• Title/Summary/Keyword: microstructure effect

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Effect of activator types on cement mortar with polymeric aluminum chloride waste residue

  • Ping Xu;Yuhao Cui;Dong Han;Minxia Zhang;Yahong Ding
    • Advances in concrete construction
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    • v.15 no.3
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    • pp.149-159
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    • 2023
  • Water glass (WG) and sodium sulfate (SS) were used to prepare polymeric aluminum chloride residue cement mortar (PACRM) by single and compound blending with polymeric aluminum chloride waste residue, respectively. The structural strength and textural characteristics examinations showed that PACRM consistency increased by incorporating WG, but decreased by incorporating SS. When WG and SS were compounded, the mortar consistency initially rose before falling. The compressive strength of PACRM increased and then decreased as WG was increased. The mechanical properties of PACRM were better enhanced by SS than WG, showing no strength deterioration. The main reason for the improved mechanical properties of polymeric aluminum chloride waste residue in the presence of activators is the increased precipitation of reactive substances, such as C-S-H gels, calcium silica, and Ca(OH)2. The density of the specimens with PACRM and the degree of aggregation of hydration products were significantly enhanced by generating more hydration products in the mortar. Further, the cracks and pores were significantly reduced, and the matrix structure was continuous and dense at 5% SS doping and 3% compound doping.

Size-dependent strain rate sensitivity in structural steel investigated using continuous stiffness measurement nanoindentation

  • Ngoc-Vinh Nguyen;Chao Chang; Seung-Eock Kim
    • Steel and Composite Structures
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    • v.47 no.3
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    • pp.355-363
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    • 2023
  • The main purpose of this study is to characterize the size-dependent strain rate sensitivity in structural steel using the continue stiffness measurement (CSM) indentation. A series of experiments, such as CSM indentation and optical microscope examination, has been performed at the room temperature at different rate conditions. The results indicated that indentation hardness, strain rate, and flow stress showed size-dependent behavior. The dependency of indentation hardness, strain rate, and flow stress on the indentation size was attributed to the transition of the dislocation nucleation rate and the dislocation behaviors during the indentation process. Since both hardness and strain rate showed the size-dependent behavior, SRS tended to depend on the indentation depth. The results indicated that the SRS was quite high over 2.0 at the indentation depth of 240 nm and quickly dropping to 0.08, finally around 0.046 at large indents. The SRS values at large indentations strongly agree with the general range reported for several types of low-carbon steel in the literature (Chatfield and Rote 1974, Nguyen et al. 2018b, Luecke et al. 2005). The results from the present study can be used in both static and dynamic analyses of structures as well as to assess and understand the deformation mechanism and the stress-state of material underneath the indenter tip during the process of the indentation testing.

Effect of γ-C2S Addition on the Properties of GGBFS Containing Mortar in Accelerated Carbonation Curing (가속 탄화 조건에서 γ-C2S 첨가가 모르타르 함유 GGBFS의 특성에 미치는 영향)

  • Tran, Duc Thanh;Lee, Han-seung;Singh, Jitendra Kumar
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2020.11a
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    • pp.33-34
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    • 2020
  • 𝛾-dicalcium silicate (𝛾-C2S) is characterized by its strong carbonation reactivity and has the prospect to be utilized as a building material with the added benefit of CO2 capture. This paper aims to point out the impact of 𝛾-C2S on the microstructure characteristics and mechanical properties of GGBFS paste, and mortar samples. The compressive strength of 𝛾-C2S added GGBFS cement mortar is higher compared to without 𝛾-C2S in accelerated carbonation (AC) up to 14 days of curing but once the curing duration is increased, there is no significant improvement in compressive strength. This study suggests that 𝛾-C2S can capture the atmospheric CO2 (mostly generated from cement and metallurgy industries) and utilized in construction.

