• Corrosion Science and Technology
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• 제5권5호
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• pp.160-167
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• 2006

S-Acetyl Isothiourea Acetate (S-AITA) was synthesized in the laboratory and this influence on the inhibition of corrosion of mild steel in 1.11 N hydrochloric and 1.12 N sulphuric acids was investigated by weight loss and potentiostatic polarization techniques at 303K, 353K and 403K. These results were confirmed by the impedance technique. The inhibition efficiency increased with increase in concentration of inhibitor and decreased with rise in temperature from 303K to 403K. The maximum inhibition efficiency of S-AITA was found to be 99.95% (0.5% of S-AITA) at 303K in sulphuric acid. The adsorption of this compound on the mild steel surface from the acids has been found to obey Temkin's adsorption isotherm. The potentiostatic polarization results revealed that S-AITA was a mixed type inhibitor. Some thermodynamic parameters i.e., activation energy (Ea), free energy of adsorption (${\Delta}G_{ads}$), enthalpy of adsorption (${\Delta}H$) and entropy of adsorption (${\Delta}S$) were also calculated from weight loss data.

• Steel and Composite Structures
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• 제27권2호
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• pp.229-242
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• 2018

High strength steel is widely used in industrial applications to improve the load-bearing capacity and reduce the overall weight and cost. To take advantage of the benefits of this type of steel in construction, an innovative hybrid fabricated member consisting of high strength steel tubes welded to mild steel plates has recently been developed. Component-scale uniaxial and multiaxial cyclic experiments have been conducted with simultaneous constant or varying axial compression loads using a multi-axial substructure testing facility. The structural interaction of high strength steel tubes with mild steel plates is investigated in terms of member capacity, strength and stiffness deterioration and the development of plastic hinges. The deterioration parameters of hybrid specimens are calibrated and compared against those of conventional steel specimens. Effect of varying axial force and loading direction on the hysteretic deterioration model, failure modes and axial shortening is also studied. Plate and tube elements in hybrid members interact such that the high strength steel is kept within its ultimate strain range to prevent sudden fracture due to its low ultimate to yield strain ratio while the ductile performance of plate governs the global failure mechanism. High strength material also significantly reduces the axial shortening in columns which prevents undesirable frame deformations.

• 국제초고층학회논문집
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• 제7권4호
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• pp.287-298
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• 2018

High strength steels have been widely applied in recent years due to high strength and good working performance. When subjected to fire conditions, the strength and elastic modulus of high strength steels deteriorate significantly and hence the load bearing capacity of structures reduces at elevated temperatures. The reduction factors of mechanical properties of high strength steels are quite different from mild steels. Therefore, the fire design methods deduced from mild steel structures are not applicable to high strength steel structures. In recent ten years, the first author of this paper has carried out a lot of fundamental research on fire behavior of high strength steels and structures. Summary of these research is presented in this paper, including mechanical properties of high strength steels at elevated temperature and after fire exposure, creep response of high strength steels at elevated temperature, residual stresses of welded high strength steel member after fire exposure, fire resistance of high strength steel columns, fire resistance of high strength steel beams, local buckling of high strength steel members, and residual strength of high strength steel columns after fire exposure. The results show that the mechanical properties of high strength steel in fire condition and the corresponding fire resistance of high strength steel structures are different from those of mild steel and structures, and the fire design methods recommended in current design codes are not applicable to high strength steel structures.

• Corrosion Science and Technology
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• 제22권2호
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• pp.73-89
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• 2023

Due to continuous promotion of green alternatives to toxic petrochemicals by government policies, research efforts towards the development of green corrosion inhibitors have intensified recently. The objective of the current work was to develop novel green and sustainable corrosion inhibitors derived from 4-aminoantipyrine to effectively prevent corrosion of mild steel in corrosive environments. Gravimetric methods were used to investigate corrosion inhibition of 4-((furan-2-ylmethylene)amino)antipyrine (FAP) and 4-((pyridin-2-ylmethylene)amino)antipyrine (PAP) for mild steel in 1 M HCl. FAP and PAP were subjected to quantum chemical calculations using density functional theory (DFT). DFT was used to determine the mechanism of mild steel corrosion inhibition using inhibitors tested in HCl. Results demonstrated that these tested inhibitors could effectively inhibit mild steel corrosion in 1.0 M HCl. At 0.0005 M, these inhibitors' efficiencies for FAP and PAP were 93.3% and 96.5%, respectively. The Langmuir adsorption isotherm was obeyed by these inhibitors on the mild steel surface. Values of adsorption free energies, ΔG^o_ads, revealed that FAP followed chemical and physical adsorptions.

• 한국가스학회지
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• 제19권6호
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• pp.62-66
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• 2015

LNG선이나 해양플랜트 같은 설비나 구조물은 작동 조건을 고려할 때, 특히 부재마다 가지는 고유한 연성 취성천이온도(Ductile to Brittle Transition Temperature, DBTT)를 고려하여 설계되어야 한다. 본 연구에서는 해양플랜트 및 LNG선에 hull plate로 쓰이는 A-grade 연강(mild steel)에 대해 DBTT를 샤르피 V-노치(CVN) 실험을 통해 알아보았고 파괴형상을 통한 파괴거동을 살펴보았다. 그 결과 온도가 감소함에 따라 충격 흡수에너지는 감소함을 보였다. Upper shelf energy region과 lower shelf energy region이 나타나고 그 사이 구간의 천이점을 통해 DBTT가 결정되었다. 파괴형상에서는 upper shelf energy region에서 수많은 딤플이 연성파괴 형상으로 관찰되고 lower shelf energy region에서는 전형적인 취성파단형상이 관찰되었다. 이를 통해 BCC 구조를 가지는 A-grade 연강은 upper shelf energy 구역과 lower shelf energy구역을 보이고 그 사이 구간의 천이점에서 급격하게 온도가 떨어지는 DBTT구간을 뚜렷하게 보이는 특성을 알 수 있었다.

