear was determined using a computer simulation. The cold point was located between the corn kernel and the cob. The microorganisms on the surface of sweet corn were reduced by more than 1 log CFU/g after alcohol sanitation, then the whole corn was treated to satisfy the degree of sterilization ($F_{121.1}=4$). The quality of sterilized sweet corn was compared with the control that was treated with steaming. The quality changes of sterilized sweet corn during storage were monitored for 9 months at $25^{\circ}C$. The hardness was maintained within 30% of its initial value. The minimum of hardness was $464.50{\pm}103.35g$ and maximum of hardness was $514.50{\pm}81.83g$. The differences in the sugar content among the samples were found, but the sugar content of corn kernel remained within 30% of the control, ranging from $28.83{\pm}1.05$ to $34.36{\pm}0.42%$. The yellowness was higher than that of control by 5%. The maximum value of yellowness was $34.36{\pm}0.42$. The general bacteria and molds and yeasts in corn kernel stored at $25^{\circ}C$ were not detected after 9 months of storage at $25^{\circ}C$. Therefore, in this study, we have demonstrated that the thermal sterilized method extends the shelf-life of whole sweet corn with minimizing its quality changes over 6 months in room temperature.

The Design of Broadband Ultrasonic Transducers for Fish Species Identification - Bandwidth Enhancement of a Ultrasonic Transducer Using Double Acoustic Matching Layers- (어종식별을 위한 광대역 초음파 변환기의 설계 ( III ) - 이중음향정합층을 이용한 초음파 변환기의 대역폭 확장 -)

  • 이대재
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.34 no.1
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    • pp.85-95
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    • 1998
  • The broadband ultrasonic transducers have been designed to use in obtaining the broadband echo signals from fish schools in relation to the identification of fish species. The broadening of bandwidth was achieved by attaching double acoustic matching layers on the front face of a Tonpilz transducer consisted of an aluminum head, a piezoelectric ring, a brass tail and to evaluate the performance characteristics, such as the transmitting voltage response(TVR) of transducers. The constructed transducers were tested experimentally and numerically by changing the parameters such as impedances and thicknesses of the head, tail and matching layers, in the water tank. Also, the developed transducer was excited by a chirp signal and the received chirp waveforms were analyzed. According to the measured TVR results, the available 3 dB bandwidth of the transducer with double matching layers of an $Al_O_3/epoxy$ composite of 7 mm thick and a polyurethane window of 18 mm thick was 7.3 kHz with a center frequency of 38.8 kHz, and the maximum and the minimum values of the TVR in this frequency region were 135.7 dB and 132.7 dB re $1\;{\mu}Pa/V$ at 1 m, respectively. Also, the available 3 dB bandwidth of the transducer with double matching layers of an $Al_O_3/epoxy$ composite of 11 mm thick and a polyurethane window of 15 mm thick was 6.2 kHz with a center frequency of 38.6 kHz, and the maximum TVR value in the frequency region was 136.3 dB re $1\;{\mu}Pa/V$ at 1 m. Reasonable agreement between the experimental results and the numerical results for the TVR of the developed transducers was achieved. The frequency dependant characteristics of experimentally observed chirp signals closely matched to the measured TVR results. These results suggest that there is potential for increasing the bandwidth by varying other parameters in the transducer design and the material of the acoustic matching layers.

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X-band CW Doppler Radar Development for Measurement of Muzzle Velocity (포구 속도 측정을 위한 X-band CW 도플러 레이더 개발)

  • Kim, Jae-Heon;Koh, Yeong-Mok;NamGung, Sung-Won;Jang, Yong-Sik;Park, Yong-Seok;Ra, Keuk-Hwan;Choi, Ik-Kwon
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.20 no.5
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    • pp.460-470
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    • 2009
  • In this paper, we described the implementation of the X-Band continuous-wave doppler radar for muzzle velocity measurement. The radar is consisted of microwave transceiver, signal processor, power board, and the measuring program was developed for the operating and field test. The operating frequency of doppler radar is able to set ${\pm}3\;MHz$ with 5 channel from the center frequency, and the output power is 25 dBm. The minimum receiving power is -117 dBm. The radar would obtain the doppler frequency from the artillery, and calculate accurate velocity point and then estimate muzzle velocity. The performance test for this radar was done with 155 mm at barrel and tripod mounted, and also compared the performance with the reference radar. As a result, the performance of the our new radar is equal with the reference one.

Mid-latitude Geomagnetic Field Analysis Using BOH Magnetometer: Preliminary Results

  • Hwang, Jun-Ga;Choi, Kyu-Cheol;Lee, Jae-Jin;Park, Young-Deuk;Ha, Dong-Hun
    • Journal of Astronomy and Space Sciences
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    • v.28 no.3
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    • pp.173-181
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    • 2011
  • Korea Astronomy and Space Science Institute researchers have installed and operated magnetometers at Mt. Bohyun Observatory to measure the Earth's magnetic field variations in South Korea. We, in 2007, installed a fluxgate magnetometer (RFP-523C) to measure H, D, and Z components of the geomagnetic field. In addition, in 2009, we installed a Overhauser proton sensor to measure the absolute total magnetic field F and a three-axis magneto-impedance sensor for spectrum analysis. Currently three types of magnetometer data have been accumulated. In this paper, we provide the preliminary and the first statistical analysis using the BOH magnetometer installed at Mt. Bohyun Observatory. By superposed analysis, we find that daily variations of H, D, and Z shows similar tendency, that is, about 30 minutes before the meridian (11:28) a minimum appears and the time after about 3 hours and 30 minutes (15:28) a maximum appears. Also, a quiet interval start time (19:06) is near the sunset time, and a quiet interval end time (06:40) is near the sunrise time. From the sunset to the sunrise, the value of H has a nearly constant interval, that is, the sun affects the changes in H values. Seasonal variations show similar dependences to the sun. Local time variations show that noon region has the biggest variations and midnight region has the smallest variations. We compare the correlations between geomagnetic variations and activity indices as we expect the geomagnetic variation would contain the effects of geomagnetic activity variations. As a result, the correlation coefficient between H and Dst is the highest (r = 0.947), and other AL, AE, AU index and showed a high correlation. Therefore, the effects of geomagnetic storms and geomagnetic substorms might contribute to the geomagnetic changes significantly.

Formulation of Ceftriaxone Conjugated Gold Nanoparticles and Their Medical Applications against Extended-Spectrum β-Lactamase Producing Bacteria and Breast Cancer

  • El-Rab, Sanaa M.F. Gad;Halawani, Eman M.;Hassan, Aziza M.
    • Journal of Microbiology and Biotechnology
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    • v.28 no.9
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    • pp.1563-1572
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    • 2018
  • Gold nanoparticles (AuNP) and their conjugates have been gaining a great deal of recognition in the medical field. Meanwhile, extended-spectrum ${\beta}$-lactamases (ESBL)-producing bacteria are also demonstrating a challenging problem for health care. The aim of this study was the biosynthesis of AuNP using Rosa damascenes petal extract and conjugation of ceftriaxone antibiotic (Cef-AuNP) in inhibiting ESBL-producing bacteria and study of in vitro anticancer activity. Characterization of the synthesized AuNP and Cef-AuNP was studied. ESBL-producing strains, Acinetobacter baumannii ACI1 and Pseudomonas aeruginosa PSE4 were used for testing the efficacy of Cef-AuNP. The cells of MCF-7 breast cancer were treated with previous AuNP and Cef-AuNP at different time intervals. Cytotoxicity effects of apoptosis and its molecular mechanism were evaluated. Ultraviolet-visible spectroscopy and Fourier transform infrared spectroscopy established the formation of AuNP and Cef-AuNP. Transmission electron microscope demonstrated that the formed nanoparticles were of different shapes with sizes of 15~35 nm and conjugation was established by a slight increase in size. Minimum inhibitory concentration (MIC) values of Cef-AuNP against tested strains were obtained as 3.6 and $4{\mu}g/ml$, respectively. Cef-AuNP demonstrated a decrease in the MIC of ceftriaxone down to more than 27 folds on the studied strains. The biosynthesized AuNP displayed apoptotic and time-dependent cytotoxic effects in the cells of MCF-7 at a concentration of $0.1{\mu}g/ml$ medium. The Cef-AuNP have low significant effects on MCF-7 cells. These results enhance the conjugating utility in old unresponsive ceftriaxone with AuNP to restore its efficiency against otherwise resistant bacterial pathogens. Additionally, AuNP may be used as an alternative chemotherapeutic treatment of MCF-7 cancer cells.