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Effect of Blowing Agents on Physical Properties of Polyurethane-polydimethylsiloxane Hybrid Foam

  • Asell Kim;Hyeonwoo Jeong;Sang Eun Shim
    • Elastomers and Composites
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    • v.58 no.4
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    • pp.208-215
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    • 2023
  • In this study, the properties of polyurethane-polydimethylsiloxane (PU-PDMS) hybrid foams containing different types and contents of physical blowing agents (PBAs) were investigated. Two types of blowing agents, namely physical blowing agents and thermally expandable microspheres (TEM), were applied. The apparent density was measured using precisely cut foam samples, and the pore size was measured using image software. In addition, the microstructure of the foam was confirmed via scanning electron microscopy and transmission electron microscopy. The thermal conductivities related to the microstructures of the different foams were compared. When 0.5 phr of the hydrocarbon-based PBA was added, the apparent density and pore size of the foam were minimal; however, the pore size was larger than that of neat foam. In contrast, the addition of 3 phr of TEM effectively reduced both the apparent density and pore size of the PBAs. The increase in resin viscosity owing to TEM could enhance bubble production stability, leading to the formation of more uniform and smaller pores. These results indicate that TEM is a highly efficient PBA that can be employed to decrease the weight and pore size of PU-PDMS hybrid foams.

On vibrations of functionally graded carbon nanotube (FGCNT) nanoplates under moving load

  • Alaa A. Abdelrahman;Ismail Esen;Mohammed Y. Tharwan;Amr Assie;Mohamed A Eltaher
    • Advances in nano research
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    • v.16 no.4
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    • pp.395-412
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    • 2024
  • This article develops a nonclassical size dependent nanoplate model to study the dynamic response of functionally graded carbon nanotube (FGCNT) nanoplates under a moving load. Both nonlocal and microstructure effects are incorporated through the nonlocal strain gradient elasticity theory. To investigate the effect of reinforcement orientation of CNT, four different configurations are studied and analysed. The FGM gradation thorough the thickness direction is simulated using the power law. In the context of the first order shear deformation theory, the dynamic equations of motion and the associated boundary conditions are derived by Hamilton's principle. An analytical solution of the dynamic equations of motion is derived based on the Navier methodology. The proposed model is verified and compared with the available results in the literature and good agreement is found. The numerical results show that the dynamic performance of FGCNT nanoplates could be governed by the reinforcement pattern and volume fraction in addition to the non-classical parameters and the moving load dimensionless parameter. Obtained results are reassuring in design and analysis of nanoplates reinforced with CNTs.

Effect of Carburizing Heat Treatment Process on Microstructure and Residual Stress Changes in AISI 9310 Steel. (AISI 9310강의 침탄열처리 경로가 조직 및 잔류응력 변화에 미치는 영향)

  • Youngchul Jeong;Joohyeon Bae;Jaeman Park;Seungjun OH;Janghyun Sung;Yongsig Rho
    • Journal of the Korean Society for Heat Treatment
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    • v.37 no.3
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    • pp.128-137
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    • 2024
  • In this study, the carburizing heat treatment process used in aircraft gear manufacturing was compared with the general carburizing heat treatment process using AISI 9310 steel. The process of carburizing followed by slow cooling, and then quenching after austenitizing(Process A) showed less compressive residual stress and less retained austenite in the surface layer compared to the process of quenching directly after carburizing(Process B). In prpcess B, there was a large amount of retained austenite when quenched immediately after carburization, and when treated with subzero, martensite rapidly increased and the compressive residual stress increased significantly, but at the same time, there is a risk of cracking due to severe expansion in volume. Therefore, in the case of aviation parts, it is believed that a step-by-step heat treatment cycle was adopted to ensure stability against heat treatment cracks. As a result of the final tempering after sub-zero treatment, the A process specimen showed a deeper effective case depth and HV700 depth and a higher hardness value above HV700 than the B process specimen.

Effect of tempering conditions on the tempering behavior and mechanical properties of tempered H13 steel (H13 강의 템퍼링 조건에 따른 템퍼링 거동 및 기계적 물성 효과 )

  • Gi-Hoon Kwon;Byoungho Choi;Yoon-Ho Son;Young-Kook Lee;Kyoungil Moon
    • Journal of Surface Science and Engineering
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    • v.57 no.2
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    • pp.105-114
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    • 2024
  • Tempering behavior and mechanical properties in AISI H13 steel, quenched and tempered from 300 ℃ to 700 ℃ for different tempering time (1, 2, 5, 10, 20 hr) were quantitatively investigated by scanning electron microscopy (SEM), x-ray diffractometer (XRD), impact test machine, rockwell apparatus, ball-on-disk tester. Under the condition that the tempering time is 2 hours, the hardness increases slightly as the tempering temperature increases, but decreases rapidly when the tempering temperature exceeds 500 ℃, while the impact energy increases in proportion to the tempering temperature. Friction tests were conducted in dry condition with a load of 30 N, and the friction coefficient and wear rate according to tempering conditions were measured to prove the correlation with hardness and microstructure. In addition, primary tempering from 300 ℃ to 700 ℃ was performed at various times to establish a kinetic model to predict hardness under specific tempering conditions.