• 대한기계학회논문집
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• 제6권2호
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• pp.107-112
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• 1982

In order to analyze and investigate in the fatigue behavior of the notched specimens under the two level stressing, the U-notched specimens of structural carbon steel which is generally used is prepared. The obtained results are summarized as follows; (1) The fatigue limit of the U-notched specimens is lower than that of the unnotched. The fatifue notch factor (.betha.) of the U-notched specimens is 1.44 for mild steel and 1.52 for harden steel. The notch sensitivity (q) is 0.68 for mild steel and o.8 for harden steel. That is, these facts show that harden steel is more sensitive to the notch than mild steel. (2) The fatigue life time of the U-notched specimens under the overstressing is shorter than under the constant stressing, and the degree of fatigue life time decrease is different to each stress level; the degree for the high stress level is more than for the low stress level. (3) The fatigue life time of the U-notched specimes under the understressing is longer than under the constant stressing, and the degree of fatigue life time increase for the low stress level is more than for the high stress level.

• Journal of Electrochemical Science and Technology
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• 제11권3호
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• pp.257-272
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• 2020

This study covers the stages of testing whether the azo dye with chemical name (E)-5-[(4-(benzyl(methyl)amino)phenyl)diazenyl]-1,4-dimethyl-1H-1,2,4-triazol-4-ium zinc (II) chloride (DMT), known as Maxilon Red GRL in the dye industry, can be used as an anticorrosive feasible inhibitory agent, especially in industrial areas other than carpet, yarn and fibre dyeing. These test stages consist of the electrochemical measurement techniques such as potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and linear polarization resistance (LPR) for diverse concentrations and durations. The adsorption of the viewed DMT molecule on the mild steel surface obeyed the Langmuir isotherm. The zero charge potential (PZC) of mild steel was also found to assess the inhibition mechanism in containing DMT solution. The inhibition performance of DMT on the mild steel in a 1.0 M HCl solution was also investigated using methods such as metal microscope, atomic force microscope (AFM) and field emission scanning electron microscope (FE-SEM).

• Journal of Electrochemical Science and Technology
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• 제8권3호
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• pp.222-235
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• 2017

First, in this study, the inhibition efficiencies of metal complexes with Cu(II), Ni(II) and Zn(II) of STSC ligand for corrosion control of mild steel in oilfield formation water were investigated. The IEs for a mixture of 500 ppm STSC and 5 ppm metal ion ($Cu^{+2}$, $Ni^{+2}$, $Zn^{+2}$) were found to be 88.77, 87.96 and 85.13 %, respectively. The results were obtained from the electrochemical techniques such as open circuit potential, linear and tafel polarization methods. The polarization studies have showed that all used Schiff base metal complexes are anodic inhibitors. The protective film has been analyzed by FTIR technique. Also, to detect the presence of the iron-inhibitor complex, UV-Visible spectral analysis technique was used. The inhibitive effect was attributed to the formation of insoluble complex adsorbed on the mild steel surface and the adsorption process follows Langmuir adsorption isotherm. The surface morphology has been analyzed by SEM. Secondly, the computational studies of the ligand and its metal complexes were performed using DFT (B3LYP) method with the $6-311G^{{\ast}{\ast}}$ basis set. Finally, it is found that the experimental results were closely related to theoretical ones.

• Corrosion Science and Technology
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• 제4권5호
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• pp.191-200
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• 2005

Two azole compounds viz., Imidazole (IM) and 2-Methylimidazole (2-MIM) were studied to investigate their inhibiting action on corrosion of mild steel in phosphoric acid ($H_3PO_4$) solution by mass loss and polarization techniques at 302K-333K. It has been found that the inhibition efficiency of the all inhibitors increased with increase in inhibitor concentration and decreases with increasing temperature and also with increase in acid concentrations. The inhibition efficiency of these compounds showed very good inhibition efficiency. At 0.5% of IM and 2-MIM in 1N and 5N phosphoric acid solution at 302K to 333K for 5 hours immersion period, the inhibition efficiency of 2-Methylimidazole found to be higher than Imidazole. The adsorption of these compounds on the mild steel surface from the acids has been found to obey Tempkin's adsorption isotherm. The values of activation energy ($E{\alpha}$) and free energy of adsorption (${\Delta}G{\alpha}ds$) were also calculated. The plots of log $W_f$ against time (days) at 302K give straight line which suggested that it obeys first order kinetics and also calculate the rate constant k and half life time $t_{1/2}$. Surface was analyzed by SEM and FITR spectroscopy.

• Journal of Electrochemical Science and Technology
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• 제7권4호
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• pp.251-262
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• 2016

The corrosion protection of mild steel in 1M HCl and 0.5M $H_2SO_4$ solutions by ethanol extract of Vernonia amygdalina (VA) was studied using a combination of experimental and computational methods. The obtained results revealed that VA reduced the corrosion of mild steel in both environments and inhibition efficiency increased with VA concentration but decreased with prolonged exposure. Electrochemical results showed that the extract functioned via mixed corrosion inhibiting mechanism by adsorption of some organic constituents of the extract on the metal/acid interface. Findings from infrared spectroscopy and electron microscopy all confirmed that VA retarded mild steel corrosion in both 1M HCl and 0.5M $H_2SO_4$ through an adsorption process. The adsorption behavior of selected constituents of the extract was modeled using density functional theory computations.