• Korean Journal of Mineralogy and Petrology
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• v.35 no.3
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• pp.215-233
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• 2022

The zircon U-Pb and trace element analyses were performed for banded gneiss in the Euiam gneiss complex, central Gyeonggi Massif. An age of detrital zircon shows predominant age peaks at ca. 2500-2480 Ma with numerous ages ranging from Siderian to Rhyacian period. The youngest age peak of detrital zircon constrains the maximum deposition age of protolith of banded gneiss at ca. 2070 Ma. Meanwhile, the zircon rim yielded metamorphic age of ca. 1966 ± 39 Ma ~ 1918 ± 13 Ma. Based on the error range, degree of discordancy, and value of mean squared weighted deviation, we considered that the age of 1918 ± 13 Ma is the most reasonable age indicating the timing of metamorphism for banded gneiss. The zircon rims yield Ti-in-zircon crystallization temperature of 690-740℃. Therefore, we suggested that there was a high-grade metamorphic event in the Gyeonggi Massif at ca. 1918 Ma which is older than the metamorphic event that occurred in the Gyeonggi Massif during ca. 1880-1860 Ma.

• Tunnel and Underground Space
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• v.33 no.3
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• pp.189-207
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• 2023

In the present study, the thermoshearing experiment on a rough rock fracture were modeled using a three-dimensional grain-based distinct element model (GBDEM). The experiment was conducted by the Korea Institute of Construction Technology to investigate the progressive shear failure of fracture under the influence of thermal stress in a critical stress state. The numerical model employs an assembly of multiple polyhedral grains and their interfaces to represent the rock sample, and calculates the coupled thermo-mechanical behavior of the grains (blocks) and the interfaces (contacts) using 3DEC, a DEM code. The primary focus was on simulating the temperature evolution, generation of thermal stress, and shear and normal displacements of the fracture. Two fracture models, namely the mated fracture model and the unmated fracture model, were constructed based on the degree of surface matedness, and their respective behaviors were compared and analyzed. By leveraging the advantage of the DEM, the contact area between the fracture surfaces was continuously monitored during the simulation, enabling an examination of its influence on shear behavior. The numerical results demonstrated distinct differences depending on the degree of the surface matedness at the initial stage. In the mated fracture model, where the surfaces were in almost full contact, the characteristic stages of peak stress and residual stress commonly observed in shear behavior of natural rock joints were reasonably replicated, despite exhibiting discrepancies with the experimental results. The analysis of contact area variation over time confirmed that our numerical model effectively simulated the abrupt normal dilation and shear slip, stress softening phenomenon, and transition to the residual state that occur during the peak stress stage. The unmated fracture model, which closely resembled the experimental specimen, showed qualitative agreement with the experimental observations, including heat transfer characteristics, the progressive shear failure process induced by heating, and the increase in thermal stress. However, there were some mismatches between the numerical and experimental results regarding the onset of fracture slip and the magnitudes of fracture stress and displacement. This research was conducted as part of DECOVALEX-2023 Task G, and we expect the numerical model to be enhanced through continued collaboration with other research teams and validated in further studies.

• Journal of the Mineralogical Society of Korea
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• v.24 no.4
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• pp.265-278
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• 2011

Clayey ores of the Jeonnam province mainly consist of pyrophyllite (monoclinic), kaolinite (1T), and minor amounts of quartz, muscovite, and feldspars. Mineralogical studies revealed that two kinds of clay minerals were mainly produced from the volcanic sediments with similar ages and compositions. Kaolinite deposits sometimes contain neither diaspore nor corundum, but alunites are often found in the upper portions of the kaolin ore bodies. On the other hand, corundum and diaspore are commoner in the pyrophyllite deposits than the kaolin deposits. As ages of rock formations are becoming younger, amounts of pyrophyllite and kaolinite are rather radically decreased, and finally disappeared. But muscovite, quartz, and plagioclase feldspars are inclined to be preserved because of weak alteration. Most of clay ore bodies contain purple tuff beds on the uppermost portion, and silicified beds, tuff, and lapillistone are found in an ascending order in the most of clay quarries. Chemical analyses show that higher contents of $Al_2O_3$ might not necessarily be due to the argillization, since some tuffs contain higher $Al_2O_3$ contents originated from feldspars. $SiO_2$ contents are fairly higher in the silicified beds than in those of adjacent formations, which might have been introduced from the ore bodies. And $K_2O$ contents are obviously lower than those of $Na_2O$ and CaO in the ores and their vicinities. Ignition losses of some of clays represent much higher contents than those of the ordinary ones because of the sporadic presence of alunite, diaspore and corundum which are accompanied with lots of $SO_4$ and $Al_2O_3$ contents. REE (rare earth element) abundances of most of volcanics and clay ores show rather higher LREE (light rare earth elements) contents, and represent small to moderately negative Eu anomalies. Though most of ores ususally show milky white color, fine-grained and well bedded formations which could be easily discernible in the most of outcrop. But more distinct characteristics are desirable where rather massive ore bodies exist. Purple tuffs and silicified beds above the ore bodies would be useful as marker horizons/key beds since they have rather obvious lithology, extension and mineralogy than those of other adjacent formations.

