• Title/Summary/Keyword: micro-emulsion

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Characteristics of ignition and micro-explosion for droplets of water-in-fuel emulsion (유화액적 연료의 점화와 미소폭발의 특성)

  • Jeung, Incheol;Lee, Kyung-Hwan
    • Journal of Advanced Marine Engineering and Technology
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    • v.37 no.1
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    • pp.1-8
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    • 2013
  • The water-in-fuel droplets were applied to investigate the effect of mixing ratio between water and decane, ambient temperature, droplet size and spacing between droplets on ignition and micro-explosion in a heated chamber with high temperature. The ignition temperature of droplet was found lower as the droplet size was increased and the contents of water was decreased. The life time of droplet, however, decreases as the contents of water increases due to the micro-explosion. The occurrence of micro-explosion also increases as the size of droplets and the ambient temperature increase. The flame spread speed gets faster as the contents of water and the number of suspender decreases.

Gastrointestinal Absorption of Phenytoin from on Oil-in-water Microemulsion

  • Kwon, Kwang-Il;Bourne, David-W.A.
    • Archives of Pharmacal Research
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    • v.20 no.5
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    • pp.480-485
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    • 1997
  • The absorption profile of phenytoin Na emulsion were examined compared to that of phenytoin suspension after oral administration in the rat. The corn oil-in-water emulsion, particle size of $184{\pm}$57.8 nm, was prepared using a microfludizer, and phenytoin Na added by shaft homogenizer. The phenytoin emulsion or suspension, 100 mg/kg, were intubated intragastrically using oral dosing needle and blood samples were withdrawn via an indwelling cannula from the conscious rat. Plasma concentrations of phenytoin were measured with HPLC using phenacetin as an internal standard. The plasma concentration versus time data were fitted to a one compartment open model and the pharmacokinetic parameters were calculated using the computer program, Boomer. The phenytoin plasma concentrations from the emulsion at each observed time were about 1.5-2 times higher than those from the suspension, significantly at time of 5, 6 and 7 hr after administration. The absorption $(k_a)$ and elimination rate constant $(k_e)$ were not altered significantly, however the AUC increased from 65.6 to $106.7{\mu}ghr/ml$ after phenytoin suspension or emulsion oral administration, respectively. From an equilibrium dialysis study, the diffusion rate constant $(k_{IE})$ was considerably higher from the phenytoin Na emulsion $(0.0439 hr{-1})$ than phenytoin suspension $(0.0014 hr{-1})$.

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Preparation f emulsion by Microfluidizer (고압유화장치를 이용한 emulsion의 제조)

  • 백승석;한창규
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.19 no.1
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    • pp.127-138
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    • 1993
  • This study was investigated optimal conditions which were necessary to prepare emulsion of four component systems by the Microfluidizer. Squalane, isopropyl myristate, PPG-15 stearyl benzoate ester were used as an oil and POE(20) sorbitan monolaurate, POE(20) sorbitan monopalmitate, POE(20) sorbitan monostearate, glycerine were selected as a cosurfactant and surfactant. The emulsion was affected by the operating pressure, the recycle frequency and oil, surfactant, cosurfactant phase. The operating pressure and recycle frequency increased, the droplet diameter of emulsion decreased and was constant later. In this study, the optimal pressure and recycle frequency were 1400 bar, 4 cycles. The droplet size was the smallest when the concentration of glycerine was 30 wt.%. As the oil phase is increased, the size is increased.

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Combustion Characteristics of Bio Emulsion Fuel (바이오에멀젼 연료의 연소 특성)

  • Kim, Moon-Chan
    • Journal of the Korean Applied Science and Technology
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    • v.35 no.4
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    • pp.1421-1432
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    • 2018
  • Water soluble oil was obtained from the pyrolysis of coconut waste as a biomass at $600^{\circ}C$. It was studied that the combustion characteristics of bio-emulsion fuel by mixing and emulsifying 15~20% of water soluble oil which obtained from pyrolysis of coconut waste as a biomass and MDO(marine diesel oil) as a marine fuel. Engine dynamometer was used for detecting emissions, temperature, and power. The temperature of combustion chamber was decreased because the moisture in bio-emulsion fuel deprived of heat of evaporation in combustion chamber. While combustion, micro-explosion took place in the combustion chamber by water in the bio-emulsion fuel, MDO fuel scattered to micro particles and it caused to smoke reduction. The temperature reduction of combustion chamber by using bio-emulsion fuel reduced the NOx emission. The increasing of bio-oil content caused increasing water content in bio-emulsion fuel so total calorific value was reduced. So the characteristics of power was decreased in proportion to using the increasing amount of bio-emulsion fuel. Heavy oil as a marine fuel exhausts a lot of smoke and NOx. We expect that we can reduce the exhaust gas of marine engine such as smoke and NOx by using of bio-emulsion fuel as a marine fuel.

The Effect of Fluorine Based Emulsion on the Watertightness Properties of Portland Cement (시멘트 수밀성에 대한 불소계 에멀젼의 영향)

  • Kang, Hyun Ju;Song, Myong Shin;Song, Su Jae;Park, Su Haeng
    • Applied Chemistry for Engineering
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    • v.20 no.5
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    • pp.505-510
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    • 2009
  • It is well known that the properties of concrete such as the compressive strength, water permeability, water tightness and durability are affected by micro-structure in hardened cement paste. Especially, for durability of concrete, watertightness of cementitious materials is the most critical property among various properties. Recently, many types of material such as organic and/or inorganic materials are used for watertightness of concrete. In this study, we examined the effect of fluorine-based emulsion on watertightness property. And we also discussed the change of microstructure and formation of hydrates in hardened cement paste by the addition of fluorine-based emulsion. Cement paste with fluorine-based emulsion showed improvement of watertightness by the surface activation of cement paste and by formation of $CaF_2$ fine crystals in cement pore structure.