Corrosion characteristics in stress and various environments with Sn addition to Cu pipe (구리 배관의 Sn 첨가에 따른 응력 및 다양한 환경에서의 부식 특성)

  • Serim Kim;Uijun Kim;Myeonghoon Lee;Seunghyo Lee
    • Journal of Surface Science and Engineering
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    • v.57 no.3
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    • pp.192-200
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    • 2024
  • Cu as a heat exchanger tube is an important component in thermal fluid transfer. However, Cu tubes are exposed to stress in certain environments, leading to stress corrosion cracking (SCC). In this study, the effect of Sn addition on microstructure and corrosion characteristics was examined. The microstructural examination revealed the presence of columnar crystal and a grain refinement due to the addition of Sn. Electrochemical measurements showed that the 5 wt.% NH3 environment was the most vulnerable environment to Cu corrosion, and the corrosion current density increased as stress increased. The immersion test exhibited the formation of Cu2O and Cu(OH)2 corrosion product in 3.5 wt.% NaCl and 5 wt.% NH3 environments, respectively. Results indicated that Sn addition to Cu was an important factor in improving the mechanical strength.

Effect of biofibers addition on the structure and properties of soy protein composite films

  • Ye Eun Kim;Su Jin Kim;Yong-Il Chung;Chae Hwa, Kim;Tae Hee Kim;In Chul Um
    • International Journal of Industrial Entomology and Biomaterials
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    • v.48 no.1
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    • pp.25-32
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    • 2024
  • Soy protein isolate (SPI) has garnered researchers' attention due to its abundance, costeffectiveness, excellent biocompatibility, hemo-compatibility, and biodegradability. However, SPI faces limitations in application due to poor processability and weak mechanical strength. Substantial efforts have been made to address these challenges. In this preliminary study, glycerol and biofibers were added to SPI to improve the mechanical properties and film forming, and glyoxal was employed to crosslink SPI molecules. The microstructure and mechanical properties of the resulting SPI/composite films were evaluated. A 15% addition of glycerol proved sufficient for good film formation. Among the biofibers, short SF microfibers were the most effective in enhancing breaking strength, while TEMPO-oxidized CNF (cellulose nanofiber) excelled among CNFs. Crosslinking with glyoxal significantly enhanced the mechanical properties, with the type of biofiber minimally affecting the mechanical properties of the crosslinked SPI composite films.

Waste to shield: Tailoring cordierite/mullite/zircon composites for radiation protection through controlled sintering and Y2O3 addition

  • Celal Avcioglu;Recep Artir
    • Nuclear Engineering and Technology
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    • v.56 no.7
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    • pp.2767-2774
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    • 2024
  • In this study, investment casting shell waste successfully utilized to produce cordierite/mullite/zircon composites. Green pellets, consisting of investment casting shell waste, alumina, and magnesia, were prepared and sintered at temperatures between 1250 and 1350 ℃. The influence of the sintering temperature on the crystalline phase composition, densification behavior, flexural strength, microstructure, and radiation shielding properties of the cordierite/mullite/zircon composites is investigated. Phase analysis showed that characteristic cordierite peaks appear at 1250 ℃, but the complete conversation of silica from investment casting shell waste into cordierite requires a sintering temperature of at least 1300 ℃. Notably, the cordierite/mullite/zircon composite sintered at 1350 ℃ exhibited a sixfold increase in flexural strength compared to the ceramic composite directly fabricated from investment casting shell waste at the same sintering temperature. Furthermore, the effect of Y2O3 addition on composites' radiation shielding properties is investigated. The results show that the Y2O3 addition improves densification behavior, enhancing the shielding capabilities of the composites against fast neutron and gamma radiation. Our findings suggest that the developed ceramic composites show significant potential for gamma-ray and neutron shielding applications.