• Korean Journal of Mineralogy and Petrology
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• v.35 no.3
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• pp.355-365
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• 2022

Precipitation and phase transition of iron minerals in mine drainage greatly affect the behavior of trace elements. However, the precipitation of ferrihydrite, one of the major iron minerals precipitated in drainage, and the related behavior of trace elements have hardly been studied. In this study, the effects of pH change and time on mineral precipitation characteristics in mine drainage from the Munkyeong coal mine were investigated, and the behavioral changes of trace elements related to the precipitation of these minerals were studied. In the case of precipitated mineral phases, goethite was observed at pH 4, and 2-line ferrihydrite mixed with small amount of 6-line ferrihydrite was mainly identified at pH 6 or higher. In addition, it was observed that the precipitation of calcite additionally increased as the pH increased in the samples at pH 6 or higher. The occurrence of goethite was probably due to the phase change of initially precipitated ferrihydrite within a short time under the influence of low pH. Our results showed that the concentration of trace elements was strongly influenced by pH and time. With increasing time, Fe concentration in the drainage showed a abrupt decrease due to the precipitation of iron minerals, and the concentration of As existing as oxyanions in the drainage, also decreased rapidly like Fe regardless of the pH values. This decrease in As concentration was mainly due to co-precipitation with ferrihydrite, and also partly to surface adsorption on goethite at low pH in drainage. Contrary to this observation, the concentration of other trace elements, such as Cd, Co, Zn, and Ni was greatly affected by the pH regardless of the mineral species. The lower the pH value, the higher the concentration of these trace elements were observed in the drainage, and vice versa at higher pH. These results indicate that the behavior of trace elements present as cations is more greatly affected by the mineral surface charge influenced by the pH values than the type of the precipitated mineral.

• The Korean Journal of Mycology
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• v.21 no.4
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• pp.273-278
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• 1993

In order to determine of trace mineral elements of wild edible mushrooms in Korea, the dried carpophores of Armillariella mella(Vahl.ex Fr.) karst., Armillariella tabescens(Scop.) Sing., Lepista nuda(Bull.ex Fr.) Cooke and Lepista sordida(Schum.ex Fr.) Sing., Hygrophorus russula (Schaeff.ex Fr.) Qu'el., Hygrocybe conica(Scop.ex Fr.) Kummur were incinerated and analyzed by an atom adsorption spectrophotometry. The six mushrooms contained ubiquitously potassium, iron, zinc, sodium, manganase, copper and calsium in that order, and the content of potassium was the highest than other inorganic components and the content of zinc in Hygrocybe conica was especially the most than the other five mushrooms. Total contents of inorganic components(except Cd) were universally the highest in Hygrocybe conica than other five mushrooms, and decrease in order Hygrophorus russula, lepista nuda, lepista sordida, Aarmillariella mella and Armillariella tabescens. Calsium was not present in Amillariella mella and lepista nuda, and copper not in Hygro­cybe conica, and content of cadimium in Hygrophorus russula and Hygrocybe conica were trace.

• Geophysics and Geophysical Exploration
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• v.14 no.1
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• pp.7-17
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• 2011

We have developed an inversion code for three-dimensional (3D) resistivity tomography including the anisotropy effect. The algorithm is based on the finite element approximations for the forward modelling and Active Constraint Balancing method is adopted to enhance the resolving power of the smoothness constraint least-squares inversion. Using numerical experiments, we have shown that anisotropic inversion is viable to get an accurate image of the subsurface when the subsurface shows strong electrical anisotropy. Moreover, anisotropy can be used as additional information in the interpretation of subsurface. This algorithm was also applied to the field dataset acquired in the abandoned old mine area, where a high-rise apartment block has been built up over a mining tunnel. The main purpose of the investigation was to evaluate the safety analysis of the building due to old mining activities. Strong electrical anisotropy has been observed and it was proven to be caused by geological setting of the site. To handle the anisotropy problem, field data were inverted by a 3D anisotropic tomography algorithm and we could obtain 3D subsurface images, which matches well with geology mapping observations. The inversion results have been used to provide the subsurface model for the safety analysis in rock engineering and we could assure the residents that the apartment has no problem in its safety after the completion of investigation works.