A Study of Emulsion Fuel of Cellulosic Biomass Oil (목본계 바이오매스오일의 에멀젼 연료화 연구)

  • Kim, Moon-Chan
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.4
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    • pp.836-847
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    • 2016
  • Water soluble oil was obtained by pyrolysis of biomass. The characteristics of emulsified fuel by mixing water soluble oil and MDO(marine diesel oil) and engine emissions were studied with engine dynamometer. Saw dust was used as biomass. Water soluble oil was obtained by condensing of water and carbon content with pyrolysis of saw dust at $500^{\circ}C$. Emulsion fuel was obtained by emulsifying MDO and water soluble oil by the water soluble oil mixing ratio of 10 to 20% of MDO. Exhaust gas detection was performed with engine dynamometer. While combustion, micro-explosion took place in the combustion chamber by water in the emulsion fuel, emulsion fuel scattered to micro particles and it caused to smoke reduction. The heat produced from water vapour reduce the temperature of internal combustion chamber and it caused to inhibition of NOx production. It can be verified by the lower exhaust temperature of each ND-13 mode using emulsion fuel than that of MDO fuel. The NOx and smoke concentration were reduced by increasing water soluble oil content in the emulsion fuel. The power also decreased according to the increment of water soluble oil content of emulsion fuel because emulsion fuel has low calorific value due to high water content than MDO. As a result of ND-13 mode test with 20% bio oil content, it was achieved 25% reduction in NOx production, 60% reduction in smoke density, and 15% reduction in power loss.

A Study on Nano-emulsion for Enhanced Transdermal Delivery of Hippophae rhamnoides Leaf Extract (비타민나무 잎 추출물의 피부 흡수 증진을 위한 나노에멀젼 연구)

  • Chae, Kyo Young;Kwon, Soon Sik;Park, Soo Nam
    • Applied Chemistry for Engineering
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    • v.24 no.3
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    • pp.260-265
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    • 2013
  • In this study, nano-emulsions containing 0.01, 0.03, 0.05, and 0.10% ethyl acetate fraction of Hippophae rhamnoides (H. rhamnoides) leaf extracts were prepared. The particle size, particle size distribution and skin permeability of the nano-emulsions were evaluated for five weeks. Nano-emulsion was prepared by the sequential use of homogenizer and microfluidizer. Nano-emulsion containing the ethyl acetate fraction exhibited a monodispersed form. Nano-emulsion containing 0.03% ethyl acetate fraction was the most stable for five weeks. The in vitro skin permeation study of nano-emulsion containing 0.03% ethyl acetate fraction was carried out using Franz diffusion cell. The nano-emulsion showed a better skin permeability than that of O/W emulsion. These results indicate that the nano-emulsion containing the ethyl acetate fraction of H. rhamnoides leaf extract showed a remarkable stability and skin permeability than that of O/W emulsion.

Technology Trend for the Preparation of Polymeric Particles by SPG Technique (SPG 막유화법을 이용한 고분자 입자 제조기술의 동향)

  • Lee, Sang-Kug;Kim, Sung-Wook;Choi, Kyoung-Ho;Lim, Eun-Hee
    • Elastomers and Composites
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    • v.44 no.3
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    • pp.222-231
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    • 2009
  • Shirasu-porous-glass (SPG) membrane emulsification is highly attractive in the field of toner industries, foods and drug delivery systems because of its easy control of particle size in micro-scale, narrow size distribution and multiple emulsion. The particle size and morphology of emulsion droplets can be controlled by changing the type of initiators, additives, monomers, crosslinkers and inhibitors in SPG membrane emulsification. In this paper, principles of SPG membrane emulsification, influence of process parameters and industrial applications have been addressed.

Influence of Several Physicochemical Conditions on the Flocculation of Micro Stickies

  • Kim, Jong-Min;Lee, Hak-Lae
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.40 no.5
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    • pp.20-26
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    • 2008
  • Behavior of micro stickies was analyzed using model micro stickies prepared with PVAc emulsion adhesive. Flocculation of micro stickies increased with temperature. Acidic state also induced greater flocculation of micro stickies since they became more unstable under these conditions. Flocculation of micro stickies increased as calcium ion concentration increased. But the presence of calcium carbonates made micro stickies dispersed indicating that calcium carbonates cause two different effects on the behavior of micro stickies. Talc increased flocculation of micro stickies because of its hydrophobic nature. Cationic polymer increased flocculation of micro stickies. Especially cationic starch has far greater effect in flocculating sticky particles by forming bridging flocculations.

A Study on the Encapsulation of Cosmetic Emulsion Using Microfluidics (Microfluidics를 이용한 화장품 에멀젼 캡슐레이션에 대한 연구)

  • Jeong, Nam-Gyun;Jin, Hong-Jong
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.22 no.1
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    • pp.81-86
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    • 2021
  • The cosmetic industry is technology-intensive in the field of fine chemistry and continues to grow globally. The functional aspects have been mainly emphasized in the past to increase the market share in these cosmetics industries. Recently, however, efforts have been made to attract the attention of consumers to the visual effects as well as the excellent performance of cosmetics at home and abroad. Accordingly, cosmetic manufacturers are trying various technologies that encapsulate the cosmetic emulsion and modify the shape, color, and texture of the emulsion capsule. The basic and easiest method of encapsulating emulsion is dropping the emulsion through the nozzle from emulsion storage. On the other hand, the existing method of encapsulating emulsion has a limit in reducing the size of the capsule. In this study, the limit was shown by theory and numerical analysis method, and the emulsion encapsulation phenomena occurring in the micro-channel were studied to apply microfluidics as an alternative.