• Journal of Korean Medicine for Obesity Research
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• v.9 no.2
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• pp.33-45
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• 2009

Objectives This study was performed to evaluate the relation between hair tissue mineral elements(HTME) and Heart rate variability(HRV) of the metabolic syndrome(MS). Methods 89 persons(41-69 ages) who visited Oriental hospital for medical examination were divided MS group(n=22) and control group(n=67). HTME and HRV were compared, and were analyzed correlation with five contents of the MS. Results (1) In total subjects, waist circumference had a positive correlation with Pb. Blood pressure had a negative correlation with Mg. High density lipoprotein cholesterol(HDL-chol) had a negative correlation with Pb, Sb and K, while positive correlation with Ca/K. Triglyceride(TG) had a negative correlation with Mg and Na/K, while positive correlation with K and Ca/Mg. (2) In total subjects, TG and fasting blood sugar(FBS) had negative correlation with high frequency(HF), while positive correlation with low frequency/high frequency ratio(LF/HF). (3) In MS group, most of the level of toxic minerals were higher, and the level of major nutritional minerals were lower, but there were no statistical signficance. In two groups, there is no contrast between the correlations of the MS contents and HTME. (4) In MS group, HF was significantly lower and LF/HF was higher than normal group. LF/HF had a negative correlation with waist circumference in MS group, while positive correlation in normal group. (5) In total subjects, TP had a positive correlation with Mg. In two groups, there is no contrast between the correlations of the MS contents and HRV. However LF/HF had a positive correlation with Na in MS group, TP and LF had negative correlation with Ca, while RMSSD and HF had negative correlation with Cu in normal group. Conclusion These results may suggest that HTME and HRV are useful in diagnosing and preventing the metabolic syndrome.

• Geophysics and Geophysical Exploration
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• v.14 no.2
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• pp.164-175
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• 2011

Using natural electromagnetic (EM) fields at low frequencies, magnetotelluric (MT) surveys can investigate conductivity structures of the deep subsurface and thus are used to explore geothermal energy resources and investigate proper sites for not only geological $CO_2$ sequestration but also enhanced geothermal system (EGS). Moreover, marine MT data can be used for better interpretation of marine controlled-source EM data. In the interpretation of MT data, MT modeling schemes are important. This study improves a three dimensional (3D) MT modeling algorithm which uses edge finite elements. The algorithm computes magnetic fields by solving an integral form of Faraday's law of induction based on a finite difference (FD) strategy. However, the FD strategy limits the algorithm in computing vertical magnetic fields for a topographic model. The improved algorithm solves the differential form of Faraday's law of induction by making derivatives of electric fields, which are represented as a sum of basis functions multiplied by corresponding weightings. In numerical tests, vertical magnetic fields for topographic models using the improved algorithm overcome the limitation of the old algorithm. This study recomputes induction vectors and tippers for a 3D hill and valley model which were used for computation of the responses using the old algorithm.

• Journal of the Korean Geographical Society
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• v.39 no.3
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• pp.425-443
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• 2004

Fluvial terraces is poorly developed along Bukhan River in Central Korea. Altitude from riverbed of T1 terraces are 18-29m, T2 terraces 2539m, respectively. Rubification index of T2 is 0.66, T1 is 0.54, and thickness of gravel weathering rind on gneiss of T2 are 14.0mm, granites of T2 are $\infty$, gneiss of T1 are 5.0mm and granites of T2 are 8.0mm, because weathering in deposits of T2 terraces, older than T1, is severer than T1 terraces. Since deposits in T2 have more active and longer weathering than T1, SiO$_2$/Al$_2$O$_3$ is 3.32 in T2 and 4.06 in T1, and SiO$_2$/R$_2$O$_3$ is 2.64 in T2 and 3.19 in T1. CIA(Chemical Index of Alteration) is 87.85％ in T2 and 85.88％ in T1. Kaolinite and halloysite are founded in deposits of T2 indicating high weathering, and are founded gibbsite made tv eluviation of kaolinite. However, deposits of T1 have no kaolinite, and are found plagioclase, weak mineral in weathering process. Comparing to previous researches by estimated age as altitude from riverbed, rubification index, thickness of gravel weathering rind, element contents and mineral composition, forming age of T2 terraces in Bukhan River are estimated in marine oxygen isotope stage 6 (130-190ka), and T1 terraces are marine oxygen isotope stage 4(59-74ka).

• Economic and Environmental Geology
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• v.41 no.2
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• pp.183-199
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• 2008

This study is focused on characterization of the physio-chemical and mineralogical properties, investigation of their vertical changes in the tailing profile of the Guryoung mining area, classification of the profile into distinct zones, and condition conceptual model of physio-chemical conditions and phases-water relationships controlling the element behaviors in the tailings. The upper part of the groundwater is characterized by the high contents of $Fe_2O_3$ and $SO_3$ for whole rock analysis, low pH, and the occurrence of jarosite, schwertmannite and Fe-oxyhydroxide as the secondary mineral phases. The tailing profile can be divided into the covering soil, jarosite zone, Fe-sulfate zone, Fe-oxyhydroxide and gypsum-bearing pyrite zone, calcite-bearing pyrite zone, soil zone, and weathered zone on the based of the geochemical and mineralogical characteristics. The profile can be sampled into the oxidized zone and the carbonate-rich primary zone with the dramatic changes in pH and the secondary mineral phases. The conceptual model proposed for the tailing profile can be summarized that the oxidation of pyrite is the most important reaction controlling the changes in pH, the dissolution of the primary silicates and carbonates, the precipitation of secondary mineral phases, acid-neutralizing, and heavy metal behaviors through the